The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
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Influence of Filler Dispersion on Electrical and Rheological Properties of Pc/San Blends with Graphite Nanoplates or Expanded Graphite
The effect of Graphite Nanoplates (GnPs) and Expanded Graphite (EG) on electrical and rheological properties was investigated in co-continuous melt-mixed polycarbonate (PC) /poly(styrene-acrylonitrile) = 60/40 wt% prepared using micro-compounder in two steps. Mixing conditions in premixing the fillers into PC were varied. Similar to carbon nanotubes (CNTs), GnPs and EG tend to localize in PC. Improved filler dispersion for samples exposed to higher mixing energy in the premixing step resulted in larger increase of complex viscosity and storage modulus. However, electrical resistivity was lower in samples which experienced lower mixing energy. Comparing EG and GnP, the effects are quite similar. EG showed a slightly better electrical performance.
Increased Throughputs in Blown Film Extrusion by Using a Contact Cooling Sleeve
One of the most important requirements for an efficient blown film extrusion process is the cooling of the film bubble. Conventional blown film lines use air rings to cool the film bubble. A new approach to enhance the cooling power is the use of an additional contact cooling sleeve that is placed on top of the die and which cools the melt via conduction.
The influences of the use of the contact cooling sleeve on the blown film process and the resulting film properties were tested. In order to do so, process settings were varied and the mechanical and optical film properties, as well as the maximum throughput of the blown film line have been determined. These trials showed that the mechanical film properties are not significantly influenced by the use of a contact cooling sleeve. For the optical film properties, the transmission is slightly decreased while the haze of the films is increased by about 10 % absolute. With the use of a contact cooling sleeve, it is possible to increase the throughput of the blown film line especially for smaller blow-up ratios. A simulation of the cooling process of the melt within the cooling sleeve has been performed as a first step to be able to dimension cooling sleeves for different sizes of blown film lines and process conditions.
Improvement of the Extrusion Foaming Properties of Externally Plasticized Cellulose Acetate by Reactive Melt Mixing Using a Multifunctional Reactive Oligomer
Externally plasticized cellulose acetate was modified by reactive melt mixing with a multi-functional oligomer (chain extender). The modified compound was characterized in terms of molecular properties and viscosity. The reactive modification was applied in an extrusion foaming process using 1,3,3,3-tetra-fluoropropene (HFO-1234ze) as blowing agent. The reactive modification in the foam extrusion process can be used to affect the rheology and thereby foaming properties of the cellulose acetate compound to optimize the cell morphology of the resulting foam sheets or boards.
Cycle Time Reduction by Water Spray Cooling in Thermoforming
The cycle time of automated multi-station thermoforming machines is limited by the cooling time. Optimizations of heat dissipation in negative thermoforming are especially focused on the mold-side cooling. However, cooling the inner, non-mold-contact side of formed part also provides potential for increasing the total cooling rate. The injection of water spray on the non-mold-contact side during the forming step is a promising approach to reduce the cooling time in thermoforming due to better heat transfer properties or the evaporation potential. In this paper the influence of an internal water spray cooling on the deforming temperature of thermoformed cups is examined.
During water spray cooling a conflict of aims results between the maximum cooling effect and a water-residuefree cup. The injected volume of water spray significantly affects both the deforming temperature of the formed cup and the water residue. By optimizing the process a maximum injection volume of 6 ml water can be achieved for the examined 400 ml large cup with negligible residual water containing after deforming in the molded part. The results show that already minimal wetting of the partsurface results in effective cooling. To ensure negligible amount of residual water, a superposition of the water spray droplets should be avoided. Otherwise larger water droplets are created, which can not be removed by evaporation or an additional blowing process step. By using water spray, the cooling can be accelerated up to 6 K/s for the cup demonstrator. Thus, the application of water spray cooling reduces the cycle time of multistation thermoforming machines.
Highspeed Tensile Testing of Polymer Materials Considering Force-Oscillations and its Origin
The force-oscillation phenomenon describes a superimposition of force measurements with an oscillating signal which can be monitored in tensile impact testing. These oscillations become predominant with an increase of the haul-off velocity which prohibits a resilient evaluation of the measured force characteristics. Hence force-oscillations present a limiting factor to the maximum haul-off velocities in tensile impact testing and therefore a limitation to material data measurement for crash analysis in general.
