SPE Library

The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings

Use of Temperature-Modulated and Step-Scan DSC and DMA to Study Curing in an Epoxy Composite
Bryan Bilyeu, Witold Brostow, Kevin P. Menard, May 2001

Prepregs of an amine-rich mixture of the tetrafunctional epoxy tetraglycidyl 4,4-diaminodiphenyl methane (TGDDM) and the tetrafunctional amine 4,4'-diaminodiphenylsulfone (DDS) were characterized with temperature-modulated DSC (TMDSC) as well as dynamic mechanical analysis (DMA). The baseline shift of the glass transition was separated from the curing exotherm by using temperature-modulated and step scan DSC temperature scans. Likewise, the baseline shift in heat capacity due to vitrification was isolated using TMDSC isotherms. Using the TMDSC glass transition temperature, degree of conversion, and vitrification results, combined with the gelation data generated from DMA, a time-temperature-transformation (TTT) diagram was constructed, providing information necessary for optimization of industrial processing of the epoxy prepreg. Thus, effects of storage, preprocessing, and postprocessing on the overall curing process are taken into account.

Characterization of Adhesive Failure and Modeling for Dynamic Analysis
N. Suresh, Golam Newaz, Gilbert Chapman II, Craig Patterson, Lawrence J. Oswald, May 2001

One of the ways of increasing fuel efficiency of a typical automobile is to reduce its overall weight. To this extent, plastics, especially fiber reinforced plastics are finding an increasing role as automotive structural components. The automotive structural systems made up of these structural fiber reinforced plastic components, should satisfy the needs in terms of safety, strength, NVH and durability, in addition to being affordable, manufacturable with desired fit and finish and recyclable. In general, structural components made up of fiber reinforced plastics are adhesively bonded together to form structural systems, capable of carrying automotive structural loads under static and dynamic conditions. Fiber reinforced plastics and the adhesive used to bond them to form a structure are inherently viscoelastic in behavior. It is imperative therefore, to understand the behavior of these adhesively bonded fiber reinforced plastic components, in terms of their load carrying capacity at different temperatures and different load or strain rates. One of the key factors in this understanding is to characterize the adhesive failure itself at different temperatures and different strain rates of loading. The present paper is an attempt to present some results from an ongoing research work on fiber reinforced adhesively bonded large injection molded thermoplastic automotive structural systems. In particular the paper presents the results from the test methodology and the mathematical models used to characterize the failure mechanics of adhesively bonded automotive body sections, at different temperatures and different load or strain rates.

Double Foam-In-Foam Polymer Materials
Y. Yuan, F. Shutov, May 2001

Reticulated 100% open-pore low density (20 kg/m3) flexible polyurethane (PUR) foams with various pore sizes (1-8mm) were used as three-dimensional fillers to reinforce low-density closed-cell PUR flexible foams. The final materials represent the double foam-in-foam" structures where one foam "impregnates" another one. Compared to the "single" closed-cell PUR foam the double material exhibit considerable improvement of mechanical properties: for the same low density the compressive modulus increased up more than 10 times. Marketing aspects of a new family of the developed foams are discussed such as cushioning and packaging application."

360 Degree Competitive Intelligence A Full Circle" Perspective of the Competitive Environment"
L.N. Kattas, F. May, May 2001

A competitive intelligence methodology has been developed which ensures an actionable customer focus is reflected in an assessment of the competitive arena. This is accomplished by combining the classic top down" or Industry analysis of a competitor (or group of competitors) with a "bottoms up" view from the customer perspective. The Industry approach assesses factors such as external environment market position technology supply chain issues and corporate culture among others identifying strengths weaknesses and apparent strategy. The Customer view obtained by in depth field interviews provides insights into unmet needs emerging trends and supplier performance against the strategy. The result is an externally focused actionable plan. This paper will detail the combined methodologies employed and the value added obtained by a review of case studies."

