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The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
Very High Molecular Weight Polyethylene Obtained through Heterogeneous Cp2ZrCl2 on Aluminas
Moacir de Alcantara, Maria F.V. Marques, May 2001
The heterogenization of Cp2ZrCl2 on different aluminas, under distinct thermal and chemical pre-treatments, produced PEs of very high Mw. Some polymerizations achieved high activities, compared to the homogeneous catalyst. The aluminas owned distinct surface properties. and their different themml pre-treaUnents showed great influence on the supported catalyst activities. Methylalmninoxane (MAO), trinlethvlaluminimn (TMA) mad another cheaper agent were utilized as chenfical pre-treatments on the calcined aluntinas. Their activities were compared. The cheaper agent showed an excellent catalyst activitv.
Polyethylene Produced by Polymer-Supported Cp2ZrCl2/TIBA/MAO Catalyst System
Patricia Aragão do C. Junior, Renata Barbosa M. Costa, Fernanda M.B. Coutinho, Grupo de Polímeros, May 2001
Heterogeneous metallocene catalyst systems have been developed in order to be employed in industrial plants of polyolefins producing with conventional Ziegler-Natta catalyst systems. In this work polyethylene was synthesized using Cp2ZrCl2 catalyst system based on pretreated organic supports employing triisobutylaluminum (TIBA) as impurities scavenger and methylaluminoxane (MAO) as external cocatalyst. The heterogenization of the catalyst caused no significant effect on polymers characteristics. However a slight tendency of increasing on molecular weight and polydispersity was observed.
Development of a Notebook PC Housing by Using MMSH (Momentary Mold Surface Heating) Process
Dong-Hak Kim, Myung-Ho Kang, Young Ho Chun, May 2001
MmSH (Momentary Mold Surface Heating) process is an invention that heats only the mold surface over 400°C in few seconds with gas flame and cool it down very quickly again[1,2]. Practically it was tried to produce a shiny surface of 98% light reflecting of notebook PC housing of 20% glass fiber reinforced Polycarbonate. In addition to the outstanding surface quality, physical properties such as falling dart impact strength and heat resistance were improved. And it was carried out successfully with simple attached equipment and specially designed MmSH Mold which is to supply the gas fuel and air between the two parts of mold. The results of injection-molded notebook PC housing with MmSH Process will be discussed in this paper.
The Effect of TiO2 Pigment Particle Size and Masterbatch Rheology on the Dispersion Performance of TiO2 Pigment within the Polyethylene Blown Film Process
G.P. Milligan, G.M. McNally, W.R. Murphy, M. Leathem, May 2001
During the extrusion of pigmented blown film products, film quality can sometimes be affected by inadequate pigment dispersion and in some cases excessive melt build-up around the die lips during extended production runs. These problems are particularly evident during the extrusion of white (TiO2) pigmented films. The rheological characteristics of a range of commercially available titanium dioxide based masterbatches, with different polyethylene carrier polymer melt flow indices, were investigated using a dual capillary rheometer over the temperature range of 190°C to 230°C. Scanning electron microscope studies were performed on the individual masterbatches to determine pigment particle size and the degree of pigment agglomeration. Blown film extrusion trials, using a Killion blown film line, were carried out to determine film quality. The results showed that the masterbatches containing relatively large individual particle size caused more difficulties during film extrusion. Rheological analysis showed that the pigment masterbatch with the higher shear viscosities gave improved pigment dispersion in the film, and improved agglomerate breakdown during the extrusion process.
Revolutionizing Runner Designs in Hot & Cold Runner Molds
John P. Beaumont, May 2001
A next generation runner design is proving to yield unprecedented consistency in multi-cavity molds as well as providing new process aids which can control distribution of melt conditions in a cavity. This paper explains how variations in melt conditions are created in cold and hot runner molds and how they impact Cpk, productivity and molded product characteristics. These variations are rarely understood or appreciated, yet are possibly the most significant influencing factors in the successful production of injection molded products today. A next generation runner is revealed which provides the performance of a small cavitation mold, improves product consistency, and increases productivity and process control of injection molding to a new level.
