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The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
Thermal Stabilization of PVC-Wood Composites
R. Bacaloglu, P. Kleinlauth, P. Frenkel, P. Reed, May 2004
The rate of PVC-Wood composites discoloration was used to estimate the effect of PVC heat stabilizers. The mechanical properties of these composites were strongly dependent on stabilizer efficiency and were improved by more effective stabilizers.
Technical Review of the Four Major Thermal Press Applications: Staking/Swaging, Inserting, Degating, Part Marking
Thomas R. Kirkland, May 2004
Thermal presses are used primarily in four applications with regard to assembly (decorating) of thermoplastic parts: staking/swaging, inserting, degating and part marking. Thermal staking/swaging and inserting are generally thought of as competitor processes to ultrasonic, while degating operations with heated tooling are thought of as an augmentation to degating by force alone. Part marking such as date- or lot-coding and serializing is another area where these machines can be applied. This paper discusses these four applications areas and references competing processes to highlight the strengths and weaknesses of utilizing modern thermal presses for these applications.
Optical Correction for Heat Buildup in the Center of TTIr Plastics Welds
Scott Caldwell, David Grewell, May 2004
Through Transmission Infrared (TTIr) laser welding of plastics often results in voids forming in the center of the weld. These voids can lead to weak and unattractive welds. Their formation is due to non-uniform temperature distributions within the weld zone and out gassing of volatiles (such as moisture). This non-uniform temperature distribution has been demonstrated not only by a Gaussian laser light distribution but also by an even light distribution depending on the joint/part design. This paper reviews the development of tailored optics that re-shape the distribution of typical light/laser sources in order to promote uniform temperature distributions. It was seen in FEA models that by using uniform heat distributions, uniform temperature fields were produced in butt joint configurations. In addition it was seen that a distribution with high heat input on the outer edges produced uniform heating in lap shear joint configurations. Laboratory experiments verified these FEA predictions, and strong and attractive welds were generated.
Laser Welding of Polypropylene to Thermoplastic Polyolefins
Chung-Yuan Wu, Michael Cherdron, Mark Douglass, May 2004
Polypropylene (PP) and thermoplastic polyolefin (TPO) are currently used in many automotive applications. However, the weldability of these two materials using through transmission scanning laser welding has not yet been reported. This study focused on the effects of color and welding parameters on lap shear joint strength. Three colors, black, blue and tan, as well as three welding parameters, laser power, weld time and scanning speed, were used to evaluate the weldability. The samples were welded using a 200 W flashlamp-pumped Nd:YAG laser. For the 1.06 ?m wavelength, it was found that 3.2 mm thick natural PP has a transmission rate of 29%. It was also found that the black TPO had the most laser absorption, followed by the blue TPO and then the tan TPO. Therefore, the black TPO required the least amount of welding time to reach the maximum joint strength. In addition, as the scanning speed was reduced, the time required to reach maximum joint strength was also reduced.
Modeling the Bond Formation Development between Polymer Filaments in FDM Prototypes
C.T. Bellehumeur, L. Li, Q. Sun, P. Gu, May 2004
Fused Deposition Modeling (FDM) processes have the capability to fabricate parts with locally controlled properties by changing deposition density and deposition orientation. The integrity and mechanical properties of parts are largely determined by the bonding quality realized among polymer filaments. This paper reports a theoretical study of the mechanical properties of FDM prototypes, heat transfer analysis of the FDM process and modeling of the bond formation among ABS filaments. Thermal analysis of the FDM process resulted in an estimation of cooling profile of the extruded filaments. Quantitative predictions of the degree of bonding achieved during the filament deposition process were made. The model was used to estimate the effects of different manufacturing parameters in the FDM process.
