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Conference Proceedings
A Novel Understanding on the Effects of Industrial Retorting in Ethylene-Vinyl Alcohol Copolymers Used in Retortable Food Packaging Applications
J.M. Lagaron, A. López-Rubio, E. Giménez, R. Catala, T. Yamamoto, Y. Saito, R. Gavara, May 2004
The ethylene-vinyl alcohol (EVOH) copolymers are a family of excellent high barrier resins with wide implementation in a number of oxygen sensitive food packaging applications. These materials are also widely used in retortable food packaging designs, where the multilayer structure, e.g. PP/EVOH/PP, is temporarily exposed to water vapour to render the packaged food sterile. This thermal treatment is known to lead to a deterioration in the oxygen barrier performance of the EVOH internal layer present in the structure. The previous understanding of this phenomenon suggested a plasticization process by which ingress of water through the external hydrophobic layers, e.g. polypropylene (PP), reached the high barrier EVOH layer. On the other hand, the results presented here clearly indicate that, in addition to water ingress and subsequent material plasticization, a crystallinity disruption is also taking place during retorting. Nevertheless, this crystallinity disruption can be effectively overcome, and, therefore, the packaged food safety be ensured, by, for instance, adequate drying/annealing of the packaging structure after the retorting treatment. Unprecedented time-resolved WAXS analysis of a PP/EVOH32/PP multilayer permitted us to determine that EVOH32 does actually resist the retorting process when protected between PP layers.
Development of EVOH-Kaolinite Nanocomposites for High Barrier Packaging Applications
Enrique Gimenez, Lluis Cabedo, Jose Ma Lagaron, Rafael Gavara, Juan J. Saura, May 2004
This paper reports on a novel route to develop EVOH-kaolinite nanocomposites by a melt intercalation process and on some relevant nanocomposite properties as a function of composition. The kaolinite clay used is a very cheap raw material of the tile industry and as such needed to be refined and chemically modified prior to the melt intercalation step. The modification was carried out with dimethyl-sulfoxide, methanol and octadecylamine in order to increase the basal plane distance of the original clay by a factor of more than three. Wide-angle X-ray diffraction (WAXD), transmission electron microscopy (TEM) and thermogravimetric analysis (TGA) were used for characterization of the morphologies obtained. From the early results, partial exfoliation and intercalation of the clay platelets was the dominant morphology attained. The dispersion of clay nanolayers in the EVOH matrix seeks to improve the barrier properties of EVOH. An increase in thermal resistance, glass transition temperature, crystallinity and barrier properties to oxygen were also observed for mass clay loadings below 8%.
Biaxial Orientation in Polyethylene Films: Comparison of Infrared Spectroscopy and X-Ray Techniques
A. Ajji, X. Zhang, S. Elkoun, May 2004
In this study, different polyethylene films (LDPE, LLDPE and HDPE) were produced under using different processes (film blowing and biaxial orientation) and processing conditions. The orientation of the films was characterized in terms of their biaxial crystalline, amorphous and global orientation factors using birefringence, Fourier Transform Infrared Spectroscopy (FTIR) with a tilted incidence technique and X-ray pole figures. It is well established that FTIR can measure crystalline axes orientation for polyethylenes, as well as the orientation of the amorphous phase. On the other hand, X-ray pole figures determines the orientation of the crystalline axes, and in combination with birefringence can yield the amorphous phase orientation. The results from those techniques are compared and discussed in terms of the accuracy of the techniques and the contributions of different specific entities in FTIR measurements.
Evidence of Dual Phase for the Amorphous State of Polymers from Crystallization Kinetics
J.P. Ibar, May 2004
We analyze constant rate cooling and heating crystallization kinetics of PET samples by DSC. The samples have various degree of disentanglement, obtained by the new TekFlow processing technology. According to EKNET interactive Dual Phase model, the amorphous state is made up of two coupled and interactive amorphous phases. These two phases have distinct viscoelastic and thermodynamic characteristics (Tg, free volume, G' and G etc.) which are determined by the potential energy of the conformers and by the state of entanglement of the macromolecular coils.Semi-crystalline polymers such as Polyethylene Terephtalate (PET) are amorphous in the molten state and should have Dual Phase behavior. The phase duality should manifest itself during crystallization from the melt during cooling or during cold crystallization while heating quenched samples.The purpose of this communication is to quantitatively describe the kinetics of crystallization of PET samples with a dual phase kinetics formulation and determine the respective influence of molecular weight and degree of entanglement on the kinetics parameters rate of crystallization and percentage of crystallinity."
