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The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
CHANNEL FLOW SIMULATION WITH DELAYED FOLGAR TUCKER FIBER ORIENTATION MODEL
Syed Mazahir, Gregorio Velez-Garcia, Peter Wapperom, Donald Baird, May 2012
A 2-D channel flow simulation is performed with delayed Folgar Tucker model for rigid short glass fiber orientation. The continuity and Navier-Stokes equations are discretized using Galerkin finite element method and the constitutive equation for fiber orientation is discretized using discontinuous Galerkin finite element method. Material parameters have been taken from a study conducted earlier in our group. The effect of fountain flow is included in the simulations by using a pseudoconcentration method and performing a full solution of balance equations.
IN SITU GENERATED BICONTINUOUS REINFORCEMENTS
O. Sinan Yordem, Alan J. Lesser, May 2012
The principle subject discussed in the current study is a method to form bicontinuous reinforcement within a polyether ether ketone (PEEK) polymer matrix by using metal stearates as fillers. X-ray scattering, differential scanning calorimeter, dynamic mechanical analysis (DMA) and melt rheology were used to investigate the dynamics of the material and the structure of the components. Metal stearates affect the packing of PEEK molecules and reduce the total crystallinity by slightly changing the crystal growth of PEEK with no change in unit cell of PEEK. Melt rheology and DMA results suggest that PEEK is a dominant phase in the composites and the metal stearates form a secondary continuous phase in the polymer resin. The reinforcing effect of the metal stearates at low temperatures is maintained up to their softening temperature around 100°C beyond which PEEK begins to dominate the mechanical behavior. Effective moduli of metal stearates in composites suggest that the secondary metal stearate phase forms bicontinuous morphology.
THE SYNERGISTIC EFFECT OF SIO2 ON THE FLAMMABILITY PROPERTIES OF INTUMESCENT FLAME RETARDED POLY(EHTENE-CO-OCTENE) ELASTOMER (POE)/ POLYPROPYLENE(PP) BLENDS
Wu-Zhenghuan, Qu-Jinping, Zhao-Yongqing, Wen-Jinsong, May 2012
As a toughening agent, poly(ehtene-co-octene) elastomer (POE) could raise the notched impact strength of polypropylene(PP), especially in low temperatures. Ethylene-octene/ polypropylene blends were widely used in many domains. An Intumescent flame retardant and SiO2 were introduced into ethylene-octene/ polypropylene blends as flame retardant and its synergistic agent. The flame retardancy of the new system was estimated with the UL94 test, cone calorimeter test, of which contained heat release rate test and smoke release rate test, and Thermogravimetric property was also investigated. According to the results of flammability tests, the SiO2 showed synergistic effect apparently when its content reached 1%(weight percent of the whole system, the same below).
GLASS FIBER REINFORCED ENGINEERING PLASTICS SIZING AN ESSENTIAL COMPONENT FOR PERFORMANCE
Jaap van der Woude, Piet Leegstra, May 2012
Fiber glass reinforced engineering plastics are increasingly important construction materials in transportation, electrical and other field applications. With the use of fiber glass reinforcements, certain material properties such as stiffness, strength and temperature stability are significantly improved. Combined with the base plastics, attractive material properties are obtained making them suitable for very demanding applications. Traditional performance attributes such as mechanical and environmental properties, reductions in total part cost as well as lightweight benefits allow these materials to provide answers to more complex applications, while meeting lightweight, recyclability, food contact and other requirements. It is essential to use the right fiber glass product with the right sizing specific to the application. Sizing provides a powerful solution for many processes and performance attributes of short fiber compounds and allows the final product to meet a variety of additional requirements. In this paper, the latest developments in glass fiber reinforcement will be reviewed, focusing on some of the most important engineering plastics such as polyamide, polyester and others. It will be demonstrated how very small amounts of glass fiber sizing can be very effective in realizing performance attributes over a wide range of requirements. In addition, examples will show how glass fiber reinforcements can greatly enhance the performance of certain biopolymers.