The presented research looks at the phenomenon of force-oscillations on viscoelastic materials and gives an elementary investigation on its origin. Furthermore a new approach is outlined to overcome the existing limitations to tensile impact testing which enables a material data measurement basically independent of the considered haul-off velocity.
Atomized Spray as a Process Fluid for Fluid-Assisted Injection Molding
Gas- and water-assisted injection molding (GAIM, WAIM) can be used to produce hollow plastics parts. Previous research showed that the thermal properties of gas and water have a large influence on part properties and the formation of part defects. A new approach is to use atomized spray to adjust the thermal properties of the process fluid to the needs of the process and used material. The study will determine the effect of water percentage on the cooling effect of the atomized spray and the resulting part properties. High speed imaging will show effects of water coagulation on the part cooling.
Analysis of the Process-Induced Microstructure in Injection Molding of Long Glass Fiber-Reinforced Thermoplastics
Over all stages in the injection molding process of long fiber-reinforced thermoplastic (LFT) materials, the configuration of the fibers changes, which ultimately affects the mechanical performance of the finished part. This article presents a full microstructure analysis of an injection molded part made out of polypropylene reinforced with 40% by weight of glass fibers. The analysis takes into account local measurements of fiber orientation, fiber length, and fiber density distributions by applying sophisticated measurement techniques, such as micro-computed tomography.
The results of this work show that the assumption of a uniform fiber length and fiber density throughout the entire part is not valid. The number (weight) average fiber length increases from 0.64 mm (1.63 mm) close to the gate to 1.12 mm (2.81 mm) at the end of the flow path. Similarly, the fiber density varies along the flow path from 37.7 wt% in the gate region to 44.6 wt% at the end of flow. Moreover, the fiber density measurements across the part thickness show a significant fiber agglomeration in the core of the part that consistently suggests almost 30% more fibers in the core layer than in the shell regions.
Micropelletization and Their Application to Manufacture Porous Plastic Parts
A novel micropelletization technique yields micropellets with a controlled morphology and narrow particle size distribution which can be used for sintering applications and additive manufacturing processes such as laser sintering. A polymer melt is extruded through a capillary and the extruded thread is stretched with a hot air stream until flow instabilities cause it to breakup into small droplets. This work focuses on an improved experimental setup with additional temperature control for the production of micropellets. By performing a variety of test series, options for further optimization of the process have been worked out. This is another important step towards an economical, ready-to-use-process that can provide ideally shaped and size-distributed micropellets using a wide range of polymers. Furthermore, sintered parts were produced to demonstrate possible utilization of these micropellets for industrial and commercial applications.
Melt Devolatilization Extruson Process for Brominated Polymeric Flame Retardant
A brominated polymeric flame retardant has a significantly advantaged environmental, health and safety profile compared to small molecule halogenated flame retardants due to reduced molecular mobility and thus no bio-availability. The brominated polymeric flame retardant can be prepared using an innovative indirect bromination reaction, which requires the use of a halogenated solvent. A devolatilization extrusion process has been identified as an economically favorable and technically simplest isolation process among many other isolation technologies assessed. The development of a devolatilization extrusion process for the brominated polymeric flame retardant is presented.
Fiber Surface Treatment as an Approach to Increase Fiber Content in AGAVE-LMDPE Composites Produced by Rotomolding
In this study, Agave fibers (Agave tequilana Weber var. Azul) were surface treated with maleated polyethylene (MAPE) to increase the polymer-fiber compatibility with two main objectives: 1) to improve the mechanical properties of composites produced by rotational molding, and 2) to increase the fiber content in the composite. The rotomolded composites were produced at 0, 10, 20, 30 and 40% wt. of fiber contents (treated or untreated) and characterized in terms of morphology and mechanical properties (impact, tensile and flexural). The results show that the MAPE surface treatment was successful by causing a better fiber distribution and a more uniform composite morphology allowing the possibility to use higher fiber contents in rotational molding. At low fiber contents (10 and 20% wt.), the mechanical properties were improved (up to 52%) in treated fiber composites (TFC) compared to the neat polymer and untreated fiber composites (UFC). Although the mechanical properties of TFC decreased at high fiber contents (30 and 40% wt.), they were substantially higher than UFC (about 160%, 400% and 240% for impact, tensile and flexural properties, respectively).
