The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
|= Members Only|
DECISION TREE CLASSIFIER FOR ANALYSIS OF PARAMETERS ASSOCIATION CAUSING POLYMER COLOR MISMATCH
Nowadays, most manufacturing companies store their data electronically. The selection of the appropriate data mining algorithm for exploration of this data can quickly identify issues leading to process improvement and cost reduction. In this paper, The Decision Tree Classifier (DTC) is used for plastic color mismatch parameters analysis. Especially, the relationship between polymer grade, color, type, line of production, and ingredients supplier is analyzed. DTC Results showed interesting and evident relationships between certain parameters.
DIELECTRIC BEHAVIOR OF POLY(VINYLIDENE FLUORIDE)/GRAPHENE COMPOSITES WITH LOW PERCOLATION THRESHOLD
Poly(vinylidene ?uoride) (PVDF)/graphene composite was successfully fabricated by a solution-cast and hot- pressing method. The composite material with graphene as conductive ?ller exhibited a very low percolation threshold (0.0018 volume fraction), but the dielectric constant was enhanced signi?cantly. The largest dielectric constant of 7940 was observed for the PVDF/graphene composite with 0.0177 graphene volume fraction at 100 Hz. Large enhancements of the ac conductivity and loss tangent were also observed for the composites with graphene content near the percolation threshold. The percolation theory was used to explain the dielectric behavior of the composite.
THE EFFECT OF FEEDING PROFILE IN THE DISTRIBUTION OF CHAINS COMPOSITION AND MECHANICAL PERFORMANCE OF STYRENE/BUTYL ACRYLATE EMULSION COPOLYMERS
A semicontinuous process was used to prepare copolymers varying the feed composition profile, to vary in a gradual manner the composition of the copolymer chains being formed through an emulsion reaction, for the (50/50, w/w) styrene/butyl acrylate system. With the cumulative composition of the copolymers (1H-NMR), the weight distribution of chains composition (WCD) was estimated, constructing a histogram that is used to elucidate the mechanical behavior (DMA, stress-strain and, impact strength) of the synthesized copolymers.
EVALUATION OF DEGRADATION OF BACK-SHEET FOR PHOTOVOLTAIC PANELS
To expand use of photovoltaic generation, there is a real need for reducing cost of generating by photovoltaic panels. One of cost-cutting of power generation is to prolong its service life. It is very important to prevent moisture from penetrating the back-sheet for insuring the long-life operation of photovoltaic panels. In this study, the correlation was evaluated between mechanical property and partial discharge of degraded polyethylene terephthalate film for the back-sheet.
POLYMER COMPOSITES WITH HOLLOW GLASS MICROSPHERES: PROCESSING, PROPERTIES AND APPLICATIONS
Reducing the weight of thermoplastics and rubber parts has been a paramount objective in various industries such as transportation, aerospace, hand-held electronics and sports and leisure. 3M ™ Glass Bubbles (hollow glass microspheres) are light weight micro additives specially engineered to withstand temperature, stress, and deformation gradients in a wide range of polymer processes ranging from liquid phase polymer processing to high viscosity melt compounding and high pressure injection molding. We will present factors influencing glass bubble survival and discuss processing methodologies to achieve the highest level of bubble survival for a given polymer grade, specifically during twin screw extrusion compounding and injection molding. We will then analyze application examples and demonstrate how the plastics industry and associated OEMs can exploit the light weight advantages of these novel additives while improving the processing and end-product properties without resorting to costly equipment modifications.