DETECTING POLYMER LONG CHAIN BRANCHING STRUCTURES BY USING ANALYTICAL RHEOLOGY
Xue Chen, Ronald Larson, May 2012
Polymer rheology is a very sensitive indicator of polymer long chain branching, and therefore can be used as a tool to determine polymer structures. This paper is thus focused on the study of the relationship between polymer linear viscoelastic properties and polymer structures using both rheological experiments as well as theoretical modeling methods applied to both model polymers and commercial polymers. In this work, the “hierarchical model” was employed to predict their rheological behaviors as well as to identify the impurities in the materials using the “analytical rheology” concept. After validating the tube model theory successfully on the model polymer melts, we tried to access the validity of the modeling predictions for commercial polyolefins.
LOOK UPSTREAM TO AVOID ‘GIGO’ PITFALLS IN EXTRUSION
Jaime A. Gómez, May 2012
The American phrase ‘garbage in, garbage out’ (GIGO for short) succinctly describes a problem often faced by plastics extrusion processors worldwide: No matter how well an extruder extrudes, its output will not be on-spec if the input blend is off-spec. When formulation problems do arise, the on-line proportioning system draws initial troubleshooting focus. But the problem itself (or its underlying cause) may lie elsewhere, farther upstream. This presentation systematically addresses the major process operations prior to extrusion (and beyond to include the materials themselves) in an effort to indentify and avoid the various pitfalls that may plague reliably accurate formulation.
EFFECT OF BLEND COMPOSITION OF EPOXIDIZED NATURAL RUBBER AND FLUOROPLASTIC VIA DYNAMIC VULCANIZATION
Tharinee Thamronglerdrit, Rathanawan Magaraphan,, May 2012
This study is purposed to develop a thermoplastic elastomer via dynamic vulcanization made of epoxidized natural rubber (ENR) and poly(vinylidene fluoride) (PVDF). Rubber parts were mixed at room temperature by using two roll mill, then fed in twin screw extruder with thermoplastic parts to occur dynamic vulcanization for pre-cured stage and compression molding for post-cured stage. This research was emphasized on the contents of ENR, PVDF and curing agent including the addition of PLA that affected on the properties of the dynamically vulcanized blends in comparison to the ternary ones. Mechanical properties including tensile strength and hardness were observed. Oil swelling test was studied by using 4 fuel oil types which are gasohol 91, gasohol 95, E20 and E85 at room temperature. It was found that increasing thermoplastic and DBPH contents have enhanced the tensile strength, young’s modulus and oil swelling resistance. Addition of PLA gave similar results as non-additional ones in term of oil swelling resistance.
COMPARATIVE STUDIES ON THE CRYSTALLIZATION BEHAVIOR OF POLY ETHER KETONE (PEK)
Mathew Abraham, Sandeep Kumar, Veena Choudhary, May 2012
The paper describes the crystallization and melting behavior of poly (ether ketone), PEK , prepared by Gharda Chemicals Ltd, India and compared with PEK supplied by Victrex Plc, UK. The routes of synthesis of the two polymers are different. Gharda Chemicals synthesizes PEK using cheap chlorine based monomers whereas Victrex Plc, synthesizes PEK using expensive fluorine based monomers. Crystallization of PEK was studied under non-isothermal conditions with differential scanning calorimetry. Crystallization parameters were evaluated with standard equations and the results were interpreted on the basis of nucleation, crystallisation, and activation energy of crystallization. The behavior of Gharda PEK and Victrex PEK was found to be comparable.
RHEOLOGY AND MELT FRACTURE OF POLY(LACTIDES)
Norhayani Othman, Bashar Jazrawi, Parisa Mehrkhodavandi, Savvas G. Hatzikiriakos,, May 2012
The wall slip and melt fracture behaviour of several commercial polylactides (PLAs) have been investigated. PLAs with molecular weights greater than a certain value were found to slip, with the slip velocity to increase with decrease of molecular weight. The onset of melt fracture for the high molecular weight PLAs was found to occur at around 0.2 to 0.3 MPa, depending on the geometrical characteristics of the dies. Addition of 0.5wt% of a poly(?- caprolactone) (PCL) into the PLA that exhibits melt fracture was found to be effective in eliminating and delaying the onset of melt fracture to higher shear rates.