Structure and Properties of Extruded Corn Starch/Polymer Foams
Randal L. Shogren, J.L. Willett, May 2001
Expanded foam peanuts made from blends of thermoplastic starch and various polymers were studied in order to better understand relationships between structure and properties in these systems. Some polymers such as polylactic acid (PLA) gave high radial expansion while others such as EastarBio polyester actually inhibited expansion compared to the control. Poly(hydroxyester-ether) (PHEE) was most effective in reducing friability of normal corn starch foams although there was still some dusting at low humidity. High amylose starch/PHEE foams had zero friability indicating that corn starch chemical modification is not necessary to confer good physical properties. Low friability seems to be correlated with a high surface concentration of polymer (as measured by XPS) and with polymers having a high degree of energy dissipation (low crystallinity, Tg near room temperature).
Blends of Starch with Poly(Vinyl Alcohol)/Ethylene Copolymers for Use in Foam Containers
Geoffrey A.R. Nobes, William J. Orts, Gregory M. Glenn, Gregory M. Gray, Micahel V. Harper, May 2001
The use of foamed polymer packaging such as polystyrene (PS) cups, bowls and clamshells has decreased in recent years because of perceived environmental disadvantages. Blends of starch with poly(vinyl alcohol-co-ethylene), PVOH, a degradable, water-resistant polymer, were processed into viable alternatives to PS providing degradable polymers from renewable resources. Modulated DSC and X-ray crystallography were used to characterize the miscibility and morphology of extruded starch/PVOH blends that contained a series of plasticizers. These included combinations of water, glycerol, triacetin, citrate esters, and amino acids. The optimal blend formulation, based on miscibility, strength, aging characteristics, and capability to replace PS foam was--60-65% wheat starch, -25 -30% PVOH, and -5-10% plasticizer.
Numerical Investigation of the Continuous Electronic Laminate Processing
Mingjun Yuan, Tim A. Osswald, Jose M. Castro, L. James Lee, May 2001
The continuous electronic laminate processing method is a novel method which addresses the major industrial concerns: solvent elimination, void removal, dimensional consistency, and economics. To better understand its process mechanism, modeling and numerical simulation is implemented on resin flow, heat transfer, and conversion process. In this study, the problem of resin flow and heat transfer through the composite channel is analyzed. The channel is assumed to be a two-layer system, one filled with a resin saturated porous medium and the other with a clear resin. The Brinkman - Forchheimer - Extended Darcy equation is utilized for the glass fiber matrix porous region. The viscosity effect accompanied by the resin curing process is coupled into the flow model. For the heat transfer analysis, a uniform heat flux is imposed at the copper plate, and the heat diffusion effect in resin cure is also considered. The laminate thickness variation and the curing degree profile can also be obtained using the numerical simulation.
Use of Cavity Pressure Sensors to Build Viscosity Data for Flow Simulations
Paul Van Huffel, Mike Groleau, May 2001
Mold filling analyses are frequently used in the design of a part or mold, but are rarely validated to verify the assumptions used in the simulation. This includes assumptions about the accuracy of the material property database(s). The purpose of the proposed study was twofold: 1. to reconstruct viscosity data for a material using actual process data from a standard mold geometry; and 2. to validate the data by comparing simulation results with actual cavity pressure data. Validation was performed using different analysis models and processing conditions, and showed promising correlation with actual process results.
Automatic Design for Parting Line on Injection Mold
Hiroshi Koresawa, Masato Sakashita, Hiroshi Suzuki, May 2001
This study discusses a method for the automatic design of a suitable parting line, which enables a reduction in flash, which occurs at the front edge of the parting line, a molded defect in injection molding. The amount of flash is estimated by the size of the gap, which is calculated at the front edge of the parting line, using numerical analysis by the non-linear finite element method. The parting line is automatically determined, using heuristic search methods of a genetic algorithm. As for the application of this algorithm, its validity will be examined in the following steps in the process of a numerical experiment : encryptation of individuals expressing parting line, the definition of the fitness function to evaluate such individuals, and genetic operation (selection, crossover, and mutation) for the individuals. Our study found determination of a parting line, which almost satisfies the size of the gap and effective stress given as targeted values, and its possibility of automatic design.
