SPE Library

The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
Generating Alternative Time and Energy Saving Processing Concepts for Rotational Foam Molding
Remon Pop-Iliev, May 2007
The nature of the rotational molding process is cyclic. It requires the temperature of the rotating mold and the plastic it is charged with to be elevated from room temperature to beyond its melting temperature and then cooled back to room temperature. Consequently, rotational molding cycle times are lengthy, which is often considered as the fundamental drawback of this plastic fabrication process. The motivation and objectives of this paper are twofold. First, the presently proposed research focuses on developing an innovative processing technology for the manufacture of integral-skin cellular composite moldings having adjacent, but clearly distinct, layers of non-cellular and cellular structures, consisting of identical or compatible polyolefin grades. Its primary goal is to significantly reduce the processing cycle time in comparison with respective currently implemented technologies.
Analysis and Validation of Mold Design Guidelines for Cooling Time and Runner Sizing
Nivant Zombade, Ryan Bean, Andrew Thompson, David Kazmer, May 2007
Injection molds have been designed over the years using rules of thumb" which have become almost standard guidelines in industry practice. This paper analyzes and validates two common guidelines for 1) estimation of cooling time and 2) determination of runner sizing. The common guideline for cooling time estimation is compared to the analytical solution of the heat equation and found to have a small average error but significance variance across material properties and processing conditions and validated against industry data. A common guideline for runner system design was found to provide very good results compared with optimal designs produced with the Hagen-Pouiselle flow equations."
Preparation and Melt Viscoelastic Properties Study of TPV Nanocomposite Using Peroxide Crosslinking System
A.Jalali, F.Goharpey, H.Nazockdast, A.A.Katbab, May 2007
Dynamically vulcanized thermoplastic elastomer (TPV)/organoclay nanocomposites based on EPDM/PP containing 2, 4, 6% of organically treated montmorillonite were prepared by using EPDM-g-MA and PP-g-MA as compatibilizer. Dicumylperoxide (DCP) and triallyl cyanurate (TAC) were employed as crosslinking system. X-ray diffraction (XRD) analysis has been performed to evaluate the extent of the intercalation.. In this study, attempts have been made to exclusively reinforce rubber dispersed phase. Rheological behavior and melt viscoelastic properties of the samples such as elastic modulus, and elastic response expressed in terms of relaxation time distribution, H (?) , were studied. The results were also supported by differential scanning calorimetry (DSC) and mechanical tests.
The Study of Particle Size and Surface Treatment of next Generation Radiopaque Fillers Used in Bio-Medical Device Applications
Charles J. O’Neil, Lawrence A. Acquarulo Jr., Sunil P. Mirji, Tony Listro, Stephen Burke Driscoll, May 2007
Medical tubing and catheters have revolutionized the medical industry by enabling minimal invasive surgery procedures. The trend in the medical-device industry is thinner walls, especially in critical applications. Extruding smooth surface using micron-sized radiopaque fillers forms a challenge since they can form rough surface due to non-uniform dispersion. An effort was made to study the effects of particle size and surface treatment of radiopaque fillers on the dispersion, rheological and mechanical properties of PEBA at three loading levels. New generation barium sulfate and bismuth trioxide radiopaque fillers were chosen for this study.
The Effect of Nucleation Specificity on Thermal Behaviour of Photodegraded Polypropylene
Jana Výchop?ová, Roman ?ermák, Martin Obadal, Vincent Verney, Sophie Commereuc, May 2007
This work focuses on thermal behaviour of UVirradiated polypropylenes (PP) containing ?- or ?- nucleating agents or their combination. After irradiation the samples were melted, then non-isothermally crystallized and subsequently melted again. It was found that ?-nucleated PP possessed the highest UV-stability. The photodegradation was also suppressed in materials containing ?-nucleating agent. The effect of UVirradiation led to a splitting of crystallization exotherms into two peaks. The strong efficiency of ?-nucleating agent used was reflected by predominant formation of ?- phase in non-irradiated material containing a combination of both ?- and ?-nucleating agents. However, after only 24 hrs of UV-irradiation this effect was reduced and a preferable formation into ?-phase in re-melted material was detected.
