SPE Library


The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings

The Physical Property Advantages Gained when Alloying/Blending of Polycarbonate with Polymethyl Methacrylate
J.P. Ibar, T. Hicks, S. Morneau, May 2006

Blends of Polymethyl Methacrylate and Polycarbonate (20/80 & 50/50) were made. This was accomplished using a Dual TekFlow Processor which has already demonstrated its ability not only to blend and intimately alloy polymers, but also offers the advantage to reduce the viscosity of the new blend by disentanglement. The result is usually a new blend, with properties closer to a theoretical mix, i.e. with a more predictable performance level than what has been possible by more conventional methods of blend preparation. Rheological and thermal testing shows that the blends have very little degradation and about 40% disentanglement, meaning an improved fluidity by 40% when compared to the compounded contribution of the individual components. The 20/80 PC/PMMA blends look white, extremely well dispersed, and could be mistaken, at first glance, with Polypropylene. Injection molded specimens were made for the blends and both virgin resins, which allowed for investigation of their comparative tensile, flexural, impact and thermal properties. Mechanical test results indicate that the properties of the 20/80 PC/PMMA blend are slightly better than the Virgin PMMA, whereas the 50/50 PC/PMMA blend has intermediary properties compared to both resins.

α- and β-Polypropylenes: The Effects of Processing on Final Properties
Roman Cermák, Martin Obadal, Veronika Habrová, Lubomír Benícek, May 2006

The study directs attention towards different effects of mould temperature and holding pressure on the tensile properties of injection-moulded neat and ?-nucleated polypropylenes. A commercial-grade of polypropylene was modified with a ?-nucleator. From both the original and ?- nucleated materials, tensile test specimens were injection-moulded. Stress-strain measurements performed at room temperature revealed that the effects on the tensile characteristics of both materials are more pronounced within mould temperature changes, compared with those of holding pressure.

New Long Rayon Fiber Reinforced Thermoplastics Utilizing the LFT-D Process
Frank Henning, September 2005

PowerPoint Presentation at ACCE 2005.

Long-Fiber Reinforced Thermoplastics Tailored for Structural Performance
Manfred Brummer, September 2005

PowerPoint Presentation at ACCE 2005.

Thermoplastic Pressure Vessels for Automotive Applications
Ralph Funck, September 2005

PowerPoint Presentation at ACCE 2005.

Thermoplastic Film Adhesives
William Asmann, September 2005

PowerPoint Presentation at ACCE 2005.

Aerospace Composites Processing Methods for Light Weight Automotive Body Panels
Carroll Grant, September 2005

PowerPoint Presentation at ACCE 2005.

Natural Fiber Reinforced Thermoplastics - Tailored for Interior Applications
Ronnie Tornqvist, September 2005

PowerPoint Presentation at ACCE 2005.

Using Aesthetic Additives in Engineering Thermal Plastics for In Mold Automotive Applications
Patrick Gaule, September 2005

PowerPoint Presentation at ACCE 2005.

Development of High Impact Strength for Long-Glass-Fiber Reinforced Polypropylene
Hiroshi Suzuki, September 2005

Recently long-glass-fiber-reinforced thermoplastics have become popular in the automotive industry. These materials have high rigidity and impact balance. However there are still areas for improvement of mechanical properties especially impact strength which is desirable for new applications such as floors roofs and trunk lids as well as other structural parts. We have developed a way to improve the impact strength of this material. This paper offers the explanation for this method and suggests the best way how to use these materials.

NISSAN Murano Thermoplastic Hatchback Door
Karl-Heinz Kalmbach, September 2005

PowerPoint Presentation at ACCE 2005.

PushtrusionSM Process Technology
Steve Bowen, September 2005

PushtrusionSM is a new technology that combines continuous fiber reinforcement with molten polymer creating fiber reinforced compounds during the molding process. The continuous reinforcing fibers are cut to specified lengths to create short fiber compounds long fiber compounds or even continuous fiber reinforced materials. The technology can be used with many part forming processes including injection molding compression and transfer molding extrusion and filament winding. The process was developed and patented by Woodshed Technologies Inc. The process is licensed to end-users. PlastiComp LLC acquired the technology including patents and trademarks from Woodshed in May 2005. Equipment is manufactured to use existing molding machines (retro-fit) or for new molding machines with compounding technology integrated by licensed OEM machine manufacturers.

Use of Co-Rotating Twin Screw Extruders in the Automotive Sector For Composite and In-Line Process Applications
Daniel Schwendemann, September 2005

Co-rotating Twin Screw Extruders while mainly used in plastics or polymer applications have also penetrated several different niche markets such as chemical or food processing. One of these market sectors where co-rotating twin screw extruders are used is in the direct extrusion In-line compounding of specialty materials. There are various applications in the automotive industry where co-rotating twin screw extrusion and other processing steps are combined to successfully produce automotive composites and other “In – line” products. This paper gives an overview about such applications/ processes.

Introduction of Corn By-Products to Composites for Use in In-Line Compounding
Darin Grinsteinner, September 2005

Composite Products Inc. has been developing their Advantage and Advantage Plus In-Line Compounding Processes to use alternative rein forcements and filler materials for automotive and non-automotive applications. While fiberglass remains the favorite when it comes to reinforcing thermoplastic composites natural reinforcements are beginning to gain renewed interest. Corn by-products when added to polypropylene can offer several advantages. Corn by-products offer low cost weight savings environmental friendliness and relatively good material properties.

