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Conference Proceedings

How Important Is the Volumetric Absorption Concept? Part 1 – Model Building
Jim Throne, May 2017

I lay the groundwork for a thorough comparison of radiopaque and volumetric absorbing heat transfer models. I define the technical models for thin-gauge thermoplastic sheet through what I have called the Lumped Parameter Model (LPM) where conduction through the plastic plays no role. And I define the radiopaque and volumetric absorbing models for thick-gauge thermoplastic sheet. I call these models the Distributed Parameter Models (DPM) where conduction plays an important role in energy transfer from sheet surface to core. This is preparatory to my solving the arithmetic for these models.

How Important Is the Volumetric Absorption Concept? Part 3 - DPM
Jim Throne, May 2017

This is the third of a three-part series examining the role of volumetric absorption in heating of thermoplastic sheet. In this paper I compare the traditional radiopaque distributed parameter transient one-dimensional heat conduction model (DPM) with a transient heat conduction model with internal heat generation, viz, volumetric absorption of inbound radiant energy. It is apparent from calculations for two sheet thicknesses and two plastics that the two models produce distinctly different temperature profiles. I conclude that more attention needs to be paid to the role volumetric absorption of inbound radiant energy plays in the heating of both thin and thick plastic sheet.

Fabrication of Polypropylene Bio-Composites Utilizing Camelina Press Cake
Brent Tisserat, Mark Berhow, Louis Reifschneider, May 2017

Camelina (Camelina sativa (L.) Crantz, family Brassicaceae) is an emerging oilseed crop which produces high oil content but has a press cake that contains glycosinolates which are potential health risks if employed as an animal feed. As an alternative to a dietaric use Camelina press cake (CAM) was employed as a filler material to fabricate lignocellulosic plastic composites (LPC). LPCs were generated by blending polypropylene (PP) with 25% or 40% CAM with 0% or 5% by weight of maleated PP (MAPP) via a twin screw compounding and injection molding. Injection molded test specimens had mechanical and flexural properties comparable to neat PP.

A Method for Controlling the Mold Filling Volume for BMC Injection Molding
Nicolina Topic, Reinhard Schiffers, Stefan Moser, Dietmar Drummer, May 2017

Bulk molding compound (BMC) compositions are characterized by a comprehensive property profile, which makes this thermoset material attractive for a wide range of high-performance applications. BMC processing by injection molding allows high production rates and the fabrication of parts with a considerable shape complexity. Although the injection molding machine offers a high reproducibility and process reliability, several effects such as material induced disturbances or changing ambient conditions may cause fluctuations in BMC injection molding. The result is a varying part quality for example in the form of volumetric filling differences which causes rejects. The manual adaption of certain process setting parameters presents a possibility to react on disturbances in order to achieve constant part properties. However, the outcome of these adjustments is dependent on the experience of the operator, since an accurate knowledge of the influence of certain setting parameters on individual part quality features is required. In this paper a correlation between process setting parameters and the part filling volume for BMC injection molding is introduced and discussed. The main aim is the development of an adaptive machine function which autonomously compensates occurring disturbances and ensures a constant part filling in BMC injection molding.

Model Investigation of the Cooling Error
Fabian Ullrich, Bernhard Gesenhues, May 2017

Uniform cooling plays a large role in the production of high quality plastic parts. However, simulations to help with this task are often too expensive and complex to perform in the mold’s early design phases. The literature on this topic provides various equations dealing with this issue. The so-called ‘cooling error’ presents an example of the issues surrounding uniform cooling. Some strange experiences with the equation describing the cooling error revealed the need to validate it. This paper examines the cooling error through thermal FEM simulations. The simulated results are then compared to those of the equation given in the literature. It turned out that it is necessary to re-evaluate the equation. Thereafter, the usefulness of the equation is analyzed with further thermal analysis.