Effect of Processing Parameters on Bond Strength for Multicomponent Injection Molding
Shaival R. Mehta, Dipen R. Parikh, May 2001
TPVs already have a number of successful applications in many multiple component parts. Part consolidation and integration resulted in cost saving and added value. Useful attributes, such as soft touch for ergonomics, contrasting color for better consumer appearance and marking for corporate recognition, can be achieved along with better quality and performance. In those parts, TPVs play a very important functional role, as such integrated seals & gaskets for water tight applications, soft touch grips for kitchen wares, living hinges and/or energy absorption elements. Co-process fabrication technology takes advantage of the melt-processibility of TPVs and the heat fusion bonding to a compatible substrate. These multi-material techniques have been creatively used in co-extrusion, tri-extrusion, insert molding, two shot molding and even co-injection [1].
TPEs in Hot Runner Systems: An Elastic Entity
Robert C. Wegelin, Shaival R. Mehta, May 2001
Hot runner systems have been around since the early 1960's. They have provided users with runnerless, finished parts for many technically exciting applications. In producing these parts, materials play an important role in the type of hot runner system used to fabricate them. Hot runner systems lend themselves to multi-shot molding applications, which eliminates the need for three-plate cold runner systems. Hot runner systems are used for a variety of reasons, the main ones being a runnerless system with zero scrap, fast cycle times and, in many cases, improvement of part quality. There are no gates to trim. Cycle times are based on the part itself, and smaller gates can be used to improve the molded part appearance. While all this paints a rosy picture, disadvantages in hot runner systems do exist. Higher mold costs and longer learning curves, along with added personnel training, tend to make using these systems more costly. For high volume production, these systems are ideal and they can improve the ability to engage in a lights out" operation for best efficiencies. In our review we will touch briefly on standard hot runner systems for thermoplastics but the focus will be on hot rudder systems for thermoplastic elastomers (TPEs) and thermoplastic vulcanizates (TPVs)."
Ballistic Impact Measurements of Polycarbonate Layered-Silicate Nanocomposites
Alex J. Hsieh, John W. Song, Jon Nebo, Anant Singh, May 2001
The effect of layered-silicates on the impact response of polycarbonate (PC) nanocomposites against the .22 caliber fragment-simulating projectile was determined. The amount of nanoclays incorporated appears to be critical in the overall ballistic performance. For example, nanocomposites consisting of 5 wt.% nanoclays exhibit brittle mode of failure, while ductile deformation is observed for the nanocomposites containing 2.5 wt.% of nanoclays as well as for the PC control. Stress whitening, which is not observed in the pure PC, is apparent in the 2.5 wt.%-PC nanocomposites. This is consistent with their quasi-static mechanical response, and is attributed to good interfacial bonding and proper stress transfer between the matrix and layered-silicate reinforcements.
A Potential Screening Method for Interface Stability in Particulate Filled Dental Composites
A. Prasad, A. Karmaker, N. Sarkar, May 2001
This study involves in-vitro simulation and characterization of the degradation process of dental composites. Composite formulations with different silane contents on filler surfaces were prepared. Cylindrical test specimens of 6mm in diameter and 3mm in depth were prepared using visible light curing system. Cured specimens were treated with an aqueous solution of 0.1N sodium hydroxide (NaOH) at 60°C for various time intervals. They were then neutralized with hydrochloric acid (HCl) solution followed by 24 hours immersion in distilled water and air- dried. The radial surface of each specimen was polished and the depth of degradation was measured using an optical microscope. Specimens with optimized silane content exhibited the lowest degradation, and those with unsilanated fillers displayed the highest.
Printing on Vinyl-Part II, FTIR and TOF SIMS Studies
Joseph W. Burley, May 2001
Earlier surface analysis studies suggested that, at least in some situations, the print adhesion properties of barium/zinc stabilized, stearic acid lubricated, PVC are influenced by the migration (exudation) of a barium/zinc stearate complex. This paper expands the previous study in attempts to reproduce the effects observed on samples of commercially produced films, explain the origin of the migrating specie and to identify the variables which influence the extent to which the phenomenon occurs. The effects of different lubricants, stabilizers and processing conditions are studied. Mechanistic work suggests that a revised hypothesis is appropriate and that the hydrolyzed complex is actually formed in the PVC matrix and not at the surface.