OSHA’S COMBUSTIBLE DUST NATIONAL EMPHASIS PROGRAM AND COMBUSTIBILITY CHARACTERISTICS TESTING OF PVC RESINS AND PVC DUSTS
Richard Krock, Lawrence Halprin, Peter de la Cruz, May 2012
This paper provides an overview of the current and potential regulation of the hazards of combustible dust (CD) by the Occupational Safety and Health Administration (OSHA) and the influence of National Fire Protection Association (NFPA) standards and U.S. Chemical Safety Board (CSB) investigations on OSHA enforcement and rulemaking activities. This paper also presents the results of recent laboratory testing performed to determine the explosibility and other combustibility characteristics1 of samples of a variety of polyvinyl chloride (PVC) resin grades provided by resin producers. Explosibility testing was performed on samples of PVC dispersion resins, PVC copolymer resins, PVC suspension resins, and PVC dust particles sampled from a baghouse serving a PVC suspension resin production line. All test results fell into Class St 1, described as a weak explosion risk, when evaluated in a 20 liter test chamber. Because PVC resins by themselves do not have a known history of incidents where explosions occurred, this suggested the possibility that the test results from the 20 liter chamber test vessel reflected a false positive (or “overdriven”) situation caused by the ignition of the PVC particles as they passed through the flame of the ignition source rather than through the self-propagating deflagration that represents explosibility. As-received suspension resin samples from producers were retested for explosibility in a 1 cubic meter test chamber and the results indicated no explosion risk, falling into Class St 0. This suggests that, at least for the tested suspension resins, the test results from the 20 liter chamber test vessel reflected a false positive (or “overdriven”) situation and that the samples were not explosible. This paper was prepared for presentation at the SPE ANTEC on April 2, 2012.
TILTING DIE | THE CONVINCING NEW SOLUTION TO CENTRE AN ANNULAR DIE
Heinz Gross, November 2011
A totally new solution was developed to centre the die in regard to the mandrel of an annular die. The tilting technology overcomes most of the drawbacks of the existing conventional centering solutions. The new tilting technology can be easily retrofitted to existing heads for pipes | for blown films and for the extrusion blow molding process. Tilting dies enable to further reduce remaining eccentric thickness differences in the extruded products. So they help to improve the quality of the products while in the same time the cost of the production is reduced.
High Performance EVOH Nanocomposites of Interest in Packaging Applications
Eugenia Núñez | Jose M. Lagaron, November 2011
EVOH are materials with broad application in high barrier packaging due to transparency and superior oxygen barrier. However | these materials suffer from strong plasticization in properties due to sorption of moisture | which handicaps their application under high moisture conditions such as those applied in many packaging cases. This paper[1] shows the development of novel nanocomposites based on an optimized kaolinite grade | commercially marketed as O2Block® | which exhibit enhanced UV and gas barrier and decreased water permeability and sensitivity.
THE EFFECT OF COMPOSITION AND PROCESSING PARAMETERS ON THE MORPHOLOGY AND PROPERTIES OF PC/ABS/ORGANOCLAY NANOCOMPOSITES
Marianna I. Triantou | Petroula A. Tarantili, November 2011
In this study | blends based on poly(acrylonitrile-butadiene-styrene) (ABS) and polycarbonate (PC) were prepared and studied | in an attempt to explore the performance of mixtures deriving from recycling of waste electrical and electronic equipment (WEEE). The modification of ABS and ABS/PC blends via the incorporation of reinforcing fillers | such as organic modified montmorillonite nanoparticles (OMMT) | was also explored and its effect on the structure and properties was evaluated.
Failure Analysis of cracking HDPE cartridges. Optimization of Molding process using Dr. Taguchi Method of D.O.E.
S. Fuentes Purroy, November 2011
This paper’s goal is to explain how to achieve the optimum molding conditions that minimize the effect of stress cracking without removing the causes of degradation during service use. Analyzing failure of HDPE caulking cartridges: due to premature initiation of cracking and brittleness at the cartridge wall.