Experiments on the Induction Welding of Thermoplastics
V.K. Stokes, May 2001

Because of the increasing use of thermoplastics and thermoplastic composites in load-bearing applications, welding methods are becoming important for part cost reduction. Welding requires the melting of the surfaces to be joined, followed by a solidification of the interfacial molten layers under pressure. Many welding techniques using different means for heating the joint interface are available [1]. One such versatile technique is induction welding, in which the surfaces to be joined are brought to the melting temperature" by induction heating a specially made gasket placed in the joint interface. Applications of this technique include welding of hot-water kettle housings and the welding of high-pressure water tanks. This process is not well understood. In this paper tensile tests on induction butt-welds of amorphous and semicrystalline materials are used to characterize achievable weld strengths. Microscopy is used to correlate the strengths achieved with the morphology of the failure surface."

High Carbon Fly Ash/Mixed Thermoplastic Aggregate for Use in Lightweight Concrete
Robert Malloy, Nirav Desai, Charles Wilson, Christopher Swan, Daniel Jansen, Mohsen Kashi, May 2001

Synthetic lightweight aggregate has been produced by melt compounding high concentrations of high carbon fly ash into various thermoplastic binders. The composite material is being developed as a synthetic lightweight aggregate for use in applications such as lightweight concrete. In this study, a series of lightweight aggregates have been produced using several fly ash concentrations, and several different thermoplastic binders. The synthetic aggregates have been produced using flexible thermoplastic binders, rigid thermoplastic binders, and a mixed thermoplastic binder formulation. The physical properties of the melt compounded aggregate materials have been evaluated in an effort to determine the relationship between variables, such as the binder stiffness, and the aggregate stiffness. Lightweight concrete test samples have also been prepared and evaluated. The results of the study show that the lightweight aggregate properties are influenced by both the fly ash concentration and the thermoplastic binder composition. However, the effect that the thermoplastic binder has on the physical properties of the aggregate becomes less significant at high fly ash concentrations. At fly ash concentrations of 80%, the physical properties of the aggregate are fairly insensitive" to the composition of the thermoplastic binder. The aggregates produced using a mixed plastic composition had properties that were quite similar to those produced using the individual (control) thermoplastic binders indicating that low value mixed plastic waste may be a candidate binder material for the polymer bound fly ash aggregate."

Effect of Nanoparticles and Processing Conditions on the Development of Structural Hierarchy in Injection Molded Nylon Composites
B. Yalcin, M. Cakmak, May 2001

Preliminary studies on the basic structure developed in nylon 6 and its blends with nanoparticles are presented. The melting transition and crystallization behavior of compression molded nylon 6 and its nanocomposites are investigated using DSC and WAXD techniques. The structural hierarchy developed along and across the flow direction is also addressed using optical microscopy. Polarized optical microscopy revealed that the presence of nanoparticles causes significant enhancement of the preferential orientation through the thickness direction of the molded parts even at mold temperatures very close to the melting temperature.

Efficient Injection Molding Workcells: The Case for Remote Integration
Bruce Catoen, May 2001

Today's competitive business environment requires companies to embark on continuous improvement projects aimed at dealing with plant inefficiencies and new product introductions. Almost every company is unsatisfied with the slow rate of implementation and unsatisfied with bottom line results. How do you ensure that your new system integration will not fall into the same trap? Once the plastic part is designed, the task of creating a cell to manufacture it is too often considered to be a mere formality. It is more than a simple matter of buying the pieces of individual equipment, positioning them on the floor, connecting them to the services and pressing GO" to start. In fact there are critical cell design choices and decisions to be made even before designing the plastic part which are crucial to the ultimate success of the project. A world class injection molding cell requires a well thought out plan detailed engineering design of the system including all the auxiliaries and finally rigorous testing of all the components and their interaction. The focus of this paper will be on the system integration which can be loosely defined as the physical placement/connection of the equipment as well as the performance testing and validation."

Reinforcement of Thermoplastics Using Microcomposite Fillers
Peter R. Hornsby, Charles E. Bream, May 2001

Thermoset recyclate fillers are considered as microcomposite reinforcements for polymers. Emphasis is given to glass fibre-reinforced phenolic and polyester waste products as functional fillers for polypropylene, where with appropriate surface modification, significant enhancement in mechanical properties can be achieved. In this respect, the role of a two component treatment package is discussed, in terms of fibre-matrix interfacial bonding, the effect on properties of the host polypropylene matrix, and the failure mechanism induced. Novel integrated compounding technology is described for the cost-effective preparation of polymer composites, containing thermoset recyclate fillers.