Comparison of the Mechanical Performance of Extruded Blown and Cast Polyolefin Thin Film
M. Billham, A.H. Clarke, G. Garrett, G.M. McNally, W.R. Murphy, May 2001
Thin mono-layer films of metallocene catalysed polyethylene, linear low density and conventional low density polyethylene, as well as polypropylene, were produced from a 38mm extruder through a 75mm diameter blown film die and a 600mm cast film die. By using the same die gap on each die to achieve equal draw-down ratios, the influence of orientation from the two processes on the mechanical properties of each film was investigated. Tensile strength at break, Young's Modulus, percentage elongation at break, tear propagation resistance, in both machine and transverse direction all gave significant differences in properties with cast film when compared to different blow-up ratios for blown film. Differential Scanning Calorimetry was used to measure the percentage of crystallinity in each film. Differences were found to show that the cooling process as the melt exits the die has a significant effect on the percentage of crystallinity.
Novel Process for the Production of Long Glass Fiber Reinforced Composites
Gregor Chszaniecki, May 2001
Twin screw extruders have been used successfully to incorporate glass fibers in polymer melts. However, during the compounding step, the fiber attrition can be high, resulting in poor physical properties of the finished product. In order to obtain a high overall fiber length and a gentle treatment of the fiber, the glass roving has to be impregnated with melt prior to entering the extruder. The patented Berstorff solution presented in this paper is based on two counter rotating rolls, that feed the fibers to the extruder and impregnate them with melt. The impregnating unit is designed in a compact manner and can be sandwiched between two barrel sections of a co-rotating twin screw extruder.
Feeding and Processing of Compacted Fillers on a Reciprocating Single Screw Kneader Compounding System for Automotive and Masterbatch Applications
Colin G. Richardson, Hans-Ulrich Siegenthaler, Todd A. Lemanski, Frederic Jouffret, Georges Fourty, May 2001
Fillers are used in plastics to achieve a variety of beneficial structural and performance properties. These properties are maximized by using fillers in the form of powders with fine particle sizes and specific aspect ratios. The goal is to preserve these properties after compounding. Unfortunately, low bulk density materials like these tend to bring a significant amount of entrained air into the extruder that takes up volume, hampering, among other things, throughput rates. As an alternative to these powdered forms of fillers, compacted fillers can be used which significantly reduce the level of entrained air. As a result, processing and handling of these materials are much less labor intensive. Using a reciprocating screw kneading system, a number of talc filled formulations used for automotive and masterbatch applications were compounded over a variety of conditions. The results will show improvements in throughput rates when split feeding the powdered talc and marked improvements in handling, throughput rates and overall compounding performance when using the compacted talc.
Streamline Die Design for Complex Geometries
D. Beaumier, P.G. Lafleur, C.A. Thibodeau, May 2001
Severe tolerances of profiles in the plastic industry require a simple and accurate die design method. In this paper, we present a method taking simultaneously into account the flow-balancing problem as well as the complex dimensional changes occurring after the die exit. A network model is used to predict the flow behavior within the profile die. The model is non-isothermal and includes accurate sidewall effects. Experiments with capillary and slit dies were done to determine the swelling as a function of shear rate, residence time and temperature. Several die designs for a PVC profiles were realized. Tests conducted for rectangular PVC profiles confirmed the validity of the model.
Reinforced Plastic Design: Tensile Versus Flexural Fatigue
John A. Krohn, Glen E. Novak, Michael G. Wyzgoski, May 2001
Glass fiber reinforced thermoplastics are being used in applications where fatigue life is important. Although conventional S-N or Wohler curves can be adequate for design purposes, the inherent anisotropy of these materials is often not accounted for if one uses standard molded test bars. An additional factor, generally not recognized, is the difference between fatigue data generated in tension versus flexural loading. This paper will present fatigue data for several glass reinforced materials showing the relative influence of these effects. Simple rules of thumb to estimate the appropriate fatigue data for design pruposes are also provided.


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