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The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
Printing on Vinyl-Part II, FTIR and TOF SIMS Studies
Joseph W. Burley, May 2001
Earlier surface analysis studies suggested that, at least in some situations, the print adhesion properties of barium/zinc stabilized, stearic acid lubricated, PVC are influenced by the migration (exudation) of a barium/zinc stearate complex. This paper expands the previous study in attempts to reproduce the effects observed on samples of commercially produced films, explain the origin of the migrating specie and to identify the variables which influence the extent to which the phenomenon occurs. The effects of different lubricants, stabilizers and processing conditions are studied. Mechanistic work suggests that a revised hypothesis is appropriate and that the hydrolyzed complex is actually formed in the PVC matrix and not at the surface.
Comparison of the Mechanical Performance of Extruded Blown and Cast Polyolefin Thin Film
M. Billham, A.H. Clarke, G. Garrett, G.M. McNally, W.R. Murphy, May 2001
Thin mono-layer films of metallocene catalysed polyethylene, linear low density and conventional low density polyethylene, as well as polypropylene, were produced from a 38mm extruder through a 75mm diameter blown film die and a 600mm cast film die. By using the same die gap on each die to achieve equal draw-down ratios, the influence of orientation from the two processes on the mechanical properties of each film was investigated. Tensile strength at break, Young's Modulus, percentage elongation at break, tear propagation resistance, in both machine and transverse direction all gave significant differences in properties with cast film when compared to different blow-up ratios for blown film. Differential Scanning Calorimetry was used to measure the percentage of crystallinity in each film. Differences were found to show that the cooling process as the melt exits the die has a significant effect on the percentage of crystallinity.
Novel Process for the Production of Long Glass Fiber Reinforced Composites
Gregor Chszaniecki, May 2001
Twin screw extruders have been used successfully to incorporate glass fibers in polymer melts. However, during the compounding step, the fiber attrition can be high, resulting in poor physical properties of the finished product. In order to obtain a high overall fiber length and a gentle treatment of the fiber, the glass roving has to be impregnated with melt prior to entering the extruder. The patented Berstorff solution presented in this paper is based on two counter rotating rolls, that feed the fibers to the extruder and impregnate them with melt. The impregnating unit is designed in a compact manner and can be sandwiched between two barrel sections of a co-rotating twin screw extruder.
Feeding and Processing of Compacted Fillers on a Reciprocating Single Screw Kneader Compounding System for Automotive and Masterbatch Applications
Colin G. Richardson, Hans-Ulrich Siegenthaler, Todd A. Lemanski, Frederic Jouffret, Georges Fourty, May 2001
Fillers are used in plastics to achieve a variety of beneficial structural and performance properties. These properties are maximized by using fillers in the form of powders with fine particle sizes and specific aspect ratios. The goal is to preserve these properties after compounding. Unfortunately, low bulk density materials like these tend to bring a significant amount of entrained air into the extruder that takes up volume, hampering, among other things, throughput rates. As an alternative to these powdered forms of fillers, compacted fillers can be used which significantly reduce the level of entrained air. As a result, processing and handling of these materials are much less labor intensive. Using a reciprocating screw kneading system, a number of talc filled formulations used for automotive and masterbatch applications were compounded over a variety of conditions. The results will show improvements in throughput rates when split feeding the powdered talc and marked improvements in handling, throughput rates and overall compounding performance when using the compacted talc.
Streamline Die Design for Complex Geometries
D. Beaumier, P.G. Lafleur, C.A. Thibodeau, May 2001
Severe tolerances of profiles in the plastic industry require a simple and accurate die design method. In this paper, we present a method taking simultaneously into account the flow-balancing problem as well as the complex dimensional changes occurring after the die exit. A network model is used to predict the flow behavior within the profile die. The model is non-isothermal and includes accurate sidewall effects. Experiments with capillary and slit dies were done to determine the swelling as a function of shear rate, residence time and temperature. Several die designs for a PVC profiles were realized. Tests conducted for rectangular PVC profiles confirmed the validity of the model.
Reinforced Plastic Design: Tensile Versus Flexural Fatigue
John A. Krohn, Glen E. Novak, Michael G. Wyzgoski, May 2001
Glass fiber reinforced thermoplastics are being used in applications where fatigue life is important. Although conventional S-N or Wohler curves can be adequate for design purposes, the inherent anisotropy of these materials is often not accounted for if one uses standard molded test bars. An additional factor, generally not recognized, is the difference between fatigue data generated in tension versus flexural loading. This paper will present fatigue data for several glass reinforced materials showing the relative influence of these effects. Simple rules of thumb to estimate the appropriate fatigue data for design pruposes are also provided.