LATENT ACID CATALYSTS FOR THERMOSET PROCESS CONTROL IN ADVANCED COMPOSITES
Graham S. Murray, November 2011
Bac2 has developed a storage stable | molding material | incorporating a latent acid catalyst for the compression molding of advanced composite bipolar plates | key components of fuel cell stacks. The latent acid catalyst technology is used to control the reactivity of phenolic resins and furan bio-resins | by-products from plant sources. The process control imparted using the hydroxylamine based latent catalyst has extended the opportunity to use phenolic and furan binders in wider composite and adhesives applications.
MULTIBLOCK POLYESTER ELASTOMERS/ZINC OXIDE COMPOSITES: PREPARATION AND CHARACTERIZATION
Hande Celebi | Goknur Bayram | Aydın Dogan, November 2011
In this study, composites were obtained by introducing the zinc oxide (ZnO) fillers into the block copolymers of poly(butylene terephthalate) (PBT) and poly(tetramethylene oxide) (PTMO) by melt compounding method. The thermal conductivity and coefficient of thermal expansion of composites were investigated as a function of ZnO size and concentration. It was found that addition of ZnO increased thermal stability, while it decreased coefficient of thermal expansion of the composites at low temperatures (55 to 70 °C).
2,5-FURANDICARBOXYLIC ACID; A VERSATILE BUILDING BLOCK FOR A VERY INTERESTING CLASS OF POLYESTERS
Matheus A. Dam | Gert-Jan M. Gruter |, Laszlo Sipos | Ed de Jong | Dirk Den Ouden, November 2011
Avantium is developing a next generation bioplastics based on 2,5-furandicarboxylic acid (FDCA), called “YXY building blocks”, which can be produced on the basis of sugars and other, non-food, carbohydrates. Avantium aims to replace oil-based polyesters (such as PET) with Furanics polyesters (such as PEF) in a wide range of applications, including bottles and carpets.
IMPROVEMENT OF THE THERMAL DEGRADATION BEHAVIOUR OF PLLA/MWCNT COMPOSITES BY NANOTUBE PURIFICATION
Erlantz Lizundia | Jose-Ramon Sarasua, November 2011
The thermal degradation behaviour of poly (L-lactide) nanocomposites containing both as-received (MWCNT) and purified multi wall carbon nanotubes (p-MWCNT) was evaluated by means of thermogravimetric analysis (TGA). Composites with carbon nanotube contents of 0, 0.75, 1.25, 2.5, 4 and 5 wt. % were prepared. The thermal degradation process was analyzed in the light of Kissinger and Ozawa-Flynn-Wall (OFW) models revealing a lowering of the activation energy (E) due to iron and aluminium residues present in carbon nanotubes.
SILICONE MODIFIED BIOBASED COATINGS FROM SOYBEAN OIL FOR WATER RESISTANT PAPERS
Shilpa Manjure | Guoren Cheng | Dan Graiver | Ramani Narayan, November 2011
The silylation chemistry of biobased vegetable oils using alkoxy silanes has been studied and patented [1]. The objective of this work was to evaluate the application of the newly developed silylated soyabean oil formulation as a water-proof coating on paper. Paper coated with the silylated oil was tested for water resistance by measuring Cobb test. Results showed upto 95% improvement in water-proofing compared to an uncoated, unmodified paper.
NATURAL GAS AS MAIN ENERGY SOURCE FOR POLYMER PLASTICIZING WITH A SPEZIAL DESIGNED HEAT EXCHANGER
Johannes Wortberg | Felix A. Heinzler, November 2011
The plasticizing process is one of the most energy intensive parts in polymer processing. Reducing energy cost is only possible by changing the principle of plasticizing. Therefore a new plasticizing system is developed, based on the primary energy carrier natural gas as main energy source. Natural gas based heaters and a special designed heat exchanger are the key technologies for this project. In addition to the concept, the layout of a demonstrator is described.


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