The Influence of Ionic Functionality on the Interfacial Tension in Polypropylene/Copolyester Blends
Peyton L. Hopson, Robert B. Moore, May 2004
The interfacial tension of binary blends of an amorphous copolyester, poly(ethylene-co-cyclohexane 1,4-dimethanol terephthalate) (PETG) and an itaconic acid grafted polypropylene (PP-g-IA) have been investigated in order to elucidate the effect of ionic incorporation on interfacial tension. PP-g-IA was formed through reactive extrusion using dicumyl peroxide as the initiator with neutralization agents of zinc and magnesium oxide. Interfacial tension was determined using the breaking thread method (BTM). Reductions in interfacial tension have been seen with the grafting of itaconic acid onto PP, with neutralized PP-g-IA showing further reductions in the interfacial tension between the blend components.
In-Situ Ultrasonic Compatibilization of Dynamically Vulcanized PP/EPDM Blends
Wenlai Feng, A.I. Isayev, May 2004
Dynamically vulcanized PP/EPDM blends were treated by high intensity ultrasonic waves during extrusion. These blends were compared with unvulcanized PP/EPDM blends that were treated by ultrasound during extrusion and then dynamically vulcanized. Die pressure and power consumption were measured. The effect of different gap sizes, ratio of components, and number of ultrasonic horns were investigated. The rheological properties, morphology and mechanical properties of the blends with and without ultrasonic treatment were compared. The results obtained indicated that ultrasonic treatment induced the thermo-mechanical degradation causing enhanced molecular transport and chemical reactions at the interfaces, thus leading to in-situ compatibilization, which is evident by the morphological and mechanical property studies. Processing conditions were established for enhanced in-situ compatibilization of the dynamically vulcanized PP/EPDM blends.
Photomechanical Oxidation of Anisotropic Polyethylene
J.R. White, T.A. Egerton, P.A. Christensen, Changqing Jin, May 2004
Blown polyethylene film was exposed to ultraviolet (UV) irradiation while under stress applied (i) parallel and (ii) perpendicular to the machine direction. Oxidation was followed using the FTIR carbonyl index and was found to accelerate under tensile stress. Some samples broke during UV-tension exposure and did so in a shorter time when stress was applied in the machine direction than when it was applied in the transverse direction. Samples with different TiO2 pigments gave different rates of carbonyl development; some showed greater acceleration when stress was applied parallel to the machine direction, others when it was applied transversely. The carbonyl index was approximately the same at break for all longitudinally stressed samples and a higher carbonyl index was found at the onset of cracking for transversely strained samples.
Biaxial Orientation of Multilayer LDPE/PET Films: Structure and Properties
A. Ajji, X. Zhang, May 2004
In this study, initially thick low density polyethylene / polyethylene terephthalate (LDPE/PET) multilayer blown films were biaxially stretched at different temperatures. The effect of draw temperature and draw speed as well as adhesion between the LDPE and PET layers, through a middle tie layer, on orientation and some properties is studied. The properties of interest are tensile properties, tear, impact strength and haze. The results indicate that the tie layer enhances the properties of stretched films and that toughness is strongly affected by draw ratio and little by draw speed and temperature in the ranges studied.