Hybrid Tooling Technologies and Standardization for the Manufacturing of Inserts for Micro Injection Molding
G. Tosello, B. Fillon, S. Azcarate, A. Schoth, L. Mattsson, C. Griffiths, L. Staemmler, P.J. Bolt, May 2007
This paper is based on the European Platform’s activities within the 4M Network of Excellence “Multi- Material Micro Manufacturing”. To overpass limitations of the current existing micro tooling capabilities, a new generation of micro hybrid tooling technologies for micro replication was developed. A metrological approach was applied to standardize the employed tooling processes (micro milling, ?EDM, laser micromachining, electrochemical ?-milling). The micro tools were then tested with different polymers (PP, PP + nano fillers, PC, COC). The paper provides a comparison of these technologies concerning obtainable feature sizes, surface finish, and aspect ratios of both micro tools and micro molded parts.
Evaluation of Oriented Polypropylene/Cast Polypropylene Film at the Heat-Sealing Part and the Edge
Yumi HASHIMOTO, Yasuo HASHIMOTO, Yew Wei LEONG, Kazushi YAMADA, Hiroyuki HAMADA, May 2007
Heat-sealing process is often employed in packaging applications of polymeric films, especially for plastic bags. Often, the failure of plastic bags would initiate from a pinhole, crack, and/or the edge near the heat-sealed part. In this study, effects of heat-sealing temperature on mechanical properties of heat-sealing part and the edge of Oriented Polypropylene/Cast Polypropylene films were investigated. Fracture toughness and tear tests were conducted with the heat-sealed Oriented Polypropylene/Cast Polypropylene films. The thermal properties of the heat-sealed parts obtained by differential scanning calorimetry (DSC) were also investigated.
Long-Term Thermal Insulation Performance of Polystyrene Foam Boards with Decay of Blowing Agents
Zhenjin Zhu, Jinho Zong, Chul B. Park, May 2007
This paper studied the long-term thermal insulation performance of polystyrene foam boards with the decay of blowing agents. A transient cell-to-cell diffusion model was developed to predict the decay of blowing agents. The Mie Theory was used to quantify the radiative conductivity. A cubic-parallel-series analogy of electric circuit was employed to acquire the thermal conductivity of gaseous phase and polymer matrix. Thus, the thermal insulation performance was estimated as the blowing agents decayed. The effects of foam morphology and blowing agent type on thermal insulation capacity were examined.
Understanding Melt Rheology & Foamability of PP-Based TPO Blends
F. Gunkel, A.N.J. Spörrer, G.T. Lim, D.S.B. Sampath, V. Altstädt, May 2007
Rubber-toughened PP is an important resin for many engineering applications. By structural foaming, material cost-saving and lightweight structures can be achieved. In this study, physical blends of PP and poly(ethylene/octene) with various compositions were characterized regarding their melt strength and shear viscosity. The high pressure MuCell® foaming process was used to obtain structural foams with average cell diameters of < 50 ?m and cell densities of ~ 8 × 106 cells/cm3. This study presents key correlations between material rheology and its suitability for structural foaming and elucidates how the foaming behavior is linked to blend composition and melt temperature for an optimum system.
A Shrinkage Prediction in Rubber Compression Moulding
Supasit Rodkwan, Watcharapong Chookaew, Nuchanat Na Ranong, Chana Raksiri, Kunnayut Eiamsa-ard, May 2007
One of the common problems found in rubber compression moulding is the shrinkage of rubber products leading to the loss of shape. In this research, an application of artificial neural network in prediction of the rubber product shrinkage in compression moulding is presented. A back propagation neural network was developed to determine the shrinkage based on the variables of the rubber compound, processing variables such as mould temperature and mould sizing. The neural network prediction for an inside diameter shrinkage and a cross section diameter shrinkage indicate that the architectures 5-11-21-1 and 5-11-16-1 provide a good prediction within 95.9% and 96.1% accuracy, respectively.