A New Test Setup for Testing Polyethylene Tubes under Constant and Cyclic Internal Pressures
Siavash Vahidi, E. Schruba, Y. Sun, M. McCarthy, Y.G. Hsuan, May 2017

A test system was designed to evaluate the failure behavior of a thin-wall small-diameter polyethylene tube under internal pressure. The test setup was capable of delivering constant (static) and cyclic (dynamic) pressure patterns as well as maintaining an elevated testing temperature to accelerate the failure. Desired pressure patterns were obtained by controlling the opening/closing duration of the solenoid valves accordingly. A water-sensing system was used to detect the failure time, particularly for small brittle failure. A data acquisition system based on LabView™ was used to control and record the applied pressures and the failure times. The constant pressure tests were performed at 65 and 75°C and the cyclic pressure tests were performed at 75°C. The test data obtained from the constant pressure tests exhibited two distinguishable linear regions in a log-log plot of hoop stress versus failure time. Slope values of -0.034 and - 0.113 were obtained for ductile and brittle regions, respectively. A brittle failure curve with slope of -0.039 was obtained under the cyclic pressure testing condition. The slow crack growth (SCG) failure was considerably accelerated by the cyclic loading.

Role of Polymer Film Mechanical Behavior in Liquid Packaging Application: Deformation Modeling of Gelbo Test
Pavan Valavala, Ashish Lokhande, Piyush Thakre, Siddharth Athreya, Jeff Zawisza, Sam Crabtree, Rajen Patel, Ty Berilgen, Lamy Chopin III, May 2017

Package integrity assurance for liquid packaging is of paramount importance to safety of packaged products. A transportation related failure mode is described as the development of pinholes in the package. ASTM F392 (Gelbo test) is often used as a screening tool for selecting materials for liquid packages. The objective of the current study is to develop an understanding of the mechanics of the film deformation during this test to help identify mechanical properties of interest. The model predicts that ‘bending rigidity’ and stiffness/toughness ratio of the film play an important role in the performance of the material in a Gelbo test based on simplified assumptions for material behavior. These predictions were verified with experimental data.

Modeling Flexible Package/Granular Material Interation through Combination of Discrete Element Method (DEM) and Finite Element Method (FEM)
Pavan Valavala, Wenbo Xu, Mark Mirgon, Sam Crabtree, Lori Kardos, Didem Oner-Deliormanli, May 2017

A variety of applications use flexible film for shipping solid granular materials. The film/packages must have sufficient toughness and/or strength to endure impact during shipping and handling. Package performance is commonly evaluated using a drop test typically from a certain height specified by ASTM and/or ISTA standards. One limitation of the drop test is that it can only qualitatively determine whether a package will survive. In order to better understand impact type loading which can lead to package failure, more quantitative information such as stresses/strains developed during the drop tests is required. We have developed a model to simulate drop tests of a flexible package containing solid particles. The model utilized some of the capabilities available in Abaqus software package, such as Abaqus/Explicit, Finite Element Method (FEM), and Discrete Element Method (DEM) to capture the interaction between the flexible package and a large amount of solid particles inside. Preliminary results compare well with drop tests carried out in our laboratory.

Flax Fiber-Polyamide 6 Composites via Solid-State Shear Pulverization: Expanding the Portfolio of Natural Fiber-Reinforced Thermoplastics
Katsuyuki Wakabayashi, Simon H. E. Vancoillie, Mekdes G. Assfaw, Frederik Desplentere, Aart W. Van Vuure, May 2017

A chilled twin-screw extruder-based processing technique called solid-state shear pulverization (SSSP) explores an opportunity to create a new set of composites made from temperature-sensitive natural fibers and high-temperature melting thermoplastics. Model polyamide 6/ flax fiber composites produced with SSSP are compared to those made by conventional compounding methods. Mechanical property tests indicate that SSSP can defibrillate the flax into elementary fibers, which have superior specific mechanical properties, while retaining the fiber lengths above the critical values. SSSP can produce PA6/flax composites on an industrial scale without excessively degrading or damaging fibers.