VALVE GATE OPTIMIZATION FOR INJECTION MOLDING OF AN AUTOMOTIVE INSTRUMENT PANEL
Injection pressure, an important factor in injection molding process, should be minimized to enhance injection molding quality. In this study, we decided the locations and open timings of valve gates to minimize the maximum injection pressure. To solve this problem, we integrated MAPS-3D (Mold Analysis and Plastic Solution-3Dimension), a commercial injection molding analysis CAE tool, using the file parsing method of PIAnO (Process Integration, Automation and Optimization) as a commercial process integration and design optimization tool. In order to reduce the time for obtaining the optimal design solution, we performed an approximate optimization using a meta-model that replaced expensive computer simulations. To generate the meta-model, computer simulations were performed at the design points selected using the optimal Latin hypercube design as an experimental design. Then, we used micro genetic algorithm available in PIAnO to obtain the optimal design solution. Using the proposed design approach, the maximum injection pressure was reduced by 35.1% compare to the initial one, which clearly showed the validity of the proposed design approach
DEVELOPMENT AND CHARACTERIZATION OF LOW DENSITY POLYETHYLENE/CELLULOSE MICROFIBRIL COMPOSITES
Banana microfibrils were prepared from banana fibre obtained from the pseudo stem of the banana plant by steam explosion process. Alkali and acid treatment coupled with high pressure defibrillation was found to be effective in the depolymerization and defibrillation of the fibre to produce the microfibrils. The different stages of steam explosion process were studied by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Atomic Force microscopy studies (AFM) revealed that the surface of the microfibrils were rough. The prepared micro fibrils were subjected to chemical treatments with potassium permanganate (KMnO4) and benzoyl chloride. Low density polyethylene (LDPE)/microfibril composites were prepared by injection molding. The dielectric and mechanical properties of composites and chemically treated microfibril composites were investigated. Dielectric constant of LDPE/microfibril composite was found to be greater that of neat LDPE. Chemical treatments reduced the dielectric constant of the composite. The mechanical properties were found to be increasing upto 20% microfibril loading. Chemical treatments further enhanced the mechanical properties of the composite.
RAPID HEATING AND COOLING SIMULATION FOR THE INJECTION MOLDING PROCESS
In recent years, injection molding technologies have been developed which use variable mold heating and cooling to improve surface finish and general part quality without significantly increasing cycle time. Simulation of these processes requires a transient time dependent mold thermal analysis. This paper presents the further development of a 3D finite element based transient mold cooling simulation capability to include the rapid heating and cooling cycling of the mold. The various rapid heating and cooling stages are explained as well their effect on the part during filling.
INVESTIGATION OF DYNAMIC MECHANICAL PROPERTIES OF METAL-POLYMER FILAMENT FOR FUSED DEPOSITION M0DELLING
POM or polyoxymethylene is an engineering resin used primarily for injection molded parts that replace metal. POM’s usefulness is derived from the combination of strength, stiffness, toughness, creep resistance, and lubricity. POM homopolymer and copolymer compete in this market space. Homopolymer grades have some mechanical advantages while copolymer grades have better thermal and chemical stability. In 2010 Ticona introduced a new high strength, high viscosity POM copolymer with the mechanical properties of a typical homopolymer, while maintaining copolymer stability. This paper introduces an improved flow, high strength POM copolymer, its property profile, salient features and potential applications.
DURABILITY, RELIABILITY AND SAFETY STUDY OF POLYMERS USED IN PHOTOVOLTAIC MODULES
The primary objective of this study was to investigate the effect of damp heat (DH) and ultraviolet light (UV) exposures on the properties and performance of polymeric materials in photovoltaic (PV) modules. The study covers the evaluation of ethylene vinyl acetate (EVA) encapsulant, TPE (PVF/PET/EV A) substrate, and laminate coupons and modules as a function of exposure time to DH (85°C, 85% RH), and UV (100W/m2, ~2 suns UV irradiance). The results showed that DH exposure had a greater aging effect than UV, and the materials exhibited a greater degree of degradation with increasing exposure time.
EFFECT OF PROCESS VARIABLES ON THE PROPERTIES OF SUPERCRITICAL CO2 FOAMED PS/GRAPHITE NANOCOMPOSITE FOAM
Polystyrene / nano-graphite nanocomposite foams were made by melt compounding and in-situ polymerization. The foam was made by batch foaming. The cell morphology was improved with the advanced dispersion of the nanoparticles. In-situ polymerization provided better dispersion and the resulting nanocomposite foam had fine cell size. Adding nanoparticles as a nucleating agent can make foams at a lower foaming pressure. This discovery creates a new route to produce microcellular foams at a low foaming pressure.
