SPE Library


The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings

Micro-Injection Molding of Medical Products: Machine Specification and Process Simulation
Thomas A. Shepard, Douglas Dunn, May 2002

Advances in surgical techniques and the drive toward surgeries, which are minimally invasive, has produced a surge in the need and design of small or micro-sized products. Therefore, while considerations regarding the machine, mold design and fabrication, part design, and polymer processing should be used to produce acceptable parts, of any size, one must consider systemic changes in each area when producing smaller parts. In order to take full advantage of the cavity details an optimized system must be defined and the machine must be able to perform.

Micro-Scale Extrusion for the Accelerated Development of New Polymeric Materials
Ronald J. Wroczynski, Radislav A. Potyrailo, Malgorzata Rubinsztajn, William P. Enlow, May 2002

Polymeric materials exhibit complex degradation mechanisms during their processing and end use. Rapid development of new polymer formulations requires new methods of processing. We have investigated increasing the throughput of such experiments by using a micro-scale (4.5-cm3 volume) twin-screw extruder. A method has been developed for evaluation of stabilizer performance that significantly reduces the amount of material and experimental time when compared to traditional methods. The method employs a micro-extruder and specific processing conditions. Validation of the method was performed on multiple polymer/additive combinations with different oxidative stabilities. The rank order of degradation of the materials in the micro-extruder correlates well (R2 = 0.982) with the results of multiple pass extrusions in traditional scale equipment.

Microstructure of Blow Molded Bottles from Polyolefin Nanocomposites Prepared by Melt Compounding
Han-Xiong Huang, You-Fa Huang, Chuan-Yang Wang, Shu-Lin Yang, Yong-Hua Zhang, Song Lu, May 2002

Polypropylene-organoclay and high density polyethylene-organoclay nanocomposite pellets were extruded by melt compounding using an industrial-scale co-rotating twin screw extruder. The as-extruded pellets were then made into bottles by using an industrial-scale single screw extrusion blow molding machine outfitted with a screw involving shearing sections. The microstructure of bottles as investigated by wide-angle X-ray diffraction and transmission electron microscopy exhibited partial exfoliation with minor regions containing locally exfoliated clay platelets and major regions of intercalated clay.

Micro-Tensile Testing Method and Sample Preparation for Small Samples
Rachel M. Thurston, May 2002

Traditional tensile testing methods use relatively large dogbone samples. Recent work at Battelle required testing of weld-line strength in irregularly-shaped polyethylene samples. The small sample dimensions made it impossible to machine dogbones. A method was developed for preparing thin, rectangular samples by microtoming. Samples were approximately 200 micrometers thick, which is much thicker than produced by normal microtoming methods. However, this size was well-suited to tensile testing. Tensile testing of samples with no weld line produced results similar to those quoted by the resin manufacturer.

Miniaturized Sensor for the Measurement of Temperatures in a Mold Cavity
Martin Moneke, Joachim Amberg, Nils Holstein, Markus Guttmann, Klaus Seemann, Wilhelm Pfleging, May 2002

The prediction of shrinkage and warpage of injection molded parts, especially from semi-crystalline polymers, still poses a major problem to the polymer processing industry.Attempts have been made to incorporate crystallization kinetics into simulation programs. The heat released by crystallization in combination with the low heat conductivity of plastics strongly influences the temperature profile in the cavity and thereby the cooling and cycle times. This could be shown with a special apparatus, which has been developed recently, for the fast cooling of polymers in connection with computer simulations (1, 2).For the measurement of the temperature distribution in the mold cavity a miniaturized sensor has been developed. The sensor design and measured temperature profiles are presented here.

Mixing and Stabilization Effects on Mechanical Properties of Poly(Vinyl Chloride)/Layered Silicate Nanocomposites
L.A. Hinojosa-Falcon, L.A. Goettler, May 2002

Poly(vinyl chloride) (PVC) nanocomposites were prepared by melt compounding of treated montmorillonite into a plasticized PVC matrix. Experimental results show how notable improvement in the mechanical properties of the PVC nanocomposites are keyed both to reinforcement parameters and to stabilization. The increase in elastic modulus, which would be valuable for extruded profiles, depends on the amount and type of organoclays, plasticizer, and stabilizer contained in the mixture as well as the time and temperature of mixing.

Mixing and Structure Development in 3D Chaotic Mixing Flows
P.D. Anderson, O.S. Galaktionov, G.W.M. Peters, H.E.H. Meijer, May 2002

This paper addresses mixing, interfacial area generation and structure developement in Kenics static mixers. A statistical description of the microstructure development is obtained using the extended mapping method. This method is adopted to the special flow conditions in spatially periodic flows, of which a static mixer is an example. The efficiency of the interface generation for different mixer layouts is compared and additional attention is given to the distribution of the interfacial area across the mixer. It is shown that the extended mapping method enables us to find the blade configuration that optimizes the mixing performance, in accordance to the standard mapping method, but now including much more details concerning the microstructure development in this chaotic flow.

