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The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
Mechanical, Thermal and Permeability Properties of PP / Oligopinene Blends
Luis C. Mendes, Fernanda C. Miranda, Anderson F. Ferreira, Fabiano M. Dias, M. Elizabeth F. Garcia, May 2002
Our interest of study is blending of polyolefins with oligomers from natural and synthetic sources. In this work we show the results on mechanical, thermal and permeability properties of polypropylene (PP) / Oligopinene systems from compression films about 10 microns which were prepared using quenching (liquid nitrogen) from the molten state and permeability was measured using CO2. The addition of oligopinene on PP changes stress-strain curve of the polyolefin. For all oligomer content no more yielding was observed and the elongation at break had an abrupt decrease at a concentration of 10% of oligomer. The thermal analysis revealed that the blend system has two glass transition temperatures. The permeability values changed slightly with the oligomer content in the blends.
Mechanical-Morphology Relationship of PS Foams
Martin N. Bureau, Richard Gendron, May 2002
The relationship between the morphology and the mechanical behavior of commercial PS foams has been investigated. The foams studied had a closed cell morphology with densities between 25 and 60 kg/m3 and number-average cell sizes between 75 and 230 ?m, and a normal cell size distribution (dv/dn ? 1.20). Mechanical results showed that the compressive strength and modulus could be expressed as a function of the foam morphology, using a unique morphological parameter taking into account the cell size and foam density. Flat sheet impact tests showed that three stages, i.e. initiation, propagation and collapse, could be identified in the impact behavior of the foams, which could be related to the morphological parameter proposed. A transition from a brittle to a ductile behavior could be rationalized using the proposed parameter.
Melt Flow Instability Studies of Metallocene Catalyzed LLDPE in Pelletizing Dies
Costas G. Gogos, Bainian Qian, David B. Todd, Thomas R. Veariel, May 2002
The capillary flow behavior of metallocene catalyzed LLDPE was studied in the melt flow instability region of the resin. Processing variables, as well as die materials of construction and geometric/design variables of the dies were explored. The extrudate performance variable that this study focused on was the detailed microscopic structures (topographies) of the extrudate surfaces, in order to obtain insights on the die-related origins of the melt instabilities involved. It was speculated that the surface melt fracture of extrudate was similar in nature to other mechanical fracture that is initiated from the formation of small cracks on the extrudate surface, caused by high wall shear stress with increasing flow rate and/or high elongation stress due to exit singularity (or velocity discontinuity). Cohesive failure creating peeling/tearing cracks observed can propagate and evolve into a well-organized structure, depending on the excess stress energy levels on the extrudate surface at the exit and cohesive strength of the polymer melt. Possible methods to mitigate the surface melt fracture in capillary dies were also suggested from the proposed fracture mechanism.
Melt Mixing Improves Hot Runner Balance and Improves Part Quality
Abdeslam Bouti, May 2002
One method of balancing multicavity molds is to restore the cross-sectional symmetry of the shear induced hot/cold lamination of the melt before a runner branch. While, this method has been used successfully with H pattern runners it's less compatible with molds including intersections with more than two branches. In this work it is demonstrated that melt homogenizing before critical runner intersections improves the balance of molds independently of their hot runner configuration. In addition, when a mixing nozzle is used to homogenize the melt before delivering it to the cavity, preferential cavity filling can be eliminated and more dimensionally stable parts can be produced with uniform microstructure and mechanical properties.
Melt Processability of Polyethylene with Long Chain Branches
Christopher G. Robertson, Srivatsan Srinivas, César A. García-Franco, May 2002
Linear viscoelastic results are presented for several polyethylenes which each exhibit, to varying degree, an increased zero shear viscosity (?0) relative to that observed for a linear polyethylene with the same weight average molecular weight (Mw). This is a well-recognized rheological signature of the presence of long chain branching (LCB). Examination of the small amplitude oscillatory shear data for the branched polyethylenes clearly reveals the presence of two separate relaxations. We examine the utility of considering these polyethylenes as blends of branched and linear species. A unique power-law behavior is observed for the dynamic viscosity in the intermediate frequency region bounded by the distinct relaxations of the linear and long chain branched components. Characterizing these rheological features appears to be a key element in formulating an understanding of the processability of polyethylenes which possess entangled branches.