Cracking of Resin Rich Layer Joined to Tank Wall Due to Fluctuating Liquid Level
Jack E. Helms, Michael W. Guillot, May 2004
Composite laminate tanks are used in corrosive services in chemical process plants. The inner surface of tanks usually consist of a glass reinforced layer that is mostly resin and is joined to the tank structure to form a corrosion barrier. A large diameter, open top, composite laminate tank containing a hot brine solution suffered vertical cracking in the corrosion barrier during normal process operations. The process involved relatively rapid changes in the liquid level at different times during each day. Vertical cracks were discovered in the corrosion barrier by plant inspectors during a routine plant turnaround. Finite element modeling was used to demonstrate that the cracking was due to transient thermal stresses near the liquid vapor interface that resulted from the fluctuating liquid level and natural convection from the tank wall in cooler weather. In this research, the effects of the amount of glass reinforcement in the resin rich corrosion barrier were also studied. The outer surface of the tank was insulated, but the insulation does not appear to have been a factor in the cracking.
Rheological Properties of PVC/Wood-Flour Composites
B.L. Shah, L.M. Matuana, May 2004
Using a factorial design approach, this study examined the effect of the component materials on the viscoelastic properties of PVC/wood-flour composites. Statistical analysis was performed to determine the effects of wood flour content, acrylic modifier content and plasticizer content on the die swell ratio and viscosity of the composites measured on a conical twin screw extrusion capillary rheometer. The experimental results indicated that both the wood flour content and acrylic modifier content have significant effects on the die swell ratio and viscosity of PVC/wood-flour composites.
Reactive Blends of Poly (Vinyl Chloride) and Thermoplastic Polyurethane
Johanna Baena, Shane Parnell, K. Min, M. Cakmak, May 2004
In this study, a novel reactive blending technique was used to produce poly (vinyl chloride) (PVC)/thermoplastic polyurethane (TPU) blends that are otherwise difficult to produce by a conventional melt blending techniques due to degradation at elevated processing temperatures. Morphological and spectral characterization studies revealed that reactive blending process generated better mixing relative to melt blending process. The miscibility of the PVC with the polyols of the TPU and with the TPU was studied by changing in the chemical structure of the polyol.
A Study of the Processing Characteristics and Mechanical Properties of Multiple Recycled Rigid PVC
A.S. Ditta, A.J. Wilkinson, G.M. McNally, W.R. Murphy, May 2004
This study focuses on the ability of U-PVC to be processed a number of times. Three different types of U-PVC were investigated: virgin lead stabilised and virgin calcium/zinc stabilised material and reground, 20 year old, post-consumer windows. Each material was extruded four times and samples taken at each stage for rheological and mechanical analysis.
Fast Joining of Composite Pipes Using UV Curing FRP Composites
Su-Seng Pang, Guoqiang Li, H. Dwayne Jerro, Jerry A. Peck, Michael A. Stubblefield, Saleem Hasan, May 2004
For this paper, twelve composite pipe joints were prepared. Among them, six were prepared using ultraviolet (UV) curing E-glass fiber reinforced vinyl ester composites and six were prepared using ambient environment curing E-glass fiber reinforced vinyl ester composites as control. Filament wound E-glass fiber reinforced vinyl ester composite pipes were used. Each section of pipe was 304.8 mm long with a 101.6 mm inner diameter. The wet lay-up technique was used to prepare the test samples. The curing time for the UV cured samples was 40 minutes, while the curing time was 24 hours for the control samples. Both internal pressure tests and four-point bending tests were conducted on the UV cured and control samples. The test results show that the UV cured FRP wrapped composite pipe joints achieved nearly the same bending strength as the control samples. However, the internal pressure rating achieved by the UV cured FRP coupled joints were lower than those achieved by the control samples. Based on the test results, the UV curing FRP can be used in joining composite truss structures and composite frame structures. Further investigation is required in order for the UV cured FRP joined pipes to be used to transport liquids or gases under pressure.
