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The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings

Colored Inorganic Pigmented Long Fiber Thermoplastics
U.K.Vaidya, K. B. Thattaiparthasarthy, S. Pillay, September 2013

Long fiber thermoplastic (LFT) composites materials are one of the fastest growing materials in the polymer composites industry. Most of the thermoplastics used in automotive transportation and recreational industry are natural or black in color; and exterior painting adds to the cost of the manufacturing. Engineered plastics have higher processing temperatures that restrict the use of standard organic pigments and dyes in the processing of thermoplastics. Organic materials are not stable at higher temperatures typically above 250 degrees Celsius and degrade during processing. Alternatively inorganic particle-based pigments are acceptable for these applications because they are thermally stable to at least 800 degrees Celsius and are compatible with the polymer systems. These high performance inorganic pigments are engineered to be weather able chemical resistant and acid resistant; however in reinforced fiber composites the pigment cause fiber attrition and thereby reduction in strength. The focus of this work is on colored inorganic pigmented long fiber thermoplastic composites. The ability to integrate the color in the manufacturing steps eliminates the need for secondary painting. Pigment variables such as particle size distribution chemistry and coatings and their influence on the strength of the final part have been investigated. The paper presents the processing and performance envelopes of inorganic pigments colored LFTs in comparison to unpigmented standard LFTs.

Thermoplastic Composites in One Step: In Situ Polymerization of Caprolactam into Fiber Glass Reinforced APA6
Jaap Van der Woude, September 2013

In situanionically polymerized fiberglass reinforced composites from lactams can provide the advantages of both thermosets and thermoplastics: long fiber retention one step process short cycle times thermoformality and re-cyclability. Due to the low viscosity of caprolactam very-high glass contents can be realized which in essence makes these composites unique new engineering materials. The very strong and lightweight composites can potentially replace many existing materials in a wide field of applications.

Finite Element Modeling of Bond-Line Read-Through in Composite Automotive Body Panels Subject to Elevated Temperature Cure
Paul Deslauriers, September 2013

Several studies have been conducted to investigate the ability of analytical tools to predict the surface distortion observed after adhesively bonding sheet molding compound (SMC) composite assemblies at elevated temperatures. This surface distortion has been termed bond-line read-through (BLRT). Initial studies using a finite element analysis (FEA) based approach showed good agreement with experimental observations and highlighted the importance of accounting for viscoelastic adhesive material properties. The current paper reviews the FEA-based approach and a parametric joint parameter study to provide background on key adhesive joint parameters. Next the results of a lab scale coupon study are presented in which measured curvature results are compared to FEA predictions. In this study several adhesive bead configurations are reviewed including a joint geometry with a machined groove. The results of this study indicate good qualitative and quantitative comparison between measured surface curvatures to FEA predictions. Lastly two analytical panel studies are presented to examine how complex three-dimensional panel geometry and local panel character line geometry can influence BLRT severity. The results of this study indicate that BLRT is a local phenomenon so that the overall panel geometry does not influence the local BLRT severity; however changes in local panel geometry can influence the BLRT severity.

THERMOPLASTIC COMPOSITES IN STRUCTURAL LIGHTWEIGHT APPLICATIONS–POTENTIAL OF UNIDIRECTIONAL FIBERREINFORCEMENT AND SANDWICH STRUCTURES
Timo Huber, Frank Henning, Andreas Menrath, Volker Heinzle, September 2013

This work presents the investigations of process developments with injection molded components in combination with damaged and planar fiber structures. Fundamental experiments with tensile loaded structures in the first and flexural loaded structures in the second case are presented. The results lead to a better understanding of the influence of local continuous-fiber reinforcements in thermoplastic composites and their applicability in structural applications.

Tensile and Fatigue Performance of a Self-Reinforced Polypropylene
P.K. Mallick, September 2013

Self-reinforced thermoplastics are single polymer composites in which the reinforcing fibers and the polymer matrix are of the same thermoplastic type. The principal advantages of such materials are that they are completely recyclable and the interfacial bond between the fibers and the matrix is very strong which helps them achieve high tensile strength. Polypropylene fiber-reinforced polypropylene is the most common self-reinforced thermoplastic available today. It not only possesses high tensile strength but also high impact strength and for these reasons it is being considered for a variety of automotive applications. In some of these applications fatigue properties of the material may be of greater significance than the tensile or impact properties. In this study both tensile and fatigue tests were conducted on a self-reinforced polypropylene fabric. Fatigue performance was evaluated in terms of number of cycles endured and changes in cyclic properties occurring during fatigue cycling.