Mixing and Surfactant Degradation in Nanocomposite Preparation
Changchun Zeng, L. James Lee, May 2002

Nanocomposites with different clay dispersions were prepared via in-situ polymerization and melt intercalation, with and without CO2, and the structure was observed by X-ray diffraction (XRD) and transmission electron microscope (TEM). The effects of clay dispersion, concentration and processing conditions on nanocomposite morphology, fire resistance, and thermal stability were studied. The thermal stability of the surfactant and the dispersion of the clay affect the fire resistance of the nanocomposites. Dispersion of the clay also affects the thermal stability of the nanocomposite.

Mixing Behavior of Model Miscible Polymer Systems Having Extremely Low Viscosity Ratio
Paul T. Shea, Robert D. Pietruski, Chi-Kai Shih, Donald A. Denelsbeck, May 2002

Hydrocarbon based oils can be used to plasticize styrenic block copolymers. At high levels (30%), the method of oil addition and the properties of the oils used will affect mixing time. This becomes very important in twin screw compounding processes where increased throughput reduces residence time (available mixing time). This paper describes the investigation of factors affecting mixing of several model polymer systems having a very low viscosity ratio (well below 0.001) using a batch internal mixer. Similar to the findings of Ratnagiri, Scott, Joung, Shih & Burch (1-5) on morphological development during mixing of immiscible and miscible polymers, we have observed Phase Inversion (PI) during mixing of miscible polymer systems of block copolymers with hydrocarbon oils (6). The time to reach high torque after addition of the hydrocarbon oil, i.e., the Phase Inversion (PI) time as defined by Ratnagiri and Scott (2), decreased with increasing viscosity and hydrocarbon oil molecular weight. It was shown that splitting of the oil addition could decrease total PI time. It was also shown that an unequal split, with the lowest amount first, led to the fastest PI times. This emphasized that a slight lowering of the major component viscosity with small additions of the plasticizing agent was the most advantageous process for decreasing total time for mixing. In addition, it was shown that part of a lower viscosity (or MW) oil could be substituted with a higher viscosity oil thereby reducing overall Phase Inversion time. Of course, it would be important that the substituted hydrocarbon oil be compatible in the final product.

Mixing in Extrusion - Parts One, General Considerations
Chris Rauwendaal, May 2002

Introduction Mixing is one of the important functions of a plasticating extruder. Other functions are solids conveying, melting (or plasticating), melt conveying, and, in vented extruders, degassing (or devolatilization). It is well recognized that mixing is important when different plastics are blended or when fillers are added to the plastic in an extruder. However, it is not widely understood that mixing is equally important when a single plastic is extruded. In this case mixing is necessary to achieve a thermally homogeneous melt at the end of the extruder. Plastics have very low thermal conductivity resulting in large differences in melt temperature in the absence efficient mixers along the extruder screw. When the extruder discharges a melt into the die with non-uniform temperatures the flow in the die and the extruded product quality will be adversely affected.

Model of Isothermic Laser-Sintering
E. Schmachtenberg, T. Seul, May 2002

In the product development of plastic components, increasing use is made of laser-sintering (LS) processes [1, 2, 3, 4]. To improve properties of prototypes, the main goals of development are reproducible density, to maintain edge sharpness, and to prevent uncontrolled shrink-age. Today, R+D mainly focuses on laser-technology, development of scan strategies, and LS process optimization.Another approach to make LS even more effective for product development is to identify the most important material properties of possible raw materials (polymer powder). The knowledge of significant material proper-ties could be an important tool for the choice of the correct material as well as for the development of new raw materials (structure- and chemistry synthesis).Thus, the current research of our group summarized in this paper mainly focuses on formulating requirements for LS raw materials [5]. Therefore, the theoretic model of isothermic laser-sintering was developed. Based upon this model it can be shown that the most important requirements for raw materials refer to crystallization and melting behavior as well as surface tension and melt viscosity.

Model Studies in Enzyme Catalyzed Transesterification Reactions
Anil Mahapatro, Bhanu Kalra, Ajay Kumar, Richard A. Gross, May 2002

Lipases are now known to also function as polyester synthases. In a previous report, we showed the ability of Lipase B from Candida antartica (Novozyme-435) to catalyze transesterification reactions between preformed polymer chains. To further study the kinetics and mechanism of these reactions, model reactions were performed using benzyl alcohol as the nucleophile and various aliphatic polyesters as substrates. Effects of the reaction temperature, time, nucleophile concentration, and the structure of the polymeric substrates on the rate of transesterification are reported. We also report the extent that these transesterification reactions occur with selectivity with respect to the site on chains that is cleaved.

Model-Based Control of Material Distribution in Thermoformed Parts
R. DiRaddo, P. Girard, S. Chang, May 2002

The thermoforming industry has achieved a good understanding of the process, which has been in large scale operation since the 1950's. Consequently, control of machine settings such as heater band temperatures, plug position, plug and mould temperatures is quite advanced. However, to date, little work has been done to address the control of state parameters describing material behaviour during processing, such as sheet temperature and material distribution in the part. Control of state parameters is essential as material property changes, environmental factors and machine operating drifts can significantly change the dynamic operating point of the machine.