Tecobax™ – A New Class of Non-softening Thermoplastic Polyurethanes for Medical Applications
Tony Walder, David Cozzens, Walid Qaqish, Michael J. Wiggins, Murty Vyakarnam, May 2017

Thermoplastic polyurethanes (TPUs) are a class of thermoplastic elastomers (TPEs) that are used in a variety of medical applications. Their characteristics including low temperature flexibility, excellent abrasion resistance, high tensile strength, good processing characteristics, and biocompatibility make them particularly attractive for medical applications by the device design engineers. In general current medical grade TPUs have the unique property of undergoing a reduction in flex modulus when placed in the body. This characteristic is referred to as “softening.” A new class of TPUs has been developed that retains many of the characteristics found attractive by designers but now offers the non-softening characteristic, broadening the design space for TPUs in medical devices. A non-softening TPU may be an attractive material for use in percutaneous interventional catheters where retention of stiffness is desired to enhance trackability and torqueability. Three grades of non-softening TPUs, covering low to mid durometers have been introduced into the market: Tecobax™ 25D, 40D, and 45D. The performance characteristics of these TPUs were measured and compared to other softening TPUs as well as non-softening TPEs. These materials maintain many of the typical TPU characteristics which make them widely used. For example, the 25D, 40D and 45D durometers have excellent tensile strengths and abrasion resistance. Softening characteristics were tested by comparing flexural modulus values at ambient conditions (22°C, 50% RH) to body conditions (100% RH, 37°C). The degree to which these new materials soften, especially in the harder grades, is significantly less than other TPUs but is comparable to non-softening TPEs. Torqueability at body conditions is also comparable to common non-softening TPEs. These materials also offer other unique characteristics which are of particular interest to the medical device community. For example, these materials have a high Vicat softening temperature; the 40D and 45D are above 100°C, resulting in compatibility with steam sterilization. In addition, these materials produce excellent quality extrusion components using standard extrusion equipment. Other unique characteristics and potential medical applications will be discussed.

Direct Particle Level Simulation Coupled with the Folgar-Tucker Rsc Model to Predict Fiber Orientation in Injection Molding of Long Glass Fiber Reinforced Thermoplastics
Ian Walter, Sebastian Goris, Jan Teuwsen, Andres Tapia, Camilo Perez, Tim Osswald, May 2017

Polymer Engineering Center at the University of Wisconsin-Madison has developed a particle level simulation model to predict fiber motion at industry relevant fiber concentrations. The model provides a solution to study fiber alignment for long and short fiber-reinforced thermoplastics at the particle level by accounting for all relevant effects, including fiber-fiber interactions. This simulation couples with the Reduced Strain Closure (RSC) Folgar-Tucker model to describe the orientation evolution and interaction coefficients for fibers placed in a simple shear flow. In this work, the process is outlined and the results are compared to existing models for predicting interaction coefficients. Results are then compared to those obtained through injection molding experiments of long glass fiber-reinforced polypropylene. A new relationship between fiber aspect ratio and volume fraction will then be proposed.

Crystallographic Matching Effect in Self-Induced Nanohybrid Shish-Kebab Structure of Poly(E-Caprolactone)
Xiaofeng Wang, Yanhong Gao, Yiyang Xu, Xuyan Li, Lin Jiang, Qian Li, May 2017

The shish-kebab structure has been investigated for many years and it has been widely applied in many field, while the formation mechanism is attracting researcher. In this study, different electrospun poly(e-caprolactone) (PCL) fibers were applied as shish material in the self-induced crystallization and two different self-induced crystal structure were obtained. By comparing with the surface crystalline structure, it seems that the self-induced nanohybrid shish-kebab (SINSK) structure follows a crystallographic matching mechanism in the crystallization process. The PCL fibers with different internal crystalline structure led to different induced crystal lamellae morphology. This study might helps people to screen the materials for formation of SINSK structure.

Study of Residence Time Distribution for a Blown Film Line Using Inline UV-VIS Spectroscopy and Optical Imaging on a Film Bubble
Jin Wang, Christopher Thurber, Michael Bishop, Daria Monaenkova, Hyunwoo Kim, Ellen Keene, Xiaoyun Chen, May 2017

Residence time distribution (RTD) in an extruder has been studied extensively, but not many experiments have focused on the RTD in an extrusion based production process, such as a blown film line. Two inline methods on the film bubble, i.e., UV-Vis spectroscopy and optical imaging, were verified to measure the RTD in a lab scale blown film line using copper phthalocyanine tracer pulses. Both methods measured similar RTD results and can be used for research and troubleshooting of the blown film line. A full factorial design of experiments was also conducted to study the effects of rate, blow up ratio, tracer type, and tracer concentration on the measured RTD by UV-vis spectroscopy. The results showed that rate was the strongest factor for the RTD in the blown film line (as expected), blow up ratio had no effect, and tracer type and tracer concentration has some minor effects.