Analysis of Adhesive Geometric Effect on Fracture Behavior in Applying Rubber Filled Epoxy Materials
Jie Feng, September 2013

Epoxy is widely used in industry as adhesives and binding matrix for composite materials. By adding liquid rubber into Epoxy it is generally accepted that the toughness of the composite can be improved due to better energy absorption in fracture. This toughening effect however can vary with the adhesive thickness due to the preferred energy dissipation manner. In view of this phenomenon this study investigates the geometric effect in applying rubber toughened epoxy as adhesive. Using a combination of experimental and predictive modeling approach the effect of bonding layer thickness and application dependent (modulated thickness) for rubber-filled epoxy system has been investigated. It is observed that the adhesive bonding geome try could affect both fracture initiation and propagation. The finding from this study can be applied to different types of substrates such as bonding of laminate materials and adhesion of composite materials.

Nylon 66 Continuous Fiber Thermoplastics Composite – Evaluation of Processing Techniques for Optimal Performance
Chul Lee, September 2013

After evaluating mechanical properties of thermoplastics composite laminates constructed from unidirectional tape of nylon 66 / glass fiber system the author will present findings in preparing prepregs including the key factors that affect laminate quality and productivity such as resin weight glass size and “knottability” and “spreadability” of tow. Also discussed will be considerations in using these properties for a composite product design and pros and cons of two compression molding methods.

High Performance Engineered Polypropylene Compounds for High Temperature Automotive Under-the-Hood Applications
John Klein, September 2013

Over the years plastic composite air intake manifolds made of glass filled nylon 6 and 66 have replaced their metal counterparts. While nylon has been a suitable material for these demanding high temperature under-hood applications optimized polypropylene compounds are proving that they are able to perform equally well in these rigorous operating environments. This paper introduces a new polymer innovation a high temperature glass reinforced polypropylene compound. Key performance attributes will be compared to incumbent materials and the material’s suitability for under hood applications will be explored.

Closing the Gap Between Polypropylene and Polyamide Composites with New Silane Grafting Technology from Dow Corning
François de Buyl, Vincent Rerat, Christophe Paulo, Scott E. Miller, September 2013

A new discovery regarding the grafting of polypropylene (PP) with silanes by melt reactive extrusion processing was demonstrated while preventing significantly the undesired |?-|scissionphenomenon. Such modified PP was then used for enabling cross linking into an injected part showing enhanced high temperature resistance for both neat PP resin and glass fiber reinforced PP composites as well as significant improvement in coupling of glass fibers versus MAgPP showing significant improvement in tensile and flexural properties as well as higher stability under heat and water. Also observed was reduction of water uptake in lignocellulosic fiber PP composites. The relevance of this work will be discussed in applications related to Automotive and the potential to replace PA with PP composites.

Near-Perfect" New Centrifugal Pump Wear Rings and Bushings"
Randy Lewis, September 2013

Pump bushing or shaft wear is readily indicated by a dramatic loss of pump performance that required down time for maintenance. With all previous bushing materials in difficult applications Carver pumps were scheduled to last no more than 90 days without maintenance down time for bushings replacement and some exceptional applications required bushing replacement every week. However a new molding compound has been developed for the manufacture of pump wear bushings. Since switching no measurable wear has been detected during pre-production testing or during 2 years in the field. Furthermore no shaft wear has been found either indicating the wear problem has been solved.

Recent Case Studies of Engineering Thermosets for Under-the-Hood Applications (Part A: Overview)
Cedric Ball, September 2013

Automotive engineers are looking for options to reduce weight and increase engine efficiency to comply with new CO2 emission and fuel economy regulations. As a consequence under-the-hood operating temperatures continue to increase. Engineering thermosets are an effective lightweighting alternative to heavier conventional steel and aluminum die-cast products. They combine outstanding temperature stability long-term mechanical strength dimensional stability and high chemical resistance. This presentation focuses on 2 recent automotive underhood applications where phenolic-based engineering thermosets successfully replaced traditional metals. First a thermoset water pump housing was shown to outperform cast aluminum in dimensional stability while lowering overall weight; and a thermoset vacuum pump also originally designed in die-cast aluminum provided high mechanical strength and improved dimensional stability at reduced cost and weight. Finally various recycling methods for these thermoset materials are described.

Unpainted Visible-Surface LFT Parts for Auto Interiors
Hansel Ramathal, September 2013

Recently LFRT materials have been used in the automotive interior to incorporate structural requirements while delivering a first-surface appearance thereby eliminating secondary operations such as painting plating or fastening. The key technical requirements in many of these applications is impact strength surface abrasion resistance and color uniformity. Added benefits of using LFRT materials are superior dimensional stability even in thin-wall parts. With proper tool design warpage can be significantly reduced while reaping the weight reduction benefits of lower specific gravity LFRT PP materials.

High Duty Lightweight Polyamide Engine Mounts
Hans-Juergen Karkosch, Holger Klink, September 2013

Engine mount components are the key link between the engine transmission unit and the body or the chassis and are designed to secure the power unit in the engine compartment and suspend it so that by damping impacts due to road irregularities and isolating engine vibrations the power unit does not come into contact with the body. Such load-bearing structural components are primarily made from steel or aluminum. but their high weight not only affects vehicle mass and thus fuel consumption but also axle load distribution. This paper will discuss the development of heavy-duty fiberglassreinforced polyamide structural components for motor vehicle engine mounts which yielded weight savings of up to 50%.