Melt Processing of Polymers Using Supercritical Fluids
Siobhán O. Matthews, Kuldip S. Dhadda, Peter R. Hornsby, May 2002
In-line rheometry has been used to study the plasticising effect of sub and supercritical carbon dioxide during polymer melt processing. The extent of the plasticising effect has been investigated using model systems so that theoretical and actual viscosity reductions achieved could be compared. Results will be presented which demonstrate these effects.As a result of this research injection moulding and extrusion processes have been optimised for a selection of polymers and highly filled polymer compositions. This has led to enhanced manufacturing process efficiency and the manufacture of components with preferential foaming.
The Melting Behavior of Amorphous Polyester in a Co-Rotating Twin Screw Extruder
Bainian Qian, Costas G. Gogos, David B. Todd, May 2002
The melting behavior of an amorphous polyester in an intermeshing co-rotating twin screw extruder was examined. It was found that the melting of this low Tg amorphous polyester could happen even in the partially-filled conveying screw section without any kneading or reverse screw elements, if a preformed melt" was created. Barrel heating is more than providing the energy required for melting but to create a layer of "preformed melt". Once this "preformed melt" was created the melting could be sustained with the heaters of the barrel being shut off. The "preformed melt" seems catalytic to this VED (Viscous Energy Dissipation) dominant melting process might also be important to many other melting processes."
The Melting Behavior of Polyethylenes Synthesized with Ziegler-Natta and Constrained Geometry Catalysts
A. Neil Smith, Andrew Hrymak, Joseph Dooley, Mark A. Spalding, Kun Sup Hyun, May 2002
The melting flux and shear stress values during melting of five polyethylenes were measured using a Screw Simulator. Four materials were produced using constrained geometry catalyst Technology (CGCT), while the fifth was produced with a traditional Ziegler-Natta (ZN) catalyst. All of the materials have nearly the same melt index value, but the solid density of each material varied. The melting flux was measured over a range of sliding velocities, temperatures and pressures typical in single screw extrusion. Melting flux values for all materials increased with velocity, temperature and applied pressure. The materials produced with CGCT had a higher melting flux than the ZN material under the same experimental conditions, in all cases. Experimental data were compared to existing melting flux and shear stress models.
The Melting Characteristics of Polycarbonate Resins
Todd A. Hogan, Mark A. Spalding, K.S. Cho, Chan I. Chung, May 2002
Melting of a polymer inside a single-screw plasticating extruder is described by a dissipative melting mechanism of the solid bed rubbing on the barrel surface. Both the melting rate and the shear stress of a solid bed are expected to increase with decreasing melt index (i.e., with increasing viscosity). However, the melting rates of polystyrene (PS) in controlled Screw Simulator tests were found to decrease with decreasing melt index even though the shear stresses increased. Such unexpected results were reported previously (1).This paper will report the results of controlled Screw Simulator tests for polycarbonate (PC) resins with varying melt indices and also on the melting phenomena in single-screw plasticating extrusion experiments.
Melting Model for Co-Rotating Twin-Screw Extruders
P. Bleiman, M. Bulters, P. Elemans, H. Slot, May 2002
A comprehensive model describing the last stage of the melting process in co-rotating twin-screw extruders is proposed. At this stage, the melting is governed by viscous dissipation and heat transfer from the melt to the unmelted particles. The residence time in the melting section mainly determines the final melt temperature and the remaining fraction of unmelts.The effects of screw speed, polymer viscosity and particle size on the melting process are shown, leading to implications for the new high-speed, high-torque machines. The model is supported by experiments using a screw configuration in which the melting section is placed at the downstream end of the screw.
Melting of High-Heat Polyamide in a Co-Rotating Twin Screw Extruder
Jos M.H. Janssen, Wiebe R. Sierksma, May 2002
Experimental work is presented on the melting behavior of high-heat polyamide in co-rotating twin screw extruders. Screw designs were tested with different melting sections located near the exit of the extruder, to isolate the melting performance. A slit-die provided a melt ribbon that was drawn down for visualization of unmolten particles that together with melt temperature quantify melting performance. This method proved to be efficient in scanning an entire process window. Evident are effects of screw speed, degree of fill, screw configuration, and low melting additives. These experimental directions, along with model simulations are the basis to optimize compounding screws covering modern hi-speed, hi-torque process windows.