Automotive Composite Fuel Cell Bipolar Plates: Hydrogen Permeation Concerns
Richard Blunk, September 2005

At present Proton Exchange Membrane (PEM) performance levels and fuel cell stack operating conditions a plate area specific resistance of less than 30 mohm cm2 and a plate thickness of less than 2 mm are required to meet the vehicular volumetric power density target (> 2 kW/l). Unfortunately it is difficult to meet these targets and simultaneously obtain good mechanical properties and low through-thickness hydrogen permeation rates when using polymeric plate materials. Polymers are brittle at the high conductive filler concentrations (e.g. > 50 v/o graphite) required for high conductivity and are more likely to generate high convection-driven H2 permeation rates at a high graphite loading and at a thin plate thickness. As a result high scrap rates are realized during plate manufacturing and stacking operations and excessive permeation rates are anticipated in pressurized stacks. This study addresses H2 permeation concerns associated with using thin highly-filled composite plates and investigates factors affecting permeation such as plate temperature thickness graphite loading and aging.

Low Cost Light Weight Single Material Solution for Soft Touch Vehicle Interior Substrates
Jesse Hipwell, September 2005

The use of low-density glass-mat thermoplastic (LD-GMT) materials in automotive interior applications has increased over the last 4 years. Nearly 20% of all headliners produced in North America are molded from LD-GMT. Its popularity and use has also begun to spread to other soft-touch applications and to other global regions. The superior mechanical properties ease of tailoring performance efficiency of processing and adjustable thickness capability makes the AZDEL SuperLite LD-GMT product a versatile material solution for both structural and non-structural interior applications. This paper is divided into 4 sections and will present the basic composition manufacturing process and properties of LD-GMT applications of LD-GMT and the benefits of its' use LD-GMT performance when subjected to severl generic interior standards and design capabilities and the forming processes for LD-GMT.

An Integrated Automotive Roof Module Concept: Plastic-Metal Hybrid and Polyurethane Composite Technology
Doug Stratton, September 2005

The implementation of metal stampings combined with injection molded 30% glass fiber reinforced polyamide type 6 (PA6-GF30%) for commercial passenger car and truck front end modules has grown in the automotive industry over the past five years. This patented Plastic-Metal Hybrid (PMH) design technology has proven its ability to enable the automotive original equipment manufacturer (OEM) to engage a flexible assembly strategy decrease capital expenditures and reduce labor hours required to manufacture a vehicle. The roof module is an opportunity to further develop content by combining adhesives coatings film and reinforced polyurethane (PUR) composite materials with PMH technology. The powerful combination provides the OEM a component ready to assemble. Technical and economic benefits to the value proposition include: weight reduction compared to glass design and styling freedom from a box shaped hard top In-mold features like brackets bosses and attachment points Different color options Removable or open/close window design Safety improvement due to lowered center of gravity and benefits in the event of a rollover crash Water management and flush finish with the body exterior This paper presents a roof module concept that utilizes PMH to create a roof frame welded to the body-in-white (BIW) structure that is capable of going though on-line electro-static coating (E-coat) processes. The frame becomes a common footprint upon which a variety of roof modules constructed with PUR composites protected by coating and film can be attached to the vehicle with adhesive. A roof frame design concept for a generic medium sized vehicle is presented. The concept includes single double or triple modular panel versions. Each version can be used to manufacture three variations: a base roof sunroof or panoramic roof module.

Feasibility of Continuous-Fiber Reinforced Blanks for Automotive Applications
Andrew Burkhart, September 2005

Recent developments in the rapid processing of continuous-fiber reinforced thermoplastics (CFRTP) offer a method for automakers and suppliers to manufacture high-performance structures that meet automotive cost performance and volume requirements. Benefits of thermoplastic composites include rapid processing high toughness ease of recycling long shelf life and multi-stage processing. CFRTP tailored blanks are flat net-shape preforms comprising aligned continuous reinforcing fibers in a thermoplastic matrix. These tailored blanks can vary in thickness fiber orientation material composition and shape based on part requirements. Main benefits include material efficiency low scrap and low weight. This paper investigates the feasibility of stamp forming CFRTP tailored blanks. Experimental results are presented showing effects of forming on consolidated tailored blanks and the potential for a high quality surface finish.

Bonded Hybrid Automotive Front End Carriers
Samar Teli, September 2005

The front-end carrier (FEC) refers to the part of a car that supports most of the cooling package headlights latch and various other components. It also ties the upper and lower longitudinal rails and plays a role in the global and local structural stiffness of the car. The trend is to use such a FEC in a module that is supplied for assembly after the engine is mounted. FECs are currently a combination of plastics to give form and various functions and metal to withstand mainly crash loading. Methods such as mechanical fasteners or over-molding are being used to form the hybrid plastic-metal part. Dow Automotive offers a new solution that combines its application development capability and materials R&D. This concept consists of an injection-molded plastic (LGF-PP) bonded to an e-coated metal reinforcement using BETAMATE3 LESA adhesive. This approach enables a closed-box profile with a continuous joint between the metal and the plastic that is not possible using traditional methods. The result is a significant increase in the stiffness/weight ratio as well as reduction in package space utilization. It also offers better design flexibility compared to other hybrid solutions and provides better bending and torsional stiffness. This paper will outline a prototype development demonstrating the technology as well as developments related to current programs.

Embedded Attachments for PU-Based Sandwich Composites
Ignasio Osio, September 2005

Attachments are critical for the performance of sandwich composites in automotive components. In this paper we continue our investigation on attachments techniques [a] and focus on a procedure to embed and test attachments for polyurethane (PU) based sandwich composites. In developing reliable attachment techniques and methods for evaluation and design we open new application possibilities for this family of composites in the automotive market. Embedded attachments are particularly suited for PU-based sandwich composites as the two-component polyurethane mixture allows intimate interlocking of the different sandwich “ingredients”. We discuss the performance of different attachment designs and configurations for applications where extra functionality can be added to this type of structures.










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