The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
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Dinorah M. Gómez, J. Ricardo Galindo, Rubén González-Núñez, Denis Rodrigue, May 2005
Low density polyethylene was blended with agave fibres of three sizes: 0.21, 0.81 and 1.11 mm. Fiber concentrations between 10 and 25% were used to produce composites using twin-screw extrusion and injection molding. To determine the effect of processing on mechanical properties, uniaxial traction and impact resistance were obtained, in relation with morphology and density. The results show that there is an optimum concentration and fibre length for each processing technique.
6 Sigma has been around for some time. It is being used to control products to decrease their defects. Here is how 6 Sigma can be used to design and sucessfully implement a Color Center of Excellence.
F. Gribben, G.M. McNally, W.R. Murphy, A.H. Clarke, May 2005
Blends of Nylon 6.6 with metallocene catalysed polyolefins have previously demonstrated phase separation and component immiscibility. This work investigates the effect of blend composition and of the addition of ethylene copolymer based physical and reactive compatibilisers on the rheological performance of these blends. The results demonstrate that the viscosity of the blends showed negative deviations from a simple log additivity rule but was dependent on both blend composition and compatibilisation.
High-performance phenolic composites are prepared by using both long fibers and nano-clays. First, Phenolicclay nanocomposites are synthesized by in-situ polymerization. Then, long carbon fibers are added into the phenolic nanocomposites to produce hybrid composites. Mechanical and thermal properties of such composites are compared with both long fiber-reinforced composites and polymer-layered silicate composites. The optimal conditions of sample preparation and processing are also investigated to achieve the best properties of the hybrid composites.
P. Sarazin, M.A. Huneault, W. Orts, B.D. Favis, May 2005
Blends of polylactide with thermoplastic starch are prepared using a one-step extrusion process. These materials, subsequently processed via injection molding, possess interesting properties. The tensile properties in these samples are related to the composition of the blends and also to the glycerol plasticizer content in the thermoplastic starch. These materials possess an advantage for the environment since they are fully biodegradable and are derived principally from renewable sources.
Reaction rates are not proportional to temperature, but instead follow Arrhenius behavior. Consequently, for systems with varying temperature, the “average temperature” is erroneous and should not be used. Instead, the easily calculated “mean-kinetic temperature”, should be used. The difference between these temperatures can be significant and failure to understand the differences can lead to catastrophic consequences. Specific examples of the calculations and the consequences are discussed.
Many processing parameters have an effect on the tensile strength of blown film. In this study a Taguchi L8 designed experiment was used as a screening design. This design allowed the determination of which processing parameters had the biggest effect on the tensile strength of blown film in both the machine and transverse directions. The processing parameters examined in this experiment were: materials, die temperature, take up roll speed, blower speed, air ring gap, extruder speed and air volume.
Q. Guo, D. Xu, S.S.Y. Chang, J. Wang, C.B. Park, R. Fenton, May 2005
This research investigated the bubble nucleation and life span phenomena occurring in chemical blowing agent (CBA)-based foaming of plastics under atmosphere and high pressure conditions. The behaviour of CBA-blown bubbles exposed to various pressure conditions was observed in a high pressure chamber using optical microscope-based digital image processing system. Critical experiments were conducted to explain the mechanisms of CBA-blown bubble nucleation.
It has been found that some thermoplastic systems survive accelerated UV weathering but fail in true environmental conditions. This is because quartz filters pass artificially high levels of 275 nm - 340 nm light, but artificially lower levels of longer wavelengths. For systems that are more reactive to longer wavelengths, the accelerated exposure tests provide false assurances of true weatherability. A specific example of this phenomenon occurring within polypropylene will be shown and discussed in detail.
Foaming of plastic/wood-fiber composites (PWC) with a fine-celled structure can offer benefits such as improved ductility and impact strength, lowered material cost, and lowered weight, which can improve their utility in many applications. This paper presents the critical issues in extrusion foaming of PWC and proposes processing techniques and strategies for producing artificial wood with enhanced properties.
R. Peila, S.S. Sangari, T. Karaki, J.C. Seferis, G. Parker, May 2005
Three types of modified organoclay were incorporated into VARTM resins at various concentrations. A Rheometric Dynamic Analyzer was used to analyze the flow behavior of the resins, while the morphology of the clay was examined by X-ray Diffraction (XRD) and Transmission Electron Microscope (TEM). It was found that the viscosity of the resins increased after the addition of the clays and the clays were exfoliated into the matrix.