DESIGN OF INDUCTION HEATING MODULE FOR UNIFORM CAVITY SURFACE HEATING
Electromagnetic induction heating has many advantages such as fast heating, low energy consumption and environmental pollution reduction. Using induction heating for rapid tool heating is more economic and efficient than any of the tool heating technique. Previous studies using electromagnetic induction heating for rapid tool heating indicate that the temperature uniformity on cavity surface is not easy to be achieved no matter with surface or insert type induction heating. In this paper, a series of experiments were conducted to study the effectiveness of temperature uniformity on mold cavity surface for different induction heating coil. The parallel type coil and magnetic flux concentrators were adopted to form the induction heating device. According to the results of heating experiments, the surface temperature of 10 mm thickness hot work die steel (JIS SKD61) could rise from 50°C to 150°C in 15 seconds and the temperature uniformity of the heated zone reached 94%~95%.
FABRRICATION OF HIGHLY TUBULAR POROUS CHITOSAN/POLY (DL LACTIC-CO-GLYCOLIC ACID) (PLGA) NANOCOMPOSITE STRUCTURES INTENDED FOR TISSUE ENGINEERING SCAFFOLD APPLICATIONS
In this study, highly tubular porous chitosan/poly (DL lactic-co-glycolic acid) (PLGA) nanocomposite structures were produced via electrospinning and unidirectional freeze drying techniques. The 3D porous structure of chitosan/PLGA was characterized by scanning electron microscopy (SEM). The properties of the chitosan/PLGA nanocomposite, including porosity, water absorption, and mechanical properties, were investigated. The results showed that a highly tubular porous structure with nano-topography was formed and the compressive modulus increased greatly due to the addition of PLGA nanofibers.
ACCELERATED CHARACTERIZATION OF THE RESISTANCE AGAINST CRACK INITIATION AND SLOW CRACK GROWTH OF POLYETHYLENE FOR GEOMEMBRANE APPLICATION UNDER THE INFLUENCE OF MEDIA
Two different HDPE-grades were investigated concerning media-resistance. Cyclic tests with CRB-specimen were conducted under three different configurations, tests on exposed and unexposed specimens and tests in a special glass cell with a liquid environment. Additionally conventional immersion-tests with subsequent tensile-tests, OIT-measurement and Infraredspectroscopy were done. A swelling effect of both media and a skin-deep chemical aging was evidenced. Cyclic CRB tests showed comparable results with more pronounced effects for the results of the media cell.
MELT EXTRUSION OF A PHARMACEUTICAL COMPOUND CONTAINING A POORLY SOLUBLE THERMOLABILE DRUG
Solid dispersions of the poorly soluble, thermolabile drug Artemisinin in a polymer matrix have been developed using twin screw extrusion. Artemisinin is a particularly challenging drug to use in melt extrusion due to its inherently temperature and process sensitive nature. A co-polymer developed for pharmaceutical extrusion was used as the matrix material and experiments were performed to assess the suitability of this drug-polymer combination at a range of drug loadings and process conditions. The drug was found to act as a plasticizer during extrusion and to be miscible in the polymer matrix. Artemisinin was found to be susceptible to degradation at extended residence times at process temperature. A half length extruder screw configuration was used to minimize degradation of the drug and this yielded optimum drug release rates.