Relationship of Shear History, Morphology – Microstructure and Mechanical Properties of Micro Injection Molded Parts
Lixia Wang, Lin Jiang, Jiajia Wang, Yiping Zhou, Xuecheng Yang, Qian Li, May 2017

The relationship of shear history, morphology-microstructure and mechanical properties of the micro-scale parts was investigated based on the polypropylene parts with thickness 0.2mm and 0.5mm molded under varied injection speed. Shear rate was analyzed using Moldflow. 0.5 mm parts showed skin-core structure in the thickness direction with imperfect shish-kebab structure appeared in the transition layer between skin layer and core layer, however, the transition layer of 0.2 mm parts shows columnar crystal. The whole shear level in shear history increased with injection speed increasing for all the parts with two thicknesses. The ratio of skin layer of 0.5 mm parts decreased as the injection speed increased, which result in the decreasing of yield stress, modulus, breaking strength and elongation at break. The ratio of skin layer of 0.2 mm parts increased with injection speed increasing, and results in increasing of yield stress, modulus and breaking strength, and decreasing of elongation at break.

Simulation of Cell Growth in High-Pressure Foam Injection Molding
Chongda Wang, Vahid Shaayegan, Sejin Han, Franco Costa, Chul B. Park, May 2017

In this work, the prediction of final cell size of high-pressure foam injection molded parts has been attempted. An in-situ visualization technique was used to capture real-time cell growth data from high-pressure foam injection molding experiments conducted with PS and CO2. The simulated cell growth profile was compared with experimental measurements. For the PS/CO2 system, quantitative agreement (over 80%) between predicted and measured growth profile were achieved. With the validated simulation, the effect of cooling history on final cell size and cell size distribution was investigated. It is shown that in high-pressure foam injection during which all the gate nucleated cells are dissolved, final morphology is characterized by having large cells in the center and smaller cells near the skin.

Development of High Density Syntactic TPU Foam by Incorporation of Expancel through Extrusion
Wanqiao Wang, Linghong Li, Ali Anwer, Muhammad Anwer, Qinping Guo, Andrew Kenny, Hani Naguib, May 2017

Extrusion was used to produce thermoplastic polyurethane foams using Expancel microspheres as a blowing agent. Few studies have looked into syntactic thermoplastic polyurethane foams by extrusion, making it a topic worth exploring. The density of the foams is reported in terms of cell size and cell density using 0.05wt%, 0.1wt%, 0.3wt%, 0.4wt%, 0.5wt%, 0.8wt%, and 1wt% of Expancel. The resulting foams were characterized mechanically in terms of tensile modulus. In general, specific gravity and tensile modulus decrease with increasing addition of foaming agent.

Selective Laser Sintering Processing Behavior of Polyamide Powders
Yuanyuan Wang, Christina M. DiNapoli, Gabby A. Tofig, Ross W. Cunningham, Raymond A. Pearson, May 2017

Selective laser sintering (SLS) is a rapid developing additive manufacturing process. It produces parts by selectively sintering powder together in a layer-by-layer mode. SLS processing behavior were investigated with a desktop printer for commercial polyamide/carbon black (PA/CB) powders and a fabricated PA12/silica nanocomposite powder. By systematically increasing thermal and laser energy received by powder, low laser power (2 W) was sufficient for successfully sintering PA11/CB, PA12/CB and PA12/silica powders. PA11/CB exhibited a wider processing window for part bed temperature than PA12/CB. Printed PA11/CB parts yielded well and elongated up to 65%, while PA12/CB parts broke before yielding. Both were of ultimate tensile strength above 50 MPa. An in-house prepared PA12/silica nanocomposite powder tolerated higher bed temperature than powder without silica in it. Incorporation of silica nanoparticles into SLS powder brought comparable tensile strength and elongation at break to parts printed without silica in the powder while tensile modulus was noticeably increased. Finally, DSC is a useful tool to evaluate degree of powder melting during SLS.