Melting Regimes in Modular Intermeshing Co-Rotating Twin Screw Extrusion: Effect of Barrel Temperature Screw Speed and Feed Rate
Hochul Jung, James L. White, May 2002
The melting of polyolefins in a modular co-rotating twin screw extruder was investigated as a function of (i) barrel temperature (ii) screw speed and (iii) feed rate. Carcasses of the melting region were removed from the twin screw extruder and sliced into sections.Our observations suggest three different mechanisms of melting; (i) Hot barrel induced melting, (ii) Screw surface induced melting, and (iii) Homogeneous bulk melting. The mechanism of (i) is favored by high barrel temperatures, the mechanism of (ii) by lower barrel temperatures and slower screw speeds, and the mechanism of (iii) by lower barrel temperatures and higher screw speeds.
Micro Molding - A New Way""
Jim Catanzaro, Bob Kadykowski, May 2002
Small parts less than one quarter of a pellet require a complete rethink by molding engineers and mold designers. Total part cost justification becomes more challenging based upon the amount of material wasted and tooling costs. Micro machinery is helping to meet the requirements of accuracy through simplicity. There is no need for complicated multiple profile closed-loop servo controlled injection and metering functions.The two-stage plunger over plunger injection unit is capable of processing basic polyolefins to high temperature LCP materials. Shot pot injection provides accuracy of volumetric control by eliminating variation caused by slider or check ring shutoff inconsistency. The minimum number of components used in the design achieves simplicity.
Microcellular Foaming of Polypropylene Containing Wood Fibre in an Injection Moulding Process
Andrzej K. Bledzki, Omar Faruk, May 2002
Microcellular foams of polypropylene containing wood fibres, cell sizes on the order of 10 to 50?m were produced in an injection moulding process. The relationships of processing/structure/property were investigated for wood fibre-thermoplastics composites foaming with a chemical blowing agent. Wood polypropylene composites (WPC) of different wood content (30%,40%,50% and 60% by weight) have been prepared using maleic anhydride-polypropylene copolymer (5% relative to the wood fibre content) as a coupling agent. Measurement of density, cell size, void content, tensile and flexural test of the prepared WPC were carried out. The shape and distribution of the voids were investigated by optical photo examination of longitudinal sections of specimens, using polishing technique and reflected light microscopy. Density of foamed composites decreased about 24%. The cell morphology and foam properties showed improvement when the coupling agent was added. Water absorption and scanning electron microscope of the composites also investigated.
Micro-Scale Extrusion for the Accelerated Development of New Polymeric Materials
Ronald J. Wroczynski, Radislav A. Potyrailo, Malgorzata Rubinsztajn, William P. Enlow, May 2002
Polymeric materials exhibit complex degradation mechanisms during their processing and end use. Rapid development of new polymer formulations requires new methods of processing. We have investigated increasing the throughput of such experiments by using a micro-scale (4.5-cm3 volume) twin-screw extruder. A method has been developed for evaluation of stabilizer performance that significantly reduces the amount of material and experimental time when compared to traditional methods. The method employs a micro-extruder and specific processing conditions. Validation of the method was performed on multiple polymer/additive combinations with different oxidative stabilities. The rank order of degradation of the materials in the micro-extruder correlates well (R2 = 0.982) with the results of multiple pass extrusions in traditional scale equipment.
Microstructure of Blow Molded Bottles from Polyolefin Nanocomposites Prepared by Melt Compounding
Han-Xiong Huang, You-Fa Huang, Chuan-Yang Wang, Shu-Lin Yang, Yong-Hua Zhang, Song Lu, May 2002
Polypropylene-organoclay and high density polyethylene-organoclay nanocomposite pellets were extruded by melt compounding using an industrial-scale co-rotating twin screw extruder. The as-extruded pellets were then made into bottles by using an industrial-scale single screw extrusion blow molding machine outfitted with a screw involving shearing sections. The microstructure of bottles as investigated by wide-angle X-ray diffraction and transmission electron microscopy exhibited partial exfoliation with minor regions containing locally exfoliated clay platelets and major regions of intercalated clay.