Surface Treatment of Polymers and Composites with UV Light in Air to Improve Adhesion
Alekh S. Bhurke, Lawrence T. Drzal, May 2004
Ultraviolet (UV) surface treatment of polymers in air has been used to successfully modify polymer surfaces in order to enhance adhesive performance and wettability in a cost efficient manner. A wide variety of polymers including thermoplastics (TPO, PP, PC, PMMA), thermosets (Epoxy, Vinyl Ester), rubbers and composites have been successfully modified with this UV treatment. Improvements in adhesive bond strengths from 100-600% can be realized for hydrophobic polymers such as TPO and PP with treatment times on the order of 30-120 seconds. Several key process parameters for UV treatment have been identified. UV radiation in the 180nm-300nm was found to be necessary for surface modification of polymers. The extent of surface modification was found to be strongly dependent on the ozone concentration. The surface temperature during treatment was also found to be a controlling factor for some polymers and preliminary evidence points to a relationship between the optimum treatment temperature and the glass transition temperature (Tg) of the polymer substrate.
Development of Methods for Assessing the Chemical Compatibility of Thread Sealants Used with Plastic Fittings
J.R. Paschal, J. Bian, May 2004
Thread sealants have been used to help ensure a leak-tight joint and reduce friction during installation between threaded metal pipe and fittings for over 100 years. Thermoplastic fittings using the same taper thread cannot be assembled as if they were metal due to chemical compatibility and maximum material stress. However these same sealants are often used on a plastic fitting joint. This may be done either because the installer has been trained to use the same sealants on all threaded joints, or because the plastic parts are not fitted properly and are leaking under pressure. Unfortunately, sealants that work well and are compatible with metal pipe threads may contain stress-cracking agents that will cause failure in plastic fitting joints. Because it is unlikely that the industry practice of using thread sealants will change in the foreseeable future, a method is needed to evaluate these products to determine compatibility with existing fittings materials and designs. The current work develops three categories of testing using tensile, flexural, and threaded part configurations. Several variations in each of these methods are attempted, with multiple types of sealants and materials. There is a definite trade-off in test duration and complexity of the test method. The results of this testing program are provided, with analysis of the failure types and recommendations for the development of an ASTM test method.
Mechanical Properties of Rotationally Moulded Nanocomposites
P.R.W. Hanna, T. McNally, E. Harknin-Jones, P. McMillian, May 2004
Polyethylene montmorillonite and quaternary tallow ammonium chloride modified montmorillonite nanocomposites were prepared by melt blending. The effect of compatibiliser concentration on composite mechanical properties was investigated. The nanocomposite morphology was examined using wide angle X-ray diffraction and scanning electron microscopy. Primarily intercalated structures were observed. The nanocomposites prepared were rotationally moulded using a peak internal air temperature of 200°C and an oven temperature of 300°C and injection moulded samples using a nozzle melt temperature of 220°C. No significant variation was evident in the shrinkage and warpage characteristics of the rotomoulded parts. The tensile, flexural and impact properties of specimens taken from both the rotomoulded and injection moulded parts varied with compatibiliser content. Generally, the properties of the injection-moulded parts were superior to that of the rotomoulded parts.
Interrelationships between Fatigue and Creep Fracture in Poly(ethylene) and Poly(vinyl chloride)
Eric Baer, Anne Hiltner, Jiong Yu, Teresa E. Bernal-Lara, May 2004
Using a fracture mechanics approach, a dynamic fatigue methodology was developed to accurately predict creep fracture in both poly(ethylene) and poly(vinyl chloride). The predictive methodology applied to cases in which the crack propagated in either a stepwise or continuous manner. The effects of material variables such as molecular weight and impact modifier were also elucidated.
Modelling Impact Fracture and RCP Resistance of Thermoplastics from Cohesive Properties
Patrick S. Leevers, May 2004
Developers of thermoplastic materials for pressure pipe applications must design them to resist rapid crack propagation. However, they are usually able only to test them for resistance to impact. The hypothesis that both failure modes are dominated by adiabatic heating leads to good quantitative predictions for each property - and hence to an account of the relationship between them. Here, the model based on this hypothesis is extended to explore the influences on fracture resistance of molecular weight and of thermal property non-linearity.