Haze Improvement with Addition of HP-LDPE or HDPE; Part II - Mechanistic Understanding
H.Y. Chen, J. Li, R.L. Sammler, C.T. Lue, R. Kolb, T.H. Kwalk, May 2004
Adding small amounts (less than 10%) of High Pressure Low Density Polyethylene (HP-LDPE) or High Density Polyethylene (HDPE) to a Metallocene Linear Low Density Polyethylene (mLLDPE) led to a reduction in haze of the resulting blown films. It was found that for both systems the haze reduction was mainly due to the reduction of surface roughness. mLLDPE films shows a rough surface with large lamellar aggregates or spherulitic superstructure. By adding HP-LDPE or HDPE to mLLDPE, the lamellar aggregates became smaller or the structure became simply a row structure in HP-LDPE blends. Both changes led to smoother surfaces. Although majority of the haze came from the light scattering of the rough film surface, the similarity between surface morphology and bulk morphology suggests that haze could be correlated to the bulk structure. In fact, it was found that the haze showed a good correlation with lamellar orientation. Blends with a higher lamellar orientation showed lower haze. Attempt to correlate haze with overall melt elasticity was not successful. The results suggested that the overall melt elasticity was not the dominate factor for forming oriented lamellae. Instead, the formation of oriented lamellae is promoted by the small amounts of molecules with extremely long relaxation times, which behave as oriented nuclei.
Predictions of MD Tear Strengths of Some Solution Octene LLDPE Film Resins
XiaoChuan (Alan) Wang, May 2004
By incorporating both polymer properties and processing variables, a robust model has been developed through multivariate statistical analysis for the MD tear strengths of some solution octene LLDPE resins produced using NOVA Chemicals' Advanced SCLAIRTECH technology. It is found that the model is applicable to different resins and processing conditions. The model suggests that MD tear strength is a nonlinear function of polymer properties, machine direction strain rate and process time. It has demonstrated its utility in product development at extrusion film lines of different dimensions, and to resins produced at both pilot and commercial scales.
Linear and Non-Linear Biaxial Stress-Optical Behavior in PET Films as Observed by Real Time True Stress-True Strain-Birefringence Technique
M. Hassan, M. Cakmak, May 2004
Biaxial stretching of polymer films such as PET is a common process in the industry. Being able to monitor the stress-strain mechanical behavior of the films during stretching and linking this with the birefringence behavior provides a good tool to investigate stress and strain optical behavior of these films undergoing complex structural organization The results indicate that PET exhibits four stage stress optical behavior in simultaneous biaxial mode. The first stage is traditional linear stress optical behavior with stress optical constant (SOC) of 5.8 GPa-1 (5800 Brewsters). In the second stage birefringence rapidly increases and this is typically associate with the formation of poorly ordered crystals that are assumed to be at the nodes of the physical network. In the third stage the birefringence begins to level off with considerable negative slope variation with stress where the crystallinity further develops. The fourth stage was observed only at high stretching rates and in this distinct stage, birefringence become near constant while stress continues to increase as the chains have reached their full extensibilities.
The Effect of Maleic Anhydride Coupling Agent on Melt Processed Semi-Crystalline PET Nanocomposite Films
Christopher Thellen, Caitlin Orroth, Danielle Froio, Jeanne Lucciarini, JoAnn Ratto, Ajit Ranade, Nandika Anne D'Souza, May 2004
Semi-crystalline PET/montmorillonite nanocomposite films were processed by melt-extrusion along with 0.5% maleic anhydride as a coupling agent. Mechanical, thermal, barrier and morphological properties of the nanocomposite films with and without the coupling agent were examined. The nanocomposites have demonstrated an intercalated/exfoliated morphology with the montmorillonite acting as a crystal-nucleating agent in all of the nanocomposite film samples. DSC experiments show this effect through faster nucleation rates and an increased overall degree of crystallization. A depressed glass transition temperature is observed in all nanocomposite samples along with an increased Young's modulus and decrease in film toughness.
