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The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings

SIMULATION DRIVEN MEDICAL PACKAGE DEVELOPMENT
Hossam M. Metwally, May 2010

The objective of this work is to demonstrate the concept of “simulation driven package development”. The concept involves not only simulating the structural behavior of the medical package (e.g. under top loading) but also predicting the package material distribution due to the manufacturing process conditions and tying that to the structural analysis. The structural analysis will thus take the more physical and usually non-uniform part material thickness distribution into consideration. The concept is highlighted through a case study.

NEW FUNCTIONS OF THERMOPLASTIC ELASTOMER BASED SANDWICH INJECTION MOLDINGS
I. Nishi , S. Matsubara , Y. W. Leong , H. Hamada , A. Goto, May 2010

Damping materials such as thermoplastic elastomer (TPE) usually has very low stiffness and easily deformable hence they are unsuitable for structural applications. This paper focuses on using sandwich injection molding technology to produce parts consisting PP skin and TPE core to impart high surface rigidity while maintaining dampening efficiency. Correlation between skin-core adhesion and flexural and damping properties of the moldings are discussed.

NEW FUNCTIONS OF THERMOPLASTIC ELASTOMER BASED SANDWICH INJECTION MOLDINGS
I. Nishi , S. Matsubara , Y. W. Leong , H. Hamada , A. Goto, May 2010

Damping materials such as thermoplastic elastomer(TPE) usually has very low stiffness and easilydeformable, hence they are unsuitable for structuralapplications. This paper focuses on using sandwichinjection molding technology to produce parts consistingPP skin and TPE core to impart high surface rigiditywhile maintaining dampening efficiency. Correlationbetween skin-core adhesion and flexural and dampingproperties of the moldings are discussed.

DETERMINATION OF MATERIAL PROPERTY CHANGES DUE TO COMBINING FLOW FRONTS
Jared Spaniol , Andrew Koleck , Brian Young, May 2010

It is a popular belief that when two plastic flow fronts converge, they merge, forming one single parabolic pressure-driven flow front. This is a common misconception; because plastic flow is laminar, these flow fronts should remain separate and maintain two individual parallel parabolic flow fronts. The purpose of this research is to examine the effect on part properties caused by increased orientation due to maintaining parallel flow fronts.

A STUDY OF THE MOLD THERMAL CHARACTERISTICS OF COOLING LINES IN CONVENTIONAL AND RAPID TOOLING
Jonathan Meckley , Robert Edwards, May 2010

This project examines the thermal differences between conventional and conformal cooling lines.?ÿ Three sets of inserts were built for this study.?ÿ A P20 insert was built and used to compare the other two rapid tooling inserts.?ÿ One rapid tooling insert had the same conventional cooling lines as the P20 insert.?ÿ The other rapid tooling insert had conformal cooling lines.?ÿ Mold temperatures were recorded and compared.?ÿ The conformal inserts had the lowest mold temperatures.

OPTIMAL PIGMENTATION STRATEGIES FOR NEAR INFRARED REFLECTING PIGMENTS
N. Kunimune, S. Tamada, T. NagasawA, Y. Makata, Y.W.Leong, H. Hamada, May 2010

Pigments are basically used to impart color. But the reflection of Near Infrared Radiation (NIR) is a requirement of modern pigments that gains particular importance for a multitude of uses. This paper reports about smart ways to formulate with this class of pigments. The main objective in this context is the enhancement of coloristic and NIR-reflective properties in typical plastics applications.

DEVELOPMENT AND CHARACTERIZATION OF POLYMERIC THERMOTROPIC MATERIALS FOR OVERHEATING PROTECTION OF SOLAR COLLECTORS
Johannes Loebel, Sami Schehata, Steven Goldstein, May 2010

Within this paper the effect of material formulation on the light-shielding performance of thermotropic glazings for overheating protection purposes is addressed. Specific focus is given to the establishment of relationships between glazing morphology and the light-shielding properties. Some major routes for further research and material optimization are deduced.

3D FEM ANALYSIS OF A WAVE TYPE SCREW CHANNEL
John Perdikoulias , Jiri Svabik , Tim Womer, May 2010

The paper presents an exploratory fundamental study of the polymer flow within a “wave” type screw channel. The analysis is performed on an “unwrapped” form of a conventional screw channel and a “wave” type channel of similar size. A 3D Finite Element Method (FEM) simulation was used to simulate the flow field and flow characteristics of the wave channel are compared relative to the plain channel.

IMPROVEMENT OF INTRINSIC VISCOSITY OF RECYCLED PET BY RADIO FREQUENCY HEATING
Minoru Ogasahara , Manabu Shidou , Shigeru Nagata, May 2010

The improvement of Intrinsic Viscosity of recycled poly(ethylene terephthalate)(R-PET) pellets by an industrial radio frequency(RF) heating is described. RPET pellets are made from post-consumer PET bottles, degraded by hydrolysis during distribution process. Hence, intrinsic viscosity(IV) or molecular weight of RPET exhibits significant lower compared to virgin PET, caused from cleavages of chains. This study evaluates the feasibility of RF Heat Treatment to improve the intrinsic viscosity of the material.