BIO-BASED POLYAMIDES WITH INNOVATIVE FIBRES FOR ENGINEERING PARTS MATERIALS – PROCESS – CHARACTERIZATION - APPLICATIONS
Bio-based polyamides, such as PA 6.10/ Nylon 6.10 and PA 10.10, were compounded with different cellulosic fibers for injection molding applications. PA 6.10 is partly bio-based (>60%) and possessing properties very similar to those of common PA 6. The melting point of PA 6.10 is 220°C and therefore compounding with thermally sensitive cellulose fibres is a challenge. A compounding process for engineering polymers, like polyamide with cellulose fibres, was developed and optimized. It is gentle to the fibers, even at temperatures above 200°C. Furthermore, the molding process parameters were also optimized. Different mechanical properties were studied. The high impact behavior and lightweight potentiality were analyzed for bio-composites with cellulosic fibres.
PREDICTION OF ELASTIC MODULUS OF HYBRID INJECTION MOLDED COMPOSITE
The main drawback of natural fiber reinforced composite is their low mechanical properties. In order to overcome this problem, the hybridization of natural fiber with synthetic fiber was proposed. This work is focused on evaluation of mechanical properties in particular elastic modulus of short glass-jute fiber hybrid polypropylene composite. The specimens have been fabricated by injection molding with different jute/glass fiber hybrid ratios. Experimentally, the tensile modulus of hybrid composite increased with increasing jute fiber content. Theoretically, the elastic modulus is predicted by using classical lamination theory (CLT). The fiber orientation was determined from the fracture surface observation method. Prediction by CLT showed close agreement with experimental values with a maximum deviation of about 5.6%.
FALLING DART IMPACT BEHAVIOUR OF POLYCARBONATE AND MICROCELLULAR POLYCARBONATE FOAMS
Foamed polymers are well know for a high energy absorption and mechanical and acoustic damping. Foams in these applications were usually produced by extrusion or reaction foaming. Based on this fact, injection moulded foams are rarely analysed with regard to their damping behavior at dynamic load. This investigation deals with the analysis of injection moulded polycarbonate foams, produced with physical blowing agent. The materials were characterized with an falling dart impact test setup. An analysis of the dependence of temperature, the influence of the applied load and the molecular weight of the polycarbonate was carried out.
INVESTIGATION OF PROCESSING AND RHEOLOGICAL PARAMETERS EFFECT ON FILM BLOWING PROCESS STABILITY BY USING VARIATIONAL PRINCIPLES
In this study, a numerical stability analysis of the film blowing process is performed considering non- isothermal processing conditions, non-Newtonian behavior of the polymer and physically limiting criteria (maximum tensile and/or hoop stress) in order to investigate the complex relationship between processing conditions (internal bubble pressure, heat transfer coefficient, mass flow rate, cooling air temperature, melt/die temperature), material parameters (extensional viscosity, rupture stress, Newtonian viscosity, flow activation energy, power law index) and film blowing stability.
STRENGTHENING THE MESSAGE OF SUSTAINABLE PLASTICS PACKAGING
Recyclable, recycled-content, or bio-based plastics packaging will require more than just the right technologies and materials for sustained growth. Sustainable packaging acceptance and use will also require increasing the number of informed, enthusiastic retailers and packaging consumers interested in being “greener.” In short, their positive attitudes must be turned into buying and recycling behaviors. This paper focuses on one way in which packaging producers are drawing consumers’ attention to the recycled-content, recyclability, or bio-basis of new plastic packaging. Simple messages on the packaging itself not only can clarify green claims about the packaging, but can also serve as calls for consumer action. This paper considers the effectiveness of various messages and, referencing the U.S. Federal “Green Guides,” considers the ways in which a clear, honest sustainability claim can be communicated to both informed and skeptical audiences.
We're sorry, but your current web site security status does not grant you access to the resource you are attempting to view.
Any article that is cited in another manuscript or other work is required to use the correct reference style. Below is an example of the reference style for SPE articles:
Brown, H. L. and Jones, D. H. 2016, May.
"Insert title of paper here in quotes,"
ANTEC 2016 - Indianapolis, Indiana, USA May 23-25, 2016. [On-line].
Society of Plastics Engineers
Note: if there are more than three authors you may use the first author's name and et al. EG Brown, H. L. et al.
If you need help with citations, visit www.citationmachine.net