Polyurethane Environment Friendly Sandwich Structure Load Floor
Allan James, September 2013

Dow Automotive and Magna International have developed a polyurethane-based system to enable a novel sandwich structure that includes extensive use of environment friendly materials. This system addresses two significant challenges in the automotive industry: weight reduction and incorporation of renewable materials. An ideal application for this technology is the load floor an interior component located in the rear of the vehicle immediately above the floor pan. This paper will review the performance requirements for a load floor the alternative materials and the development of a novel sandwich structure solution which gives the best mass to load performance with the capability to tailor shape requirements and includes the use of environment friendly materials.

EFFECT OF RUNNER AND GATE CONFIGURATION ON THE PERFORMANCE OF D-LFT COMPOSITEPARTS
V.L. Bravo, M. R. McLeod, C. Porretta, September 2013

This presentation deals with the hypothesis that the differences in the geometry of the flow channels for 2 composite moulding approaches affect the length dispersion and distribution of reinforcing fibres in the polymer matrix. It has been well documented in literature that fibre length affects the mechanical properties of the composite material while dispersion and distribution affect the uniformity of these properties. A systematic analysis of composite parts produced with the 2 processing methods was carried out results of which are reported here.

INTEGRATED SEMI-CONVERTIBLE SUNROOF SYSTEM IN GLASS-REINFORCED SMA/ABS RESIN
Marcie Kurcz, Henri-Paul Benichou, September 2013

This presentation discusses the first very-large thermoplastic sunroof module for a serial (production) cabrio (semi-convertible) vehicle. Industrial partners combined their efforts to reduce weight and optimize systems cost. The large innovative tool that was developed molds both sunroof and rear window frames at one time. The part uses glass-reinforced styrene maleic anhydride/acrylonitrile butadiene styrene (SMA/ABS-GR) resin and meets all the OEM’s requirements for precise dimensions weathering resistance good aesthetics and adhesion to other substructures. This paper will detail the development process tooling considerations and benefits vs. other materials (e.g. metals and thermoset polymers).

Multi-Scale Modeling of Failure of Continuous Carbon Fiber Composites Application to Coupon Tests
Roger Assaker, September 2013

In the steady quest for lightweighting solutions continuous carbon fiber composites come down to the ground serving now not only the aerospace but also the automotive industries. This category of carbon fiber-reinforced plastics (CFRP) has recently taken a step in car body structures for its high stiffness and strength. Continuous carbon fiber composites are much more complex than metal with respect to failure in particular. This presentation will cover the application of micro-mechanically-based progressive failure models to simple demonstrator structures such as coupons.

A FORMULATION STUDY OF LONG FIBER THERMOPLASTIC POLYPROPYLENE (PART4):THE EFFECT OF MOLDING CHANGES ON MECHANICAL PROPERTIES OF PP LFT PARTS
Creig Bowland,J. vd Woude, September 2013

In Part 4 of this multiyear study the relationship between the polypropylene long-fiber thermoplastics (PP LFT) and the processes used to mold are presented. Parts are formed by injection molding compression molding and plunger tool using the same formulation in the PP LFT part. The effects of glass-fiber diameter sizing and changes in molding conditions were explored. Prior work showed significant differences between injection molding and compression molding. The use of the plunger tool has given a unique opportunity to evaluate the effects of molding conditions and fiberglass products on the final part performance.

Progress on Simulating Orientation of Long Glass Fibers in Composites Molding
Kevin Meyer, September 2013

The bulk properties of long (> 1mm) fiber-reinforced composite materials are highly governed by the orientation of the embedded fibers within the matrix which depends on processing conditions and mold design. Modeling the orientation of long fibers in molding processes is typically carried out using the Folgar-Tucker equation for rigid rod-suspensions which is a modification of Jeffery’s equation for suspensions of prolate spheroids. In the first part of this paper we report our efforts to extend the traditional method of ellipses for measuring fiber orientation to systems of long glass fibers. In the second part we evaluate an alternative model for predicting the orientation in long fiber composite materials which allows the effect of bending to be taken into account during processing in both shear and shear-free flow fields. Simulation of fiber orientation in injection molding using the new model is compared against experimental data showing significant improvement in the predictions relative to those based on using the conventional model for rigid fibers.

Fiberglass Reinforcement Sizing 101
James Chantler, September 2013

An introduction and general overview of the manufacture of fiberglass reinforcements is presented. Included is a general discussion of the role and components of the chemical coating on the glass fibers known as the sizing and why these chemicals are important to the manufacture and final properties of composites. This presentation explains what sizing is how it affects composite properties how it is applied to glass what classes of sizing chemicals are used and what each component does and why it is needed. The goal is to help the fiberglass industry educate customers and debunk the myth that all fiberglass is the same.










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