Study on Extrudate Swell of High-Density Polyethylenes in Slit (Flat) Dies
Extrudate swell of a high molecular weight high density polyethylene (HDPE) in flat/slit dies is studied using both experiments and simulations. The experimental set-up consists of an optical micrometer to measure the extrudate dimensions (both thickness and width) and a pair of radiation heaters to control the extrudate temperature outside the die, attached to the capillary rheometer. The simulation of extrudate swell phenomenon is carried by using the well-known integral K-BKZ model. The effects of die geometrical characteristics, molecular characteristics of polymers and operating parameters on extrudate swell measurements are studied systematically. The experimental data are compared with corresponding two dimensional steady state numerical predictions. The thickness swell is predominant in comparison with width swell due to larger shear rates applied in that direction.
Dynamic Rheological Measurements of Aqueous Polyester Dispersion in Batch Reactor and Twin Screw Extruder
This paper reports on inline measurement techniques for the rheological behavior of aqueous polyester dispersion in batch reactor and twin screw extruder (TSE). Since the preparation of latex without hazardous solvent is a relatively new technique, very little has been reported to understand the kinetic aspects of the process for both batch reactor and TSE. A sudden viscosity drop is observed in a batch reactor whereas the viscosity tends to oscillate in TSE during the addition of water when surface tension is low enough. The viscosity changes during the addition of water are thought to be related to the morphological changes during the process since surfactant must be present else no change occurs. In this paper, different surfactant and NaOH concentrations have been studied for their influence on the viscosity so that emulsification may become a predictable process in a TSE.
Innovative Extrusion Process for Liquid Silicone Rubber: Calculation Versus Experiment
Silicone rubber with its good chemical and physical resistance properties is of major interest for elastic tubing. The breadth of silicone tubings is continuously manufactured by extrusion. The extruded silicone products are cured downstream of exiting the die. Thus the viscosity of the uncured silicones must be high enough for a dimensionally stable extrudate and even with high viscosities, achievable precision and tolerances are limited due to this fact. Therefore an innovative extrusion process, which uses a heated die in order to vulcanize the extrudate inside the die, has been developed.
In this work, a formula for the flow rate is derived for an in-die-curing silicone extrusion in order to mathematically describe this process and to be able to predict the capabilities of this technology. The results of the calculations are being compared to experimental results to determine their validity.
Standard Reference Materials for the Polymers Industry
The National Institute of Standards and Technology (NIST) provides science, industry, and government with a central source of well-characterized materials certified for chemical composition or for some chemical or physical property. These materials are designated Standard Reference Materials® (SRMs) and are used to calibrate measuring instruments, to evaluate methods and systems, or to produce scientific data that can be referred readily to a common base. In this paper, we discuss the history of polymer based SRMs, their current status, and challenges and opportunities to develop new standards to address industrial measurement challenges.
Rapid Spectral Measurement of the Mechanical Properties of Polypropylene Recovered from Shredded End-Of-Life Vehicles
Our industry leading separation technology enables us to recover polyolefin and styrenic plastics from complex mixed streams such as shredded end-of-life vehicles. Plastic flakes recovered using our process are compounded and sold as pellets suitable for use in injection molding and extrusion applications. This paper looks at some of the challenges of understanding and controlling the properties of the polypropylene product, including a discussion of how infrared spectroscopy and statistical analysis of the spectra may be used to rapidly measure the mechanical properties.
