“A silicate is a compound containing an anion in which one or more central silicon atoms are surrounded by electronegative ligands. This definition is broad enough to include species such as hexafluorosilicate ("fluorosilicate"), [SiF6]2−, but the silicate species that are encountered most often consist of silicon with oxygen as the ligand. Silicate anions, with a negative net electrical charge, must have that charge balanced by other cations to make an electrically neutral compound.” (Wikipedia 5/6/2009) 

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Editor's Notes

As the literature is reviewed, and items of interest concerning this topic are found. These may be added in an abbreviated form with the reference. Readers and contributors are invited to add their own notes. Contributors may add them directly and other readers can simply send their notes to the editor, Roger Corneliussen at rcorneliussen@4spe.org. He may edit and add them to this page at his discretion. “Silica, or silicon dioxide, SiO2, is sometimes considered a silicate, although it is the special case with no negative charge and no need for counter-ions. Silica is found in nature as the mineral quartz, and its polymorphs.” (Wikipedia 5/6/2009)