SPE Library

The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
A Characterization Of Soy Additives In Biobased Polyethylene Films
Peter Perez, May 2018
Four different soy additives were compounded into Linear Low Density Polyethylene (LLDPE). The four different additives were compounded and pelletized by FKuR. After a film was produced for each of the four batches, the mechanical, barrier, and thermal properties of each batch was characterized and compared to a control sample. The use of soy in polymeric films improved mechanical properties in LLDPE, reduced the cost and amount of plastic used, and improved water vapor barrier of the polymer. The modulus of each film increased with the use of filler. However, the ultimate extension and ultimate tensile strength decreased in the samples containing soy fillers. The films showed increased crystallinity in samples containing soy fillers. Additionally, thermal analysis indicated large amounts of weight loss in the soy loaded films when heated.
Mechanical Reinforcement With Cellulose Filaments
Helen Lentzakis, May 2018
Kruger Biomaterials proprietary cellulose FiloCell™ is obtained from peeling the filaments from wood fibres using a mechanical process that uses no chemicals or enzymes. Since the peeling is gentle, very thin filaments are obtained while the original length is preserved. The filaments are further surface treated without modification of the chemical structure in order to prevent hornification (agglomeration due to strong hydrogen bonds) and to produce 99.7% dried, re-dispersible filaments. The resulting filaments are renewable, non-toxic, have high surface area, high aspect ratio, mechanical strength and low density. Given these properties, cellulose filaments are a unique multifunctional lightweight filler which can be added to polymer resins as a reinforcing agent and can potentially replace glass fibers.In this work, cellulose filaments are melt-blended into thermoplastics LDPE, Nylon 6 and TPU. Cellulose filaments are shown to effectively increase the Young’s modulus and the strength of all polymer matrices. The mechanical enhancement is increased with loading level of cellulose filaments. It is shown that no compatibilizing agent is needed in order to improve the interaction between the hydrophilic filler and the hydrophobic matrix. Moreover, although one drawback of natural fiber is its thermal degradation at high processing temperature, we managed to successfully compound our cellulose filaments with nylon 6 which has a processing temperature of 230˚C. In LDPE resin, at the same weight, cellulose filaments outperform glass fibers in both tensile strength and tensile modulus. In comparison with other natural fibers, cellulose filaments have the advantage of higher mechanical performance and lower water absorption.
Modeling Doming Deflection Of Caps & Closures With Finite Element Method
Wenbo Xu, May 2018
As part of an effort to develop light weight closures for carbonated soft drinks (CSD), a finite element model has been developed to understand the impact of resin properties and closure design on the end product performance. Phase I of the model development is to understand the deformation mechanics as a precursor to light-weighting effort. The model simulates typical loading conditions in CSD closures and predicts the resultant stress & strain in the closure. The current study focuses on the doming deflection of CSD closures. Preliminary results are in excellent agreement with the experimental results. The FEA results and experimental data suggest that viscoelasticity of the resin i.e. high density polyethylene (HDPE) plays an important role in determining the long term performance of CSD closures. The current report introduces the key techniques applied in the model development and summarizes the results of the model and the validation experiments.
Yes, You Can Break Certain Design Rules And Still Have A Successful Product - A Logical Look At The Implications
Plastic parts are a lot less forgiving than their metal counterparts on the strict adherence to established design rules for meeting short and long-term performance requirements.These requirements can broadly be broken into:CosmeticsImpact strengthToughnessChemical resistanceTolerance precisionHigh and low-temperature use and cyclingOutdoor exposureCostThus, a much more rigorous adherence to the rules may be required for a high-end handheld, mission-critical computing and communicating device in a hospital that needs to be cosmetically appealing, have very high impact strength, good chemical resistance and high and low-temperature resistance. A failure due to design errors in a simple drop on a device like this in the hand of a medical technician may cause death!On the other hand, a minor blemish or crack in a lightweight remote control for a low-end TV may not nearly be as catastrophic.The base cover of an inexpensive, lightweight inkjet printer may be even more forgiving.To be realistic, design rules may have to be broken based on the end use and other conflicting product requirements.This paper will provide a logical guide on making exceptions to the design rules based on multiple case studies.It will also introduce a design checking software, DFMPro where the rigorousness of the design rules can be “dialed” in based on the specific product requirements
Influence Of Thermal Treatment On The Mechanical Properties Of Thermoplastic Composites Obtained By Large-Format 3D Printing Process
Miguel A. Hidalgo Salazar, May 2018
The process of large-format 3D printing is gaining popularity because larger pieces can be obtained in comparison to the conventional 3D printing process, being a promising alternative for products design and development due to the incorporation of innovative raw materials as biocomposites for large scale manufacturing. In this work, tensile test specimens were 3D-printed by large-format process and different commercial material used in conventional 3D printing. As-printed specimens and annealed specimens were subjected to tensile testing. DSC and TGA were used to optimize the printing process and annealing conditions of the samples. It was observed that the annealing process had a different effects on the properties depending on the materials studied.