Modeling of the Temperature Profile in Film Coextrusion
Jean-Pierre Puaux, May 2002

The question of temperature in film coextrusion is an important issue for the quality of the product. Since a direct measure of the temperatures in the melt is difficult, the modeling gives the values of the local temperatures, and the velocity profile as well. Important is the determination of the temperature at the interfaces of the layers, since this allows to compute the viscosities and the stresses at the interfaces. The ratio of the stresses is important in order to predict if the flow is stable, and to avoid instabilities. The knowledge of the temperature makes possible to avoid local overheating. We present a software running on a PC, a good tool to predict local peaks of temperature.

Modeling Peroxide Crosslinking in Polyolefins
Robert T. Johnston, May 2002

By combining sol-gel analysis and curemeter testing with a Monte Carlo simulation, the 160°C dicumyl peroxide initiation efficiency and scission/crosslinking ratio of a metallocene catalyzed ethylene 1-octene elastomer was determined to be 48% and 0.24, respectively. Using a calibrated simulation analysis, the network structural evolution during crosslinking was determined. Commonly used methods of curemeter interpretation were found to be severely flawed due to the combined effects of nonlinear evolution of elastically active chains, trapped entanglements, and slowly relaxing chain structures. A framework for correct interpretation of cure behavior is described.

Modeling Stress-Strain of Glassy Polymers up to Yield
Jonathan Moore, Mike Mazor, Scott Mudrich, Jozef Bicerano, Alexander Patashinski, Mark Ratner, May 2002

Based on a picture of a polymeric glass as a mosaic of nanoscale clusters of differing viscoelastic characteristics, we propose a new model for glassy polymers that accurately captures the stress-strain dependence at different rates and temperatures from small strain up to yield for polycarbonate. The model allows one to interpolate and extrapolate limited experimental data (it requires three stress-strain curves as input). The model also provides insight into the fundamental issue of glassformer fragility" in the glassy state and a practical means to assess dynamic inhomogeneities within polymeric glasses."

Modeling the Temperature Variation of Intrinsic Viscosity Using a Temperature Dependent Scaling Exponent
Lindsey Barrick, Veronica Cenci, Sathish K. Sukumaran, Gregory Beaucage, May 2002

Intrinsic Viscosity measurements are usually analyzed using the empirical Mark-Howink-Sakurada equation, which gives a power-law dependence of the intrinsic viscosity to the molecular weight of the polymer. Variation of the scaling exponent, a" with temperature is only poorly understood necessitating individual measurements at each temperature for every polymer/solvent system. The temperature dependence of "a" is shown to fall on a single universal curve under appropriate rescaling of the temperature of the solution. A method to obtain "a" from the static exponent is also described."

Modern Analytical Methods for Solvent Dyes Quality Control
Alex Shakhnovich, James Barren, May 2002

By application of UV-VIS spectroscopy, chromatography and some other analytical techniques new global tests and specifications for major solvent dyes have been created and validated at GE Plastics. One specification currently covers 15 dyestuffs and any number of new dyes can be added.The new testing protocols considerably speed up the QC of incoming raw materials and allow informative feedback to the supplier in case of quality issues.Rapid screening results correlate very well with color/strength data obtained in plastic testing, often making the traditional extrude-mold-test sequence unnecessary

Modification of High Flow Polypropylene by Ethylene/a-Olefin Elastomers Produced by Single Site Constrained Geometry Catalyst
M.K. Laughner, E.R. Feig, J.J. Gathers, May 2002

The recent advent and commercialization of technology using single site, constrained geometry catalyst has made possible the introduction of unique ethylene/a-olefin elastomers with novel molecular architecture. These advances in elastomer technology have resulted in differentiated materials capable of impact modifying polypropylene polymers thereby offering new TPO blends with enhanced properties. This paper will explore high flow polypropylene blends modified with this distinct class of elastomers and will discuss the influence of elastomer comonomer choice, molecular weight and crystallinity along with discussions on the effect of dispersion, morphology and rheology.

Modification of Nylon-6,6 through Solid-State Polymerization in Supercritical CO2
Costas Tzoganakis, Minhee Lee, Aristotelis Karagiannis, May 2002

The solid-state polymerization of nylon-6,6 has been studied in the presence of supercritical (SC) carbon dioxide (CO2 ) in a small autoclave. Experiments have been carried out under varying pressure and temperature conditions at several reaction times. In addition, experiments have been performed in the presence of nitrogen (N2) which is commonly used in commercial solid-state polymerization processes. The results indicate that the samples produced in the presence of CO2 have higher molecular weight and viscosity compared to those produced in the presence of N2 under the same reaction conditions. Furthermore, the polyamides produced in SC-CO2 have higher end group differences.










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