Rheology and Crystallization in Fiber Optic Cable Jacket and Conduit Extrusion
Scott H. Wasserman, J. LaMonte Adams, May 2001
Rheological tests measure melt-state polymer flow, delineating molecular structure and predicting extrudability. Rheology of compounds used in fiber optic (FO) cable jackets and in the conduits that contain such cables will be our focus. Polyolefin-based jackets strengthen the FO cable and protect internal components, while the conduit provides long-term strength and protects the cables against environmental stresses. High density polyethylene use in these applications is growing rapidly, spurred by FO cable growth. Important properties in both applications include melt-state processability, stress crack resistance and solid-state stiffness. Melt rheology directly influences processability, combining with crystallization behavior to dictate final solid-state properties.
Reinforced Plastic Design: Microstructure and Stiffness of Tensile Bars
John F. O’Gara, Peter H. Foss, James P. Harris, May 2001
The majority of mechanical property data reported for reinforced thermoplastics and available to a part designer is based upon testing end-gated injection molded tensile bars. ASTM Type I injection molded tensile bars were molded of ~30 wt% glass-filled polybutylene terephthalate, polycarbonate, and nylon-66. Detailed microstructural evaluations of the lengths and orientations of the glass-fibers were made. The experimental elastic moduli are predicted to within 4% using micromechanics. As a general observation, the simulations reveal that the modulus for a 30 wt% short glass fiber-filled thermoplastic tensile bar is 50 to 70% that expected from a composite of unidirectional fibers of infinite lengths.
Phase Morphology and Cure State Characterization of Soft Thermoplastic Vulcanizates (TPVs) by Using Atomic Force Microscopy (AFM)
Oansuk Chung, Hari P. Nadella, May 2001
AFM shows comparable capability to transmission electron microscopy (TEM) for characterization of TPV phase morphology. Phase imaging by tapping mode AFM scanning gives good contrast between the rubber phase, plastic phase, and filler in a TPV. In addition to TPV phase morphology characterization capability, it can quantitatively distinguish the cure state difference of the rubber in TPVs. A procedure for the analysis on phase imaging data is demonstrated and a good correlation is observed between AFM data, weight gain, and modulus at 100% elongation.
Tear Resistance of INSPiRE Performance Polymer Blown Films
S. Wu, C. Bosnyak, D. Faul, L. Tau, Y. Huang, May 2001
Tear resistance is critical for Polypropylene (PP) blown film in packaging applications and has been widely evaluated by several ASTM standard test methods. However, for characterization and differentiation of the tear resistance of blown films, these factors should be considered: tear behavior, tear propagation trajectory, film thickness, and tear speed. The tear strength of several mono- and multi-layer INSPiRE performance polymer films was analyzed by several test methods in this paper. The effect of film orientation, loading speed, failure mechanism, and sample geometry on tear strength will be discussed. Some uniqueness of the tear behaviors and advantages of the INSPiRE performance polymer blown films will also be discussed.
Injection Molding Long Glass Fiber Reinforced Thermoplastic Composites
Scott Gottgetreu, May 2001
Long Glass Fiber Reinforced Thermoplastic (LGFRT) Composites are produced by a proprietary pultrusion process rather than conventional extrusion compounding. This pultrusion process provides a high level of fiber impregnation in the pellets with no fiber damage compared to conventional short glass compounding. The result is injection moldable pellets containing fully wetted fibers equal in length to the pellet, typically 11 mm. This longer, initial fiber length translates into improved properties in molded parts when processing with optimized molding equipment and conditions that preserve the higher aspect ratio. As a class, long fiber composites exhibit overall higher mechanical properties, better elevated temperature performance, lower wear, and improved creep and fatigue endurance. This paper will examine the advantages of long fiber composites, properties of long vs. short fiber, equipment, tooling and processing conditions to maximize fiber length in the molded part and resultant mechanical advantage. In addition, alternative processing techniques including structural foam, injection compression & gas-assist, types of thermoplastic materials used and typical applications will be discussed.