Design For Manufacturability – 3D-CAD Design Methodology For Spiral Milled Polymer Processing Tools
Phil Hungenberg, May 2018
3D-CAD systems show limitations with regard to the design process of helical milled parts. This paper introduces a surface based design methodology, which enables the designer to bypass these restrictions. Additionally, an approach to facilitate an early knowledge transfer between production planning and design department is shown and implemented through the use of knowledge based engineering methods. Thereby a virtual product model is generated that represents the exact work piece geometry and contains specific manufacturing information while meeting the functional requirements of spiral mandrel dies and thus impacting the whole process chain positively. Furthermore, a method to optimize certain sections of the flow channel which show subpar flow properties is introduced.
Polypropylene/ Polyvinylidene fluoride Fibrous Water/Fuel Filters Produced by a Unique Multilayer Co-Extrusion Process
Cong Zhang, May 2018
A unique co-extrusion and multiplication technique combined with a water jet fiber separation process was utilized to manufacture nano/micro-fibrous filters for applications in fuel/water separation. Hydrophobic polypropylene/polyvinylidene fluoride (PP/PVDF) dual-component fibrous filters were produced having different fiber size. The filter pore size was found to decrease with decreasing fiber size and the surface area was found to increase with increasing fiber size. The filter having the smallest pore size exhibits the highest filtration efficiency as 93.5%. Corona treatment was conducted on the PP/PVDF fibrous filter to evaluate hydrophilicity influence on water separation. It is found that moderate hydrophilicity improves the water separation efficiency.
Utilizing Should Costs To Engage Millennials In The Workplace
Laurel Bougie, May 2018
The gap of skilled workers in manufacturing is expected to grow to two million workers by 2025 and millennials will make up 75% of the current workforce. Without focusing on the shortage the industry as a whole will face, there is a looming challenge many of us are already facing today, how do we attract and retain the millennial talent we already have?Forbes has noted that the number one reason millennials leave their current role is lacking a sense of purpose in their work. Deloitte has gone so far as to coin the term “purpose gap.” Millennials are not satisfied with the excuse of “that’s how it’s always been done” and have begun pushing back on inefficiencies within the workplace and asking for transparency. In this session, you will learn how the implementation of aPriori’s should costing tool can bring purpose back to your design engineers, cost estimators, and procurement teams. This tool provides real-time feedback and provides transparency surrounding part costs that allows millennials to make data driven decisions surrounding cost throughout the product life cycle and translate the impact of their contributions to the overarching company initiatives. aPriori’s Cost Insight Business analytics tool also allows for the slicing and dicing of should cost data to support business decisions and provides an overarching product cost management solution that will re-engage your millennials so you can focus on pipeline talent for 2025, not immediate back fills.
The Strategic Value Of Designing For Cost
Laurel Bougie, May 2018
Today, manufacturers are being pressured at every angle regarding cost. Customers are asking to pay less for a product, supply chains are asking to be paid more, and stakeholders are asking for a higher margin leading some manufacturers to scratch their heads and say, where do I start?Many of the challenges today stem from lack of visibility surrounding cost drivers when designing a product leading engineers to have little or no insight on the impact design changes have on overall product cost. This lack of visibility often causes late stage engineering churn as completed products exceed target costs and manufacturers are faced with a difficult decision, miss a product launch date or release a product with minimal (or no) margin.aPriori’s Design to Cost solution helps design teams identify and eliminate cost drivers early in the design process, preventing a cycle of churn throughout the organization, causing lost revenue and lost productivity.In this session, you will learn how early visibility to cost drivers will reduce churn and rework throughout your organization and how aPriori uses specific software features to provide design guidance based on cost, encouraging engineers to make cost effective decisions and removing cost related surprises at the conclusion of any project.