IMPROVED DIMENSIONAL STABILITY OF THERMOFORMED POLYLACTIC ACID ARTICLES
Julius Uradnisheck, May 2010

The shrinkage of thermoformed articles of polylactic acid are studied as a function of amount of modifier and dwell time in heated molds. Shrinkage is minimized by longer dwell times. Higher crystallinity causes lower shrinkage. Crystallinity in a thermoformed article dwelling in the heated mold is shown to rise to a higher level that predicted from laboratory tests due to supplemental crystallinity generated in the pre-heat step and forming or stretching step.

IMPROVED DIMENSIONAL STABILITY OF THERMOFORMED POLYLACTIC ACID ARTICLES
Julius Uradnisheck, May 2010

The shrinkage of thermoformed articles of polylactic acid are studied as a function of amount of modifier and dwell time in heated molds. Shrinkage is minimized by longer dwell times. Higher crystallinity causes lower shrinkage. Crystallinity in a thermoformed article dwelling in the heated mold is shown to rise to a higher level that predicted from laboratory tests due to supplemental crystallinity generated in the pre-heat step and forming or stretching step.

SIGNIFICANT ACCELERATION OF A UV-CURED COATING
John Spevacek, May 2010

Except for rare cases, increased cure speed of a UV-cured coating is greatly desirable. Our client approached us with a thiol-ene floor coating plagued with an excessively slow curing rate (9 cm/sec) and desired a 10x improvement. A wide range of process and reactant changes were explored but to little avail. Success was ultimately achieved when an alternate ene monomer was chosen despite literature references that indicated the monomer would instead decrease the reaction rate.

DECORATING METHODS FOR INJECTION MOLDED PARTS
Ronald D. Moffitt, Sandeep Vennam, Bhyrav Mutnuri, Wade DePolo, May 2010

This paper will discuss various decorating methods for injection molded parts, including industry wide definitions, descriptions and a comparison of the various methods. It will cover basic process descriptions, definitions, advantages of each, and their relationship to part design and end usage. How do I select the decorating method most suitable for my part?

LASER MARKING DAY/NIGHT PLASTICS
Jake Wieloch, May 2010

Day/Night applications surround us! Take a look around you they are in our cars trucks airplanes cell phones and the list goes on. The potential for this type of application is huge and laser marking is helping move it forward. Today's laser technology is helping to enhance and expand the field of day/night marking.

LASER MARKING DAY/NIGHT PLASTICS
Jake Wieloch ?, May 2010

The combination of advance controls, diode technology, and specially ground lenses mean high-quality, high-readability in Day/Night Components.

FLAME RETARDANCE OF ACRYLONITRILE BUTADIENE STYRENE-LAYER DOUBLE HYDROXIDE NANOCOMPOSITES
Sunny M. Ogbomo , Divya Kosuri , Nandika A. D’Souza, May 2010

Flame retardant layer double hydroxide (LDH) Zn2Al(OH)6PTS/Acrylonitrile butadiene styrene (ABS) nanocomposites were prepared by melt blending. The morphology and flammability properties were characterized by X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), and UL-94 test. XRD shows the microstructure of the composites with appearance of intercalation and exfoliation. The UL-94 test results shows that the LDH is an unprecedented flame retardant with improved flame extinction properties.

ACCELERATED AGING BEHAVIOR OF A RUBBER TOUGHENED ACRYLIC COPOLYMER AFTER GAMMA IRRADIATION
Dirk L. Pletcher, May 2010

The material property changes of an acrylic multipolymer after gamma irradiation are determined with respect to time and temperature. Empirical models are developed using a design of experiments approach. The effects of thermoforming on the aging behavior are examined. Experimental variables include irradiation dose level, aging temperature, and aging time. The models developed are used in conjunction with real time ambient temperature aging to derive Q10 factors for the material as defined in ASTM F1980.

ACCELERATED AGING OF POLY(P-PHENYLENE-2,6-BENZOBISOXAZOLE) FILAMENTS
Wolfgang Abele, Yukihito Ozaki, Takeshi Chiba, Kazunori Saegusa, May 2010

Poly(p-phenylene-2,6-benzobisoxazole) fiber is a high performance fiber. Unfortunately, the fiber reportedly degrades rapidly when exposed to moisture and heat. The objective was to perform accelerated aging of PBO filaments that would potentially lead to the development of an improved process to improve the mechanical properties of PBO fibers when exposed to moisture and heat. Results indicated the need to perform additional aging on rovings due to the large standard deviations of the filament data.

A NECESSARY STEP- SEPARATING THE SPECTRAL BANDPASS CORRECTION FROM TRISTIMULUS INTEGRATION
Hugh S. Fairman, Jack A. Ladson, May 2010

Current industry practices are examined with respect to the methods used for spectral bandpass correction. The variants in methodology are reviewed and the methods that will lead to every person knowing whether or not his spectra have been corrected are recommended. That will facilitate the user knowing what Tables are to be used to integrate the spectra. Methods of implementing the bandpass correction both algebraically and by matrix multiplication are related.







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