Functionally Graded Polymer Nanocomposites (FGPNCs) Filled with Nano Sized Filler
Sandeep S. Ahankari, K.K. Kar, May 2007
A novel FGPNCs has been developed using polymer matrix (polyisoprene) and nanomaterials (amorphous carbon). Its performance is evaluated for structural application through storage modulus, loss tangent, tensile strength, modulus, hardness, hysteresis loss, tear strength, SEM, etc. The functionally graded nanocomposites show better properties i.e., modulus, tear strength, hysteresis loss and strain energy density compared to homogeneous composite at the same percentage of nano filler loading. As for examples, 20, 35 and 40% improvement in modulli at 50, 100 and 200% elongation with respect to homogeneous composites are observed where the average nanomaterial is 30% by weight.
Manufacture and Mechanical Characterization of a Composite Material Made of Wasted Tires and Recycled Polyethylenetherephtalate (PET)
R. Mis-Fernandez, J.A. Azamar-Barrios, J. Rodriguez-Laviada, C.R. Rios-oberanis, May 2007
Solid residue was obtained by two processes to reduce discarded tires: pyrolysis and thermal shock. Techniques such as X-ray, FTIR, TGA and SEM were used to characterize the samples. Two types of polyethylenetherephtalate, PET (virgin and recycled) were analysed physicochemical and mechanically to be used as matrix. A composite material was manufactured by employing a Brabender mixing chamber in order to use the granules as filler on PET at different concentrations. The mixed material was laminated and tension test were undertaken in samples to acquire the mechanical properties. Studies of fractography were performed to understand the failure mechanics.
An Optimization of Natural Rubber Injection Molding Process Using CAD/CAE: A Case Study on the Motorcycle Rubber Step
Supasit Rodkwan, Seksan Winyangkul, Kittinan Unnanon, Chana Raksiri, Kunnayut Eiamsa-ard, May 2007
This research aims to apply Computer Aided Design/Engineering (CAD/CAE) techniques for an optimized rubber injection molding condition using a case study of rubber steps used in motorcycles. The input parameters include both physical and mechanical material properties of natural rubber and operating conditions such as gating and runner positions. The simulated variables such as temperature, pressure and velocity profiles were founded and analyzed. The numerical results are correlated well with empirical data using the vertical injection molding machine. This research provides researchers the computational tool to obtain the optimized rubber injection molding.
Shape Memory Polyurethane-Clay Nanocomposites
Feina Cao, Sadhan C. Jana, May 2007
In this paper, we present results on shape memory behavior of polyurethane (PU)/clay nanocomposites. These nanocomposites were prepared via bulk polymerization method and contained exfoliated clay particles as revealed by transmission electron microscopy and wide angle X-ray diffraction method. The PU matrix contained a crystalline soft segment, which was responsible for shape fixity. The presence of clay decreased the crystallinity of soft segments and consequently shape fixity, but the magnitude of shape recovery stress increased, e.g., by 20% with only 1 wt% clay. The mechanism of reinforcement was studied by monitoring stress relaxation and phase separation.
Injection Molding Process Optimization Using the Process Monitoring System
Joong-Keun Kang, Hyung Keun Chang, Young-Kee Cho, Byung-Ohk Rhee, May 2007
To make sure the stable state of resin in the process optimization test, the process monitoring system (PMS) was applied in a wide range in this study. For each critical step of the test, the way to utilize the PMS depended upon the phenomenon in the mold and the purpose of the test. The dependent variables such as switchover point and holding time were properly set with the aid of the PMS. Based on the relationship of the state of the resin with pressure and temperature, a new PMS index was proposed. The index showed the best correlation with the part weight among various indices through the correlation analysis.