Steven J. Grossman, Jeffrey T. Placker, Beth A. Filip, May 2005
Intellectual property law has had a number of somewhat remarkable changes in recent years. For example, the scope and enforceability of patents in the United States has been modified with respect to what might be considered an “equivalent” to a claimed invention. The role of judges and juries in ascertaining the scope of a patent has been dramatically altered. This paper will identify these new and important changes in the law of intellectual property and how such issues should be considered by the community of plastics engineers.
A common problem affecting all thermoplastic parts is shrinkage and warpage. With two-shot molding the parts will have two materials with different properties molding onto one another. Through a design of experiments (DOE) the cause and effect of changing different processing parameters along with part dimensions and materials, can be used to determine the amount of warpage on the part.
Off odor issues in packaging materials can have significant financial implications. Gas chromatography with a combination of detection techniques, olfactory (GC/O), and mass spectrometry (GC/MS) can help solve such problems. A general problem is the low detection limits afforded by the sense of smell versus the instrumental detection limits of GC/MS. Various methods of sample introduction that enhance the GC/MS response allowing identification of odor relevant compounds will be discussed.
Y.G. Li, H.B. Li, J. Wang, C.B. Park, H.S. Park, P. Chen, May 2005
The pressure-volume-temperature (PVT) property of polymer/gas mixtures is critically important in the polymer foaming process. Accurately measured volume swelling of polymer/gas solutions is not yet available. The objective of this paper is to propose a novel methodology for measuring the volume swelling accurately. The preliminary result using PP/N2 and accuracy verification using a known volume sphere will be presented.
The foamability of thermoplastic vulcanizate (TPV) has been investigated in a customized foaming system using carbon dioxide (CO2) and nitrogen (N2) as a physical blowing agent. TPV or dynamic vulcanizate is a special class of thermoplastic elastomer that is produced by mixing a crosslinked rubber and a thermoplastic simultaneously. The influence of blowing agent content and the processing conditions on the expansion behaviour, the cell-number density and the foam structure are discussed.
Denis Rodrigue, Slimane Souici, Eddy Twite-Kabamba, May 2005
It is usually reported that wood particles in wood/polymer composite foams can act as nucleating sites. Since high wood contents are used, it is difficult to determine exactly the effect of wood particles. In this study, LDPE was chemically foamed in a twin-screw extruder and small amounts of wood (0-5 phr) were added to determine their effect. Particle size was investigated using three mesh sizes: 45-61, 104-125 and 180-210 ?m. As expected, wood particles are acting as nucleating agents reducing substantially cell size and increasing cell density.
Venkata Giri Kolli, K. Jayaraman, M.D. Ellul, May 2005
The contributions of shear and elongation to the measured pressure drop in flow of polypropylene melts through semi-hyperboloidal dies have been investigated with and without external lubrication. This was done with a set of dies having a fixed ratio of inlet area to outlet area and three different lengths. The flow curves obtained without lubrication have been analyzed for the dependence on length. Two distinct terms have been identified that represent the shear contributions to the measured pressure drop in unlubricated flow.
Y.H. Lee, C.B. Park, K.H. Wang, M.H. Lee, May 2005
In order to investigate the effect of clay particles on the cell morphology of HDPE/clay nanocomposite foams, research on the batch foaming process of HDPE/clay nanocomposites using supercritical CO2 was conducted. Our study demonstrates that, in comparison with pure HDPE, nanocomposites produce much finer and more uniform cell structures. Additionally, an attempt to produce a nanocellular structure was successfully performed using HDPE/clay nanocomposites.
Natural crystalline graphite based graphite intercalated compounds [GICs] were exfoliated and milled into submicron graphite flakes. Graphite nanocomposites were fabricated with nylon 6 or nylon 66 resins. To examine the effectiveness of the exfoliated graphite as a reinforcement, composites with commercially available reinforcing materials were also fabricated and compared. The mechanical and electrical properties were investigated and exfoliated graphite showed comparable or better properties compared to the other reinforcing materials.
Any article that is cited in another manuscript or other work is required to use the correct reference style. Below is an example of the reference style for SPE articles:
Brown, H. L. and Jones, D. H. 2016, May.
"Insert title of paper here in quotes,"
ANTEC 2016 - Indianapolis, Indiana, USA May 23-25, 2016. [On-line].
Society of Plastics Engineers
Available: www.4spe.org.
Note: if there are more than three authors you may use the first author's name and et al. EG Brown, H. L. et al.
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