The Influence of Molecular Weight on the Relaxation Behavior of Uniaxially Strethed PEN Films as Investigated by Real Time Spectral Birefringence Technique
Carla Isabel Martins, Miko Cakmak, May 2004
The influence of molecular weight (Mw) on the structural evolution of as cast amorphous poly (ethylene naphthalene), PEN, during uniaxial stretching and further relaxation is investigated by real time measurement of the true mechanical and optical behavior of the material in the rubbery state. Uniaxial deformation behavior reveals that stress-optical behavior is composed of three regions: (I) traditional stress optical region where the polymer remains amorphous, (II) fast birefringence increase region that accompany rapid rise in crystallinity and (III) birefringence saturation region. Both materials follow the stress optical rule (SOR) at low deformation levels with a stress optical constant of 27.5 GPa-1. Stress-optical behavior deviates from linearity in both MW PEN's when crystallinity exceeds 7% and the material exhibit nematic order. The deviation from linearity occurs at lower stress levels for the low MW material, nevertheless. The mechanism of neck formation has a considerable influence on the crystallization of the material. After neck starts the crystallinity increases rapidly in both materials, reaching a saturation value of approx. 35% in crystallinity when strain hardening occurs. The preliminary studies revealed that the relaxation behavior of PEN involves a complete orientation recovery following the stress optical rule when the material is first stretched within the Region I and if stretched beyond the linear range the relaxation stage is found to accompany partial orientation relaxation followed by crystallization.
Haze Improvement with Addition of HP-LDPE or HDPE: Part I - Blown Film Property Comparison
C.T. Lue, T.H. Kwalk, D. Li, C.R. Davey, D.Y. Chiu, May 2004
Blends of a Metallocene Linear Low Density Polyethylene (mLLDPE) with a variety of high pressure Low Density Polyethylene (HP-LDPE) or High Density Polyethylene (HDPE) at different blend ratios were investigated. Effects of these additions on blown film haze and toughness are discussed.Dramatic improvement in haze is achievable either by HP-LDPE addition or by HDPE addition. The improvement in haze, however, is usually accompanied with losses in mechanical property. Careful choice of blending partner and level is crucial for the best balance of haze and mechanical properties.
The Influence of Draw Conditions on the Morphology and Physical Performance of POE Film
Chih-Ching Lin, Yao-Kuei Hsiao, Chao-Yin Chuang, May 2004
The influence of draw conditions on the morphology and physical performance of polyethylene-octene elastomer(POE) film were studied in this paper. The influence of draw conditions on the morphology of POE film was discussed via wide-angle X-ray diffraction (WAXD). The results showed that draw conditions caused POE film to produce a (110) plane crystalline peak in PE. When the draw ratio (DR) = 3, the interference intensity at draw temperature (DT) = 90? was greater than that at DT = 75?; and when DR = 6, the interference intensity at DT = 75? was greater than that at DT = 90 ? . Elastic recovery rate and stress-strain value were tested using an Instron multi-testing machine. The results were used to establish a dynamic deformation mechanism. The results showed that, after draw processing of POE, the stress value fell after approaching the saturation point with the increase in draw ratio. Furthermore, it was also shown that the elastic recovery rate and stress retention rate were better at DT = 75? than at DT = 90?.
Morphology Evolution in PTFE as a Function of Deformation and Melt Time and Temperature: Nano-Fibrils and Single- and Multi-Molecule Folded Chain Single Crystals
Phillip H. Geil, Junyan Yang, Rachel A. Williams, Kathryn L. Petersen, Tsuey-Chen Long, Ping Xu, May 2004
Evolution of the morphology of dispersed PTFE dispersion particles on glass and mica as a function of melt time and temperature indicates that individual molecules wander" on the substrate crystallizing (from a chain- folded "mesomorphic" state it is suggested) in single and multi-molecule chain folded single crystals when cooled. Shearing of the particles results in nano-fibril production; annealing results in shish-kebab formation through single molecule addition. Nascent dispersion particle structure will also be considered."
Influence of Co-Monomer Distribution Profile on the Crystallization Characteristics and Physical Properties of High Density Polyethylene
Rajendra K. Krishnaswamy, Qing Yang, May 2004
Three sets of two-component blends from various narrow-MWD (molecular weight distribution), linear (no rheologically significant long branches) polyethylenes were prepared with multiple compositions in each set of blends. These blends were deliberately prepared such that the branching (from 1-hexene co-monomer) was present exclusively on either the high or the low molecular weight blend component. The average branching content in each blend component was verified to be uniform across its MWD. In this study, the influence exerted by such selective placing of the branching on the crystallization characteristics of the resulting blends will be discussed. Further, some new observations relating to the tensile stress-strain behavior of these blends will also be described.