Miniaturized Sensor for the Measurement of Temperatures in a Mold Cavity
Martin Moneke, Joachim Amberg, Nils Holstein, Markus Guttmann, Klaus Seemann, Wilhelm Pfleging, May 2002
The prediction of shrinkage and warpage of injection molded parts, especially from semi-crystalline polymers, still poses a major problem to the polymer processing industry.Attempts have been made to incorporate crystallization kinetics into simulation programs. The heat released by crystallization in combination with the low heat conductivity of plastics strongly influences the temperature profile in the cavity and thereby the cooling and cycle times. This could be shown with a special apparatus, which has been developed recently, for the fast cooling of polymers in connection with computer simulations (1, 2).For the measurement of the temperature distribution in the mold cavity a miniaturized sensor has been developed. The sensor design and measured temperature profiles are presented here.
Mixing and Structure Development in 3D Chaotic Mixing Flows
P.D. Anderson, O.S. Galaktionov, G.W.M. Peters, H.E.H. Meijer, May 2002
This paper addresses mixing, interfacial area generation and structure developement in Kenics static mixers. A statistical description of the microstructure development is obtained using the extended mapping method. This method is adopted to the special flow conditions in spatially periodic flows, of which a static mixer is an example. The efficiency of the interface generation for different mixer layouts is compared and additional attention is given to the distribution of the interfacial area across the mixer. It is shown that the extended mapping method enables us to find the blade configuration that optimizes the mixing performance, in accordance to the standard mapping method, but now including much more details concerning the microstructure development in this chaotic flow.
Mixing Behavior of Model Miscible Polymer Systems Having Extremely Low Viscosity Ratio
Paul T. Shea, Robert D. Pietruski, Chi-Kai Shih, Donald A. Denelsbeck, May 2002
Hydrocarbon based oils can be used to plasticize styrenic block copolymers. At high levels (30%), the method of oil addition and the properties of the oils used will affect mixing time. This becomes very important in twin screw compounding processes where increased throughput reduces residence time (available mixing time). This paper describes the investigation of factors affecting mixing of several model polymer systems having a very low viscosity ratio (well below 0.001) using a batch internal mixer. Similar to the findings of Ratnagiri, Scott, Joung, Shih & Burch (1-5) on morphological development during mixing of immiscible and miscible polymers, we have observed Phase Inversion (PI) during mixing of miscible polymer systems of block copolymers with hydrocarbon oils (6). The time to reach high torque after addition of the hydrocarbon oil, i.e., the Phase Inversion (PI) time as defined by Ratnagiri and Scott (2), decreased with increasing viscosity and hydrocarbon oil molecular weight. It was shown that splitting of the oil addition could decrease total PI time. It was also shown that an unequal split, with the lowest amount first, led to the fastest PI times. This emphasized that a slight lowering of the major component viscosity with small additions of the plasticizing agent was the most advantageous process for decreasing total time for mixing. In addition, it was shown that part of a lower viscosity (or MW) oil could be substituted with a higher viscosity oil thereby reducing overall Phase Inversion time. Of course, it would be important that the substituted hydrocarbon oil be compatible in the final product.
Mixing in Extrusion - Parts One, General Considerations
Chris Rauwendaal, May 2002
Introduction Mixing is one of the important functions of a plasticating extruder. Other functions are solids conveying, melting (or plasticating), melt conveying, and, in vented extruders, degassing (or devolatilization). It is well recognized that mixing is important when different plastics are blended or when fillers are added to the plastic in an extruder. However, it is not widely understood that mixing is equally important when a single plastic is extruded. In this case mixing is necessary to achieve a thermally homogeneous melt at the end of the extruder. Plastics have very low thermal conductivity resulting in large differences in melt temperature in the absence efficient mixers along the extruder screw. When the extruder discharges a melt into the die with non-uniform temperatures the flow in the die and the extruded product quality will be adversely affected.


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