Polymers can be formed using azide or click reactions.  (RDC 9/9/2011)

Azides
Click Reactions
Polymerization

Recent Journal Articles

Evaluation of different catalyst systems for bulk polymerization through “click” chemistry
(4435-4441)
Polymer 52 #20 (2011)
Sheng et al of Iowa State University,, Iowa, carried out  bulk polymerization of a diyne and a bisazide through the copper-catalyzed alkyne-azide 1,3-cycloaddition (CuAAC) with different catalysts, including the homogeneous catalyst Cu(PPh3)3Br and a heterogeneous Cu/C catalyst.  (RDC 9/7/2011)