Hybrid Nanocomposites of Carbon Nanotubes (CNTs) Grown on Carbon Fiber in Polyester Matrix with Improved Thermomechanical Properties
Prabhat Agnihotri, Kamal K Kar, May 2007
Carbon nanotubes (CNTs) were grown on the surface of carbon fiber using thermal chemical vapor deposition (CVD) technique. Ni is used as a catalyst. The coating of catalyst on the surface of carbon fiber was done by electroless dip coating technique. By performing structural characterization of CNT coated carbon fiber using scanning electron microscope (SEM) and transmission electron microscopy (TEM), the length and diameter of CNTs were measured and found to be ~9000 nm and ~40 nm respectively. Thermo gravimetric analysis (TGA) of as received and CNT coated carbon fiber samples in nitrogen atmosphere indicates that the CNT coated carbon fiber samples are thermally more stable. The improvement in storage modulus in CNT coated carbon fiber samples is observed in dynamic mechanical analysis (DMA).
Influence of Part Thickness, Glass Fibre Content and Line Energy on Laser Transmission Welding of Polyamide mXD6
P.J. Bates, M-E Druart, M. Chen, G. Zak, J. Billiet, May 2007
Laser transmission welding is a process used to join two thermoplastic materials based on their abilities to transmit and absorb laser energy. The influence of part thickness, glass fibre content, and line energy on the laser welding of a semi-aromatic polyamide was examined. Plaques of polyamide mXD6 were moulded at three different thicknesses (0.5 mm 1 mm, and 2 mm), a range of glass fibre contents (0, 30, 50 and 60%) in both natural and black. Lap welds were made using a Rofin Sinar diode laser in a contour welding mode over a range of line energies. The assemblies were tested in shear and the fracture surfaces examined using scanning electron microscopy.
Modeling the Rheology and Orientation Distribution of Short Glass Fibers Suspended in Polymeric Fluids: Simple Shear Flow
Aaron P.R. Eberle, Donald G. Baird, Peter Wapperom, May 2007
In this paper we present a constitutive relation for predicting the rheology of short glass fibers suspended in a polymeric matrix. The performance of the model is assessed through its ability to predict the steady-state and transient shear rheology as well as qualitatively predict the fiber orientation distribution of a short glass fiber (0.5 mm, L/D < 30) filled polypropylene. In this approach the total extra stress is equal to the sum of the contributions from the fibers (a special form of the Doi theory), the polymer and the rod-polymer interaction (multi-mode viscoelastic constitutive relation).
Ultrasound Assisted Single Screw Extrusion Process for Dispersion of Carbon Nanofibers in Polymers
Avraam I. Isayev, Changdo Jung, Kaan Gunes, May 2007
A novel method for the continuous dispersion of carbon nanofibers (CNFs) in a polymer matrix for manufacturing high performance nanocomposites was developed using an ultrasonically assisted single screw extrusion process. The effect of ultrasound on die pressure, electrical conductivity, rheological, morphological and mechanical properties of polyetherimide (PEI) filled with 1-20 wt% CNFs was studied. A reduction in the die pressure, percolation threshold and an increase in the viscosity, Young's modulus and electrical conductivity along with better CNF dispersion in nanocomposites was achieved through ultrasonic treatment.
Studies on the Thermomechanical Properties of Nickelphosphorous Coated Carbon Fiber Fabric/Polyester Laminates
Niranjan Patra, Kamal K Kar, May 2007
A systematic study was carried out to investigate the effects of nanoscaled electroless nickel-phosphorous alloy coating on the thermomechanical properties of woven carbon fiber fabric reinforced polyester matrix composites. The electroless nickel-phosphorous coated carbon fiber fabrics with different coating time interval (0, 5, 10, 15, 20, 25, 30mins) were prepared. The polyester matrix was then used to manufacture weave carbon fabric/polyester nanocomposites using wet lay-up process. Dynamic mechanical analysis (DMA) studies were carried out in bending and tensile mode. Experimental results showed Maximum improvements in modulus for 30mins coating time reinforced composites. Dynamic mechanical analysis showed enhancement in thermomechanical properties. The nickel-phosphorous coated carbon fiber fabric composites showed a considerable improvement in the glass transition temperature (Tg).

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