New Developments in Polymers for Medical Device Housings
Cheryl Weckle, Pascal Lakeman, May 2017

Trinseo LLC has long served the medical device market with a wide range of PC, PC/ABS and ABS grades, including glass-filled and ignition-resistant (IR) materials. In order to continue to meet the more demanding performance requirements for engineering plastics in medical device housings, Trinseo has developed a number of new PC compounds (HB and V-0) that can tolerate multiple cleanings using aggressive disinfectants in both hospital and home environments. This chemical resistance requirement for equipment housings is due to the necessity of reducing the incidence of hospital acquired infections (HAI’s) that are the cause of billions of dollars in health care costs and many thousands of deaths annually. We will review these new chemical resistant materials, discuss the mechanism of how they work, and discuss their performance attributes and breadth of applications that they are suited for. These grades exhibit a superior combination of toughness and easy processing, excellent color stability as well as excellent durability.

Numerical Simulation of Discontinuous Slow Crack Growth of Semi-Elliptical Surface Crack in Polyethylene Based on Crack Layer Theory
Jung-Wook Wee, Byoung-Ho Choi, May 2017

For the structural application of engineering thermoplastics, the knowledge of failure modes depending on their service conditions is essential. The most prevalent failure mode is brittle fracture followed by the slow crack growth (SCG) initiated by surface flaws. In that the general geometry of the surface flaws is semi-elliptical, it is vital to investigate the SCG aspects from such kind of shape. The simple strategy which has been employed to predict the crack growth aspect is an application of conventional law, Paris-Erdogan relationship. The approach is regarded as quite simple since only stress intensity factor (SIF) is needed for a crack driving force term. However, through this empirical relationship, the SCG in engineering thermoplastics cannot be properly modeled. For example, in case of the high-density polyethylene (HDPE), frequently used for water transportation pipelines, the crack usually propagates discontinuously. It arises from the existence of a significant damaged zone in front of the main crack tip, which is normally observed in engineering thermoplastics. Thus, adopting one linear elastic fracture mechanics (LEFM) parameter may not reflect the severe damage zone. To handle this feature properly, a theoretical approach with a reflection of such energy dissipation is necessary. In this study, the crack layer (CL) theory was employed to simulate the discontinuous SCG of semi-elliptical surface crack in HDPE plate with finite thickness. The existing 1-dimensional CL theory was expanded to the semi-elliptical crack growth.

Nanocomposites from Lignin-Containing Cellulose Nanocrystals and Poly(Lactic Acid)
Liqing Wei, Umesh Agarwal, Nicole Stark, Ronald Sabo, May 2017

Utilizing lignin-containing cellulose nanocrystals (HLCNCs) as reinforcing agents to poly(lactic acid) (PLA) for nanocomposites was studied for the first time. The PLA/HLCNCs nanocomposites were prepared by extrusion and injection molding. The freeze-dried HLCNCs showed micron scale agglomerates. As indicated by the water contact angle measurements, the HLCNCs were more hydrophobic than dealkaline lignin and traditional, lignin-free CNCs derived from high cellulose content wood pulp. Thermogravimetric analysis (TGA) showed that the HLCNCs started to degrade at about 300°C. The thermal stability of nanocomposites was slightly lower than neat PLA. The Young’s modulus of nanocomposites containing 1%, 2% and 5% CNCs was improved by 21.0%, 18.4% and 17.7%, respectively, while the strain at break was improved by 73.2%, 63.4%, and 54.9% compared to neat PLA. The nanocomposites (PLA/2%HLCNC) exhibited increased microductility and plastic deformation over neat PLA during tensile test. No statistically significant changes in the tensile strength were found with HLCNC addition. The results provide some practical and fundamental insight of PLA/HLCNCs nanocomposites to be used for flexible packaging films. Future work to improve the dispersion of HLCNCs in the PLA matrix as well as in the CNC drying approach is suggested.

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