Technical Evaluation Of Loctite HY4060GY: The Ideal Replacement For Traditional 2K 5-Minute Epoxies
Matthew Miner, May 2018
Loctite® HY 4060GY™ is a 1:1 two component cyanoacrylate – epoxy hybrid adhesive which makes up part of the new range of Loctite® universal structural bonders launched in March 2017. These innovative products are powered by a patented hybrid technology that combines the most critical attributes of cyanoacrylate and structural adhesives. Loctite® HY 4060GY™ offers durable properties with fast time to develop handling strength in a 25 ml ‘ready to use’ pack with integrated plunger making it an ideal replacement for traditional 2K 5-minute epoxies. This paper presents the performance of Loctite® HY 4060GY™ against a number of Henkel and competitor 2K epoxy adhesives.
Quasi-Static, Non-Linear, Explicit Finite Element Analysis Of Small Pet Bottles
Naser Imran Hossain, May 2018
Packaging design must be a forethought when producing ecofriendly packaging in the water bottling industry. Bottle design research is often restricted by mold production delays and long lead time on physical prototyping. A simulation based approach, or virtual prototyping can create an effective bridge between concept and production phases of the process with a relatively short lead time. This study explores a Quasi-Static Finite Element Approach with non-linear approximations to model water packaging. The study also shows how top-load is used as a metric of structural performance for small PET bottles. The material parameters are based on Polyethylene Terephthalate (PET), the material of choice in the bottling industry.
Quality Monitoring Of Rotational Molded Parts Using A Nondestructive Technique
Felipe Gomes, May 2018
Achieving optimal quality for rotational molded parts requires a determination of specific conditions for oven temperature and heat/cool time. Traditional tests used to assess the quality of these samples rely on destructive methods, such as impact testing. This paper presents an innovative approach using ultrasonic testing associated with multivariate statistical modeling to evaluate the quality of molded polyethylene (PE) parts from several different batches. Results showed a good correlation of predicted quality using non-destructive data with both impact energy failure and melt flow index, indicating the potential of this technique to be applied on the quality monitoring of this process.
Rotational Molding Of Hybrid Composites Based On Linear Low Density Polyethylene/Ground Tire Rubber/Maple Wood Fibers
Denis Rodrigue, May 2018
In this work, ground tire rubber (GTR) and maple wood fibers (MWF) were dry-blended with linear low density polyethylene (LLDPE) to produce hybrid composites by rotational molding. In particular, the effect of a coupling agent (maleated polyethylene, MAPE) was studied to modify the mechanical properties of these hybrid composites. Each compound was characterized in terms of morphology, density and mechanical properties (tensile, flexural and impact). The results showed that the addition of GTR leads to limited impact strength improvement of the wood fiber composites (WFC), while MAPE addition improved the interfacial adhesion between the fibers and the matrix.
Mechanical Characterization Of Polyethylene/Carbon Nanofiber Composites Prepared By Rotational Molding
Milton Vazquez Lepe, May 2018
Nanocomposites of linear medium density polyethylene (LMDPE) and carbon nanofibers (CNFs) treated with oxygen cold plasma were prepared by rotational molding, mixing 0.01, 0.1 and 1% wt. of CNFs by dry-blending. The objective of this work is to study the influence, the change in surface chemistry and morphology in the carbon nanofibers. And thus, the effect on morphology and mechanical properties of this nanocomposites. The results indicated that the plasma technique increases the oxygen functional groups in CNFs. For the nanocomposites, the addition of CNFs modifies the mechanical properties, and major changes occur when were added CNFs treated with cold oxygen plasma.
Morphology And Mechanical Properties Of Poly(Lactic Acid)/Polyethylene Blends Produced By Rotational Molding
Eduardo Ruiz Silva, May 2018
Blends of poly(lactic acid) (PLA) and linear medium density polyethylene (LMDPE) at different weight ratios were prepared by rotational molding using a laboratory scale biaxial machine. The blends were previously produced by two different methods: i) dry blending using a high shear mixer and ii) melt blending with a twin-screw extruder. The prepared blends were characterized in terms of morphology, mechanical (tensile, flexion and impact) and thermal (DSC) properties. The morphological results showed a clear incompatibility between the two polymers in which the domains of the minor phase have well defined spherical shapes and a broad size distribution. On the other hand, the results of the mechanical properties depend of the blend preparation method. In general, blends prepared with melt blending presented a slight increase in flexural and tensile properties compared with those blends prepared via dry blending. For impact (charpy) mechanical properties, it was seen an increase until a maximum value was attained, after which the value decreased.