Supercritical Fluid Assisted Polymer Processing
Siobhán O. Matthews, Peter R. Hornsby, May 2001

The plasticising action of supercritical carbon dioxide in polymer melts will be demonstrated using in-line rheometry applied to a single screw extruder. By optimising processing conditions, gas dose rate, temperature and pressure, it will be shown that significant viscosity reductions can be achieved, enabling enhancement of process performance. The application and potential use of this effect to different polymers will be considered, including highly filled compositions used in ceramic fabrication. Means for achieving foam-free product will be discussed in extrusion and injection moulding processes.

Real Time Development of Stress and Birefringence in PET during Uniaxial Stretching as Detected by Spectral Birefringence Technique
Taner Zafer Sen, Shigeyuki Toki, Miko Cakmak, May 2001

The birefringence and stress development of PET films has been measured by our new stretching system that couples the Spectral Birefringence Technique with the stress strain measurements. The tensile stretching machine which is specifically designed such that both clamps of the samples move away from each other. This allows for keeping the midsection of the sample stationary. The birefringence and width of the sample is measured at this location. The width of the sample is measured using laser micrometer through which true strain is obtained real time. It has been found that the birefringence development starts before strain-hardening point. The system is fast enough to follow the deformation at high rates of strains. The increased strain rates results in higher birefringence levels through all stages of deformation

Effects of Biaxial Stretch Ratio and Stretch Mode: The Evolution of on Structural Hierarchy in Polylactic Acid
X. Ou, M. Cakmak, May 2001

A series of stretch modes: uniaxial free width (UFW) stretching, uniaxial constant width (UCW) stretching, simultaneous equall biaxial(SEB) stretching and sequential equally biaxial (SEQEB) stretching, were applied to cast amorphous films of PLA in order to investigate the effect of processing on the structure and properties. It is found that UFW stretching leads to higher crystallinity. SEQEB stretching is found to induce very high stress during this resulted in higher crystallinity development in the sequentially stretched films as compared to simultaneously stretched ones of comparable stretch ratios. This was attributed to the increased efficiency of strain induced crystallization in the sequential deformation mode stemming from the first stretching stage.

A Model for the Physical Aging of Semicrystalline Polymers above Tg: Secondary Crystallization Induced Constraining Effects
Hervé Marand, Azar Alizadeh, Seungman Sohn, Jiannong Xu, Robin Farmer, Vivek Prabhu, Steve Cronin, Vesselin Velikov, May 2001

Semicrystalline polymers exhibit changes in physical properties during storage above their glass transition temperature. According to the current paradigm, physical aging above TG is explained by densification of the rigid amorphous fraction in the vicinity of the crystalline phase. Results from differential scanning calorimetry, X-ray diffraction, atomic force microscopy and creep studies lead us to propose a different model, which considers the formation of secondary crystals and the increase in conformational constraints in the residual amorphous fraction.

Real Time Birefringence Development of Orientation in Polymers during Uniaxial Stretching as Detected by Robust Spectral Birefringence Technique
S. Toki, D. Valladares, T.Z. Sen, M. Cakmak, May 2001

Development of Stress and Birefringence during uniaxial stretching of Polymers was studied using the newly developed stretching instrument that allows simultaneous recording of stress, spectral birefringence and strain during uniaxial deformation. In this new instrument the stretching mechanism is designed such that both upper and lower sample holding clamps move away from each other simultaneously in order to probe the birefringence at the stationary mid section of the sample. The spectral birefringence technique is robust enough to follow rapid changes in the retardation (and birefringence) as well as the reversals in the trend in birefringence that may be caused by the relaxation, crystallization and/or melting depending on the processing conditions. This deviced unique instrument will allow us to study the details of the structural ordering mechanisms real time at industrially meaningful temperatures and deformation rates.