Dependence of Melting Behavior on Melt Index
Bo Ki Hong, Hyun Seog Kim, Chan I. Chung, May 2001
The dependence of dissipative melting behavior of solid bed on melt index ([MI]) was studied experimentally for polystyrene (PS) and high density polyethylene (HDPE). Melting occurs primarily by the heat generated in the melt film in dissipative melting. The melting rate and the shear stress were expected to decrease with increasing [MI] because of decreasing viscosity. For PS, the shear stress decreased as expected but the melting rate increased with increasing [MI]. For HDPE, both the shear stress and the melting rate did not show a simple dependence on [MI]. HDPEs with very low [MI] values exhibited unstable melting mechanism and their melt did not coat the metal surface. Such unstable melting mechanism is probably responsible for high screw wear. Shear stress depends on the viscosity in the melt film. [MI] only indicates the viscosity at low shear rates, far below the shear rates in the melt film, and by itself cannot indicate the viscosity in the melt film. Melting rate depends on the viscosity and also the velocity profile in the melt film. The viscosity and the velocity profile in the melt film depend not only on the [MI] but also on the shear and the temperature sensitivities in a complex way.
3D Blow Molding Today, an Overview about Different Systems Which Are Established in the Market Today
Michael Thielen, Frank Schüller, Martin Balzer, May 2001
3D-blowmolding was introduced some years ago. In the meantime a certain number of different systems became established in the market. Suction blowmolding, 3D-blowmolding with parison manipulation and a split mold, horizontal machine with vertically opening mold and a 6-axis-robot laying the parison into the cavity or a machine without a closing unit at all. All these systems can be combined with 6 or 7 layer coextrusion or with sequential coextrusion running hard-soft-hard resins one after the other. The paper gives an overview, production examples and an outlook to future developments.
Chain Extension of PA-6 and PA-6/66 copolymer via Reactive Extrusion with Triscaprolactamyl Phosphite (TCP)
M.K. Akkapeddi, Clark Brown, B. Vanbuskirk, May 2001
Polyamide 6 (PA-6) homopolymer and copolymers have been chain extended from a low molecular weight feedstock into high molecular weight, high melt viscosity nylon products via a reactive extrusion process using a novel chain extender viz., triscaprolactamyl phosphite (TCP). The chain extension process involves an 'activated' polycondensation reaction between the endgroups of the nylon. In this paper we will discuss the effect of the chain extender concentration and the extruder process conditions on the chain extension efficiency with respect to molecular weight and rheological property benefits achieved.
New High Barrier, Oxygen Scavenging Polyamides for Packaging Applications
E.P. Socci, M.K. Akkapeddi, D.C. Worley, May 2001
Honeywell International is currently developing high oxygen barrier polyamides based upon nylon 6 and blends of nylon 6 with amorphous nylons (PA6I,6T type). Significant improvements in oxygen barrier result from the introduction of a proprietary oxygen scavenger moiety (active barrier") and/or silicate nanoclays ("passive barrier"). The nanoclay is added during polymerization rather than in a melt compounding process which leads to improved barrier properties and lower haze levels in multi-layer films and bottles. These novel polyamides are suitable for use as high oxygen barrier layers in cast and blown film as well as for barrier layers in co-extrusion blow molded polyolefin based bottles and co-injection stretch blow molded PET bottles. They are part of a cost-effective multi-layer film/bottle solution for packaging oxygen sensitive products. When blended with nylon 6 amorphous nylon lowers the total crystallinity and may enhance adhesion to PET. These new high oxygen barrier nylons should meet the barrier requirements of many demanding packaging applications while continuing to offer desirable properties such as flavor barrier strength and toughness."
Time Dependence of Shear-Thinning of Polymer Melts
J.P. Ibar, May 2001
We analyze Non-Newtonian dynamic data of several polymer melts and find experimental evidence for the time dependence of shear-thinning. To summarize, viscosity is not just function of temperature, pressure and strain rate (or frequency), as is already well known, but also of time. We specify the experimental conditions to observe this phenomenon, and provide an analytical expression that fits the data very well. An interpretation of this time dependent behavior is presented. It is suggested that disentanglement" understood in terms of the dual-phase interactive model (EKNET theory) is responsible for the time dependence of viscosity. We stipulate that any desired amount of disentanglement can be induced in any polymer melt by the proper mechanical treatment specifically providing means to eliminate entropic mechanisms of melt deformation. This can be achieved by synchronizing the viscoelastic states of the dual phases for instance by a combination of the proper temperature rate and amplitude of shear deformation. It is shown that time dependence of shear-thinning can only occur below the temperature of stability of the network of interactive coupling interactions between conformers which we are able to associate with Tll Boyer's liquid-liquid transition. Practical applications to processing are discussed in a companion paper of this ANTEC meeting [1]."