Optimization Of The Rotational Molding Processing Of Agave Fiber / Lmdpe Composite Materials
Rosa Gabriela López Gonzaleznúñez, May 2018
In this work, agave fiber (20% wt) / LMDPE composites were processed by rotational molding with a commercial antioxidant type and UV stabilizer polyolefin additive in order to determine its influence on the process cycle. The aim was to reduce the processing temperature to ensure non-degradation of the agave fiber. The samples were mechanically characterized by impact, bending and traction tests. The results show that a biocomposite piece without imperfections can be obtained at a Peak Internal Air Temperature (PIAT) of 210ºC, which represents a reduction of the process cycle to obtain a piece with the same characteristics without additive, besides, the mechanical properties were not significantly affected
3-Dimensional Characterization Of The Quality Of Foam-To-Skin Bonding Of Rapid Rotationally Foam Molded Integral-Skin Cellular Composites
. UTKARSH, May 2018
Rapid Rotational Foam Molding (RRFM) was used to manufacture integral-skin composites consisting of various combinations of polyethylene (PE) and polypropylene (PP) skins that are completely surrounding respective foamed cores made of PE and PP by implementing a suitable chemical blowing agent (CBA) in extrusion. This paper presents the results of implementing a comprehensive 3-dimensional (3-D) characterization technique for evaluating the quality of the obtained foam-to-skin inter-facial bond of such RRFM composites. As the internal cellular structure and bonding depends on different polymer material properties and processing conditions, a 3-D model was developed to map the region of bubble-into-skin penetration, using a micro CT scanner. The experimental results revealed that the reconstructed 3-D model of LLDPE skin has the best bond quality and cell penetration into the skin with porosity of 74.6%.
Surface Treatment Of Agave Fibers And Its Compatibilization With Pla To Produce Rotational Molded Biocomposites
Jorge Robledo-Ortíz, May 2018
The aim of this work was to evaluate the effect of surface treating agave fibers on the compatibility of PLA-agave biocomposites produced by rotational molding. The agave fibers were treated by immersion in a solution of maleic anhydride grafted PLA (MAPLA). The treatment effect on the physical and mechanical properties was investigated at different fiber loads (10, 20, 30 wt.%). The improved compatibility due to the grafting of PLA chains onto the fiber led to enhanced mechanical properties in comparison with untreated fiber biocomposites as a result of an effective stress transfer. In particular, tensile strength increased from 25 to 41 MPa and modulus from 1.30 to 1.74 GPa at 20 wt.%. It was possible to observe lower water diffusion coefficients indicating that grafting MAPLA decreases the fiber hydrophilicity and promotes better fiber wetting.
New Generation Flame Retardants Based In Ionic Liquids
Yanjie "Jeff" Xu, May 2018
Ionic liquids — salts in a liquid state at ambient conditions — make up a fascinating family of materials whose unique physical properties have made them highly sought after for many challenging applications. Inovia Materials LLC is the first company in the world to patent and commercialize ionic liquids for polymer additive applications. Inovia Materials LLC is positioned to replace and expand the applications of traditional flame retardants with high “green chemistry” qualities, superior performance and enhanced properties. Some advantageous features include:• Negligible volatility and a benign environmental presence;• Better flame retarding performance and longer period of effectiveness;• Milder effects on thermal, mechanical, optical properties of polymers treated;• Significant reduction of polymer melt viscosity, allowing polymers to be processed or recycled at a lower temperature and in a more efficient manner.Inovia flame retardants can find applications in plastics, textiles, and elastomers in the building & construction, electronics & appliances, automotive & transportation, wires & cables, textiles, and other end-use industries.Inovia flame retardants can be applied using different methods:• Mixing with monomers or oligomers before polymerization• Compounding with plastics• Surface modification and coating application
Novel Applications Of Beta Nucleated Polypropylene In Film, Thermoforming, And Injection Molding Applications
philip jacoby, May 2018
Polypropylene can exist in three different crystal forms known as the alpha, beta, and gamma forms, and the alpha form is the most common. The beta crystalline form can be produced in molded and extruded PP parts via the addition of certain nucleating agents. The beta crystal phase can be used to produce some very unique PP products, as well as improve the properties and lower the cost in a wide range of applications. Mayzo has developed a very high activity beta nucleant that is offered in the form of a masterbatch. The converter can add this masterbatch at the extruder hopper in order to create products that exploit these benefits. In this presentation we will examine the ways in which beta nucleation is used today to produce microporous breathable films used in electronics, protective apparel, and construction applications. We will also discuss some new novel applications of breathable PP films. The use of beta nucleation to improve the thermoformability of PP leading to lighter weight and less expensive containers will also be discussed. Finally we will examine how beta nucleation is used to improve the toughness of molded PP parts, and also see how the heat seal strength of PP can be improved without the use of low-melting random copolymers.

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