Kinetics of Rapid Structural Changes during Heat Setting of Preoriented PEEK/PEI Blend Films as Followed by Spectral Birefringence Technique
S. Bicakci, M. Cakmak, May 2001

The influence of composition and pre-orientation on the development of structural hierarchy during heat setting of PEEK/PEI films was investigated using on-line birefringence, X-ray scattering and thermal analysis techniques. When the PEEK/PEI blends are drawn to deformation levels below the onset of strain hardening, the subsequent heat setting at high temperature starts with a large relaxation process followed by fast crystallization stage and long-term slow structural rearrangement process. When the films are pre-drawn beyond a critical structural level (crystallinity and orientation), the initial relaxation stage completely disappears. This signifies that beyond a critical structural order a long-range physical network, where the nodes consist of crystallized domains, is formed. The addition of non-crystallizable PEI chains was found to retard the formation of this network structure"."

A Novel Method with Improved Economics for Preparing Polymer Blends
Wesley R. Hale, David L. Murray, Allan S. Jones, May 2001

Polymer blends are, with few exceptions, made in extruders. However, extrusion can be costly and requires that the previously made starting materials (blend components) be isolated (and dried in the case of polar polymers) and handled, adding to expense. A novel method has been discovered wherein polyester/acrylate polymer blends are prepared in the polyester reactor itself. This is accomplished by emulsion polymerizing acrylate monomers in the presence of a diol continous phase. The diol can then be used to synthesize a polyester. This technology allows for blending and compatibilization strategies accessible and inaccessible through conventional methods at a reduced cost. In addition to polyesters and polyacrylates, we have expanded this technology to include other condensation polymers such as polyamides and other dispersed phase polymers such as silicone and butadiene rubbers.

Simulation of the Puncture Resistance of a Thermoformed Syringe Pack
Roy Christopherson, Marc Briere, May 2001

A potential material change for a medical packaging thermoformed pack requires costly and time-consuming re-validation. One of the major issues associated with this is the puncture resistance of the pack. This study considers a non-isothermal computational fluid dynamics (CFD) analysis of the thermoforming process of a syringe pack, followed by a non-linear structural analysis of the formed pack to estimate puncture resistance. In this way the final shape and thickness distribution of the thermoformed pack are included in the structural analysis. Two reference materials will be used in validating the usefulness of the technique.

Processing and Benefits of Commingled Glass Fiber Reinforced Thermoplastic Composites
Alexis Bricout, May 2001

Despite continuous growth over the years, thermoplastic composites suffer from rather low mechanical properties due to low levels of glass reinforcements and random fibers. The breakthrough of commingling thermoplastic and glass fibers during the glass forming process addresses that issue. When comparing commingled wovens to long fiber reinforced PP the significant improvement in properties opens the door to new applications. Recent developments have focused on combining woven fabrics and molding compounds in both injection and compression molding tools to take advantage of the benefits of both material forms.

Processing of Glass Fiber Mat Reinforced Thermoplastic Composites
Enamul Haque, Paul Bristow, Harold Giles, May 2001

In this paper, information relating to the processing of glass fiber reinforced thermoplastic composites by compression molding techniques is presented. Glass Mat Thermoplastic (GMT) composites have been used in bumper beams and other structural applications by the automotive industry since 1980. In this paper, information that will act as a processing and design guide for engineers and designers involved with thermoplastic composites is presented. Various molding parameters for successful processing, critical processing parameters, fundamental design criteria, equipment requirements for molding and other secondary operations, material selection and the differences between the various grades with advantages and disadvantages are discussed.

Polyester Polyols for Polyurethanes from Recycled PET
Peter Rossi, Edward Kosior, Pio Iovenitti, Syed Massod, Igor Sbarski, May 2001

Plastic packaging forms a significant portion of household waste, and PET soft drink bottles represent a major percentage of the waste. Consequently, PET bottle grade material makes up a significant portion of the feedstock in the recycling plant at Visy plastics. The end uses are theoretically many, however, there are few applications for less purified grades of recycled PET. This paper presents the preliminary results of an industry based collaborative research project which aims to investigate the breaking down of recycled PET into its chemical building blocks using glycolysis. The main objective is to produce a polyester polyol for the polyurethane industry from recycled PET and to compare the properties with that of a virgin resin.

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