Extrusion of Polymer Melts under Intensive Shear-Thinning Inducing Lower Pressure and Temperature Requirements
J.P. Ibar, May 2001
We have built an extension to an extruder line, which provides the means to submit polymeric melts, as they extrude out, to an intensive shear-thinning treatment by combining cross-rotational and shear vibration melt deformation. Experiments are conducted with two polymers, a highly entangled metallocene polyethylene and a general purpose extrusion grade polycarbonate. It is shown that, for both polymers, extrusion requirements for a given throughput, i.e. pressure and temperature, can be drastically reduced, by as much as 80°C for temperature, and, simultaneously by a factor 2-5 for pressure, when applying the new patented combined cross-rotational and vibrational means. We study the individual effect on shear-thinning of cross-rotation alone, and of cross-vibration alone, and also analyze their combined effect which results in drastically reducing pressure and temperature of extrusion at constant throughput. Applications are discussed, which range from the benefits of extruding melts and blends at lower temperature (when normal extrusion requirements would degrade one of the ingredients), or increasing throughput, to producing disentangled frozen-in resins, having much lower viscosity at given molecular weight, when extrusion under intensive shear-thinning is extended to much longer flow lengths.
Reduction of Viscosity of Polymer Melt by Shear-Thinning and Disentanglement : Rheological Criteria and Commercial Perspectives
J.P. Ibar, May 2001
Mechanical performance of polymers improves with molecular weight (MW). Unfortunately, melt viscosity and thus lack of processability also increases with MW. Recently, a method to temporarily reduce the melt viscosity without changing MW has been proposed [1]. The method uses processing windows such that shear oscillation superposed on extensional flow at gradually increasing shear thinning amplitude are created by imposing conditions of strain, frequency and temperature that bring the melt (G'/G*) close to 0.75-0.85. The purpose of the present communication is to report results of a two-year research and development effort aimed at reducing the viscosity of several commercial resins using a pilot stage disentanglement machinery. The paper explores the commercial implications and answers the following questions: is it possible to shear-disentangle a large quantity of commercial resin at fast throughput, is it possible to process the disentangled melt before it regains its normal entanglement, and is it possible to speed-up the re-entanglement process after forming to regain mechanical benefits? From a laboratory and low throughput extrusion scale, the answer to all these questions is positive. The technology is presently being tested at a pilot pre-production scale to quantify the answers from a commercial perspective.
Measuring the Nonlinear Viscoelastic Material Properties of Thermoplastic Materials by Dynamic Mechanical Analysis (DMA)
O. Schröder, E. Schmachtenberg, May 2001
As plastics are more and more used for high-performance application the design and material selection have to take into account the complex material properties. The lifetime of a product and the suitability of a raw material for a certain application can often only be estimated based on a huge data set of mechanical properties. Mechanical properties of thermoplastic materials are influenced by temperature, time and the level of loading. Thus, the engineer at least needs stress-strain-curves measured under varying temperatures and loading speeds to ensure an efficient product design. These measurement data are also required by software for simulating nonlinear visoelastic material behavior. Because of the costs of measurement the required data often are not available sufficiently. This paper describes first results of research aiming at generating the stress-strain-curves out of Dynamic Mechanical Analysis (DMA) measurement data. By help of DMA mechanical properties can be measured faster, more extensively and with lower costs than by tensile tests. prediction of product lifetime. Also it can reduce costs for product testing as models are able to simulate the effect of boundary conditions which in tests only can be realized with a lot of effort (e.g. changing temperatures, multi-dimensional stresses, changing loading speeds). However, material models base on measured material data. Every suitable model at least needs the data of several tensile tests.
Resistance to Erosive Wear by Copper Alloy Mold Components
Kurt Hayden, Paul Engelmann, Philip Guichelaar, Robert Dealey, Michael Monfore, May 2001
Injection molds are increasingly making use of high strength, high thermal conductivity copper alloy mold components to reduce cycle time and improve dimensional accuracy. Molders are focused on the durability of these components. This paper is the first of a two-part discussion of erosive wear. Performance of standard copper alloys and tool steels was compared. Wear measurements were taken on a flat surface across from the gate, on the core side of the mold. Samples were run without release or lubrication aides, using 33% glass-filled nylon. Uncoated copper alloys were found to have comparable performance to that of pre-hardened tool steel.


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