Residual Strain Characterization Using an Embedded FFB Sensor: Measurements and Simulations
John Botsis, Fabiano Colpo, Laurent Humbert, May 2004
Residual strains in an epoxy specimen are investigated using embedded Fibre Bragg Grating sensors. A novel OLCR technique allows the direct reconstruction of the optical period and provides the strain distribution due to epoxy consolidation along the fibre. The experimental data show an excellent agreement with finite element simulations.
Polyethylene Nanocomposites – Investigating the Tensile Properties of Polyethylene Nanocomposites for Rotational Moulding
Michael Murphy, R. Truss, P. Halley, D. Martin, C.L. Ang, May 2004
Rotational moulding is continuously expanding into new markets which require improved material properties and shorter cycle times. Conventional PE, used in over 80% of the rotational moulding market is a relatively low strength material therefore high part wall thickness, long cycle times and design limitations are imposed.The development of polymer/clay nanocomposites has shown significant improvements in mechanical properties with small additions of organoclay, which have the ability to improve mechanical performances or reduce cycle times.In this work the effect of organoclay on the tensile properties of PE nanocomposites at a range of temperatures was investigated. Tests were also conducted at a range of cross head speeds (CHS) to illustrate the effect of slow rates of extension and instantaneous loading. Tensile testing shows the final nanocomposite properties depend significantly on organoclay loading with improvements of 25% in tensile modulus at room temperature and larger improvements at higher test temperatures being reported. The results also indicate the organoclay loadings investigated had an adverse effect on the tensile yield stress.
Investigation of the Processing Characteristics and Mechanical Properties of Metallocene Catalysed Polyethylene Foams for Rotational Moulding
E. Archer, E. Harkin-Jones, M.P. Kearns, A.M. Fatnes, May 2004
The object of this work is to investigate the foaming characteristics of three grades of metallocene-catalysed Linear Low Density polyethylenes for rotational moulding using both an exothermic and endothermic chemical blowing agent. This paper reports on the results of ongoing experimental investigations in which rheological and thermal parameters are related to the polymer structure and mechanical properties. Through adjustments to moulding conditions, the significant processing and physical material parameters, which optimise metallocene catalysed linear low-density polyethylene foam structure, have been identified. The results obtained from equivalent conventional grades of Ziegler-Natta-catalysed linear low-density polyethylene are used as a basis for comparison.
The Effect of Coupling Agents on Foaming with Polymer Microspheres in Rotational Molding
D. D’Agostino, E. Takács, J. Vlachopoulos, May 2004
The use of polymer microspheres for producing microcellular foams is a new development in rotational molding. In previous studies, some reduction in mechanical properties has been found due to the immiscibility between the polymer shell and the matrix polymer. Coupling agents can act as a molecular bridge at this interface and can also affect bubble growth by altering the rheological properties of the matrix polymer. The influence of different coupling agents on the melt properties of several resins was investigated, as well as the effect of these coupling agents on the mechanical properties of foamed rotationally molded parts.
Manufacturability of Fine-Celled Cellular Structures in Rotational Foam Molding
Remon Pop-Iliev, Donglai Xu, Chul B. Park, May 2004
Any closed-cell polyolefin foam production tends to achieve the highest possible cell size distribution uniformity, cell size reduction, and cell density augmentation. However, the control of the cell size of rotationally foam molded cellular structures formed on the base of a chemical blowing agent (CBA) might be often aggravated by some inherent limitations that are unique to the rotational molding process, which results in coarsercelled final cellular structures being yield. Although a finecelled morphology (cell size < 100 [?m] and cell density > 106 [cells/cm3]) in rotationally molded foams has been closely approached, it has not been actually achieved yet, nor it has been ever clarified whether it is actually achievable in rotational foam molding or not. This study attempts to provide an answer to this fundamental question by focusing on the understanding of the mechanisms governing the formation, growth, shrinkage, and collapse of CBA-blown bubbles in non-pressurized polymer melts originating from extrusion melt compounded foamable resins in a pellet form.

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