Injection Moulding of Solid Oral Dosage Forms
Oral solid dosage forms are the most patient-accepted and therefore industrially relevant pharmaceutical applications, representing 80% of the market share. In that context, polymer processing techniques, such as hot melt extrusion (HME) or injection molding (IM), are increasingly used to process primary material into the final dosage forms due to several benefits (e.g., enhanced solubility or solvent-free processes). In this study, tablets based on solid dispersion systems were processed via injection molding using either primary powder or pellets prepared by HME. Fenofibrate, a BCS Class 2 substance (low solubility, high permeability), was selected as model API, with loadings of 10%, 20% and 30%, while Soluplus® (PVCL-PVAc-PEG co-polymer) served as matrix. It could be shown that both the achieved mechanical properties (e.g., hardness) of the tablet, as well as the release kinetics, are suitable for oral dosage forms.
Morphology of HDPE/PS Blends along the Axial Position in a Novel Co-Rotating Non-Twin Screw Extruder
In this study, a novel co-rotating non-twin screw extruder with a clam-shell barrel was designed and invented. Then, the visualization of mixing an 80/20 (wt%) ratio HDPE/PS blend was carried out after the barrel was opened. The morphological development of HDPE/PS blends in this non-twin screw extruder was studied. Two groups of operating conditions were employed when the ratio of the screw speed to the feed rate was kept constant. The effects of the screw speed on the morphological development of the HDPE/PS blends along the axial direction during extrusion were discussed. The results revealed that coalescence happened during extrusion, and increasing the screw speed resulted in a smaller droplet size and a narrower size distribution of the product. The dispersive mixing was stronger in the nip zone than in the screw channel. In addition, it was found that the morphology pattern changed considerably and the particle size decreased sharply and became more uniform after the blend went through the holes of the die.
Numerical Simulation for the Viscoelastic Effects on the Birefringence Variation for an Injected Optical Lens
Recently, polymeric optical lens have been utilized in many fields and electronic devices, such as camera, mobile phone, tablet, and other optical devices. The quality is the key for the main suppliers to keep competition, however, how the material’s viscoelasticity influences the optical features is still not fully understood yet. In this study, we have investigated the viscoelastic effects on the optical property of a lens made of Zeonex COP 480R material by the traditional injection molding, simulated with n = 0.4 and ?* = 217,000 Pa in the Cross model for the melt viscosity. Results show that if the power-law index (n) was varied from 0.1 to 0.6, the total fringed order has no significant difference, but the fringed patterns were varying dominantly in the perpendicular direction, instead of the flow direction for the case at n = 0.4. This situation was matched with the distribution of the flow-induced residual stresses. Moreover, if the ?* in the Cross model was varied from 100,000 Pa to 300,000 Pa, the total fringed patterns were apparently changing from being dominated in the flow direction to being in the direction perpendicular to the flow. The influenced width of the fringed patterns was almost linearly increased with the increasing ?*. The results can be applied as some guideline for either the further material modifications or the new material developments.
3D-Simulation of Gas-Assisted Injection Molding
The gas-assisted injection molding (GAIM) process is so complicated that increasing reliance has been placed on CAE?Computer Aided Engineering?as a tool for both mold designers and process engineers. In this paper, a 3D theoretical model and numerical scheme is presented to simulate the GAIM process, in which an equal-order velocity-pressure formulation method is employed to eliminate the pressure oscillation. In addition, the whole flow field is calculated with the gas pressure as a boundary condition to obtain the gas penetration, and a 3D control volume scheme is employed to track the flow front of the melt and gas. Finally the validity of the model has been tested through case studies and experimental verification.
Thermal Analysis of the Rotational Molding Cycle Followed by Internal Air Temperature Profiles: An Application for Foamed Polyethylene
In this study, temperature profiles for the air inside the mold was measured to analyze the thermal behavior of a polymer for a complete rotational molding cycle. Foamed and unfoamed linear medium density polyethylene (LMDPE) parts were produced by biaxial rotational molding. A chemical blowing agent (azodicarbonamide, ACA) was used at different concentrations (0, 0.25, 0.50, and 1.0 % wt.). The temperature profiles inside the mold were measured for different oven temperatures (260-320 °C). The analysis proposed is based on the temperature profiles and their derivatives to better determine the different temperature transitions occurring in a complete molding cycle.
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