The Effect of Blend Composition on the Deformation Behavior of PEN/PEI Blend Using Online Mechano-Optical Technique
Karnav Kanuga, M. Cakmak, May 2004
The influence of blend composition on deformation as well as stress-optical behavior of cast amorphous PEN/PEI blends is investigated above their respected glass transition temperatures. To elucidate the structural changes occurring during stretching a real time birefringence technique coupled with true stress/strain measurement technique is used. These techniques are able to track fast changes in birefringence and stress levels as the film is being deformed. The results obtained by these two techniques permit determination of the stress optical coefficient and the limits of validity of Stress-Optical Rule (SOR). Further investigations by X-ray and DSC measurements help to understand and clarify the structure developed during the deformation process of the material. These studies indicate that the deformation of 95/5 and 90/10 PEN/PEI blends in rubbery state involves three main stages. In the first stage the material remains amorphous following the stress optical rule. In the second stage the birefringence rises rapidly and it is associated with the highly disordered nematic like structure formation. The final stage is attributed to finite chain extensibility resulting in little change in birefringence with significant stress increase. 80/20 PEN/PEI blend does not show up the final stage III in the deformation process and it seems it is delayed to higher stretch levels as the crystallization is highly suppressed due to dilution effect .
Structure-Property Relationships in Metallocene Based Ethylene-Octene Plastomers
Manika Varma-Nair, M.G. Williams, N.R. Dharmarajan, May 2004
Ethylene copolymers are extensively used in the automotive industry as preferred plastomers for impact modification of polypropylene. Performance of these plastomers is strongly effected by the molecular architecture determined by the type and amount of comonomer, and the distribution of the co-units along the polymer backbone. In this paper we describe the analysis of a series of commercial and developmental metallocene random ethylene-octene copolymers with low and ultra-low density in the range 0.860 g/cm3 to 0.906 g/cm3, and melt index between 0.5 to 27. Thermodynamic properties and crystallization behavior are evaluated using differential scanning calorimetry (DSC) to determine the effect of crystalline and amorphous phase on the density and mechanical performance. Peak melting temperature and crystallinity are almost linearly related to the density while MI does not appear to have any effect on the crystalline phase. A thermal segregation technique is used to determine the influence of octene branches on the sequence length of crystallizable methylene units. With an increase in octene content, glass transition broadens and decreases with density as crystallization mechanism changes. Longer sequences form lamellar structures while presence of shorter sequence lead to a mixed crystalline morphology consisting of predominantly fringed-micellar crystals. Results of modelling of properties and performance will be discussed and compared with the previous analysis of a series of ethylene-butene plastomers.
Controlled Epoxy Network Structure-Property Relationships: The Effect of Chain Termination
Nikhil Verghese, Maurice Marks, James Hrovat, Ha Pham, May 2004
While epoxy thermosets are commonly used and are best known for their high glass transition temperature (Tg), creep resistance, environmental resistance and high stiffness, they are extremely complicated and intractable to thorough investigation. This is in part due to the fact that these are curing systems and gelation marks a turning point in the system’s performance as well as ability to be probed for effective structure-property relationships. In addition, practical formulations often contain multiple components that have subtle but important interactions to the final performance.In this presentation we will cover work that was performed recently to quantitatively probe the effect of one such practical yet important effect, namely chain termination. The effect of the size as well as flexibility of the chain termination group will be examined via a controlled host matrix chemistry that comprises of DER™ 332 as the epoxy, bisphenol A (BA) as extender and tris(4- hydroxyphenyl)ethane (THPE) as a crosslinker. Data and trends pertaining to Tg, stiffness, yield strength, fracture toughness and thermal expansion coefficient will be discussed.


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