SPE Library
The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
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Conference Proceedings
A Six-Sigma Approach for Investment Plans in a Plastics Production Plant
Gabriel Ventura, Ranganath Shastri, Miguel Ángel Vega, May 2007
It is possible to demonstrate that QFD (Quality Function Deployment) within a norm space permits to realize gap analysis and investment plans for a complex plastics production plant, using its process capability in the last Quality house.For the use of the same metric: DPMO, it is possible to compare man power, materials, maintenance, machinery, environment and methods. In these terms it is feasible to benchmarking the investment plans.
Failure Analysis of a Refrigerator Component Based on DOE" & Optimization Techniques"
Gabriel Ventura, Ranganath Shastri, Miguel Ángel Vega, May 2007
There are many engineering situations where it is not necessary to analyze the whole domain of a physical model.In such instances, we demonstrate that it is possible to obtain an equivalent bilinear form using Lax-Milgram theorem with an orthogonal form applied to electrical appliance and turbomachinery, with a transfer matrix and variation principles.This transfer matrix solves a problem in shorter time than the Traditional DOE-FEA (design of Experiments) (Finite Element Analysis) Methods.
Weathering and Light Stabilization of Select Plastic Materials
Peter Solera, May 2007
In this paper we will examine various aspects of weatherability for several significant polymers. Light stabilization and polymer degradation mechanisms will be compared as well as strategies for imparting weatherability for these materials. Several UV aging studies will be included to illustrate stabilization techniques, and some comparative studies highlighting accelerated weathering vs. outdoor weathering will be discussed.
A Study of Integration of LIGA and MEDM Technology on the Micro Injection Molding of Ink Jet Printers' Nozzle Plates
S.C. Tseng, Y.C. Chen, B.Y. Shew, May 2007
A new approach is introduced to fabricate nozzle plates in this study. The micro mold was made by integration of LIGA and M-EDM technology to improve the accuracy. Micro injection molding was applied to produce the nozzle plates. There are sixty micro through-holes on each plate. The diameters of molded nozzle plates were 102±1 micro meters. The proposed manufacture procedures are believed to be more accurate and economical.
Analysis of Injection Molding to Fabricate Patterned Media with Nano Pillars
Minseok Choi, Namseok Lee, Jeongwon Han, Jongill Hong, Shinill Kang, May 2007
We examined a low cost technology for perpendicular magnetic patterned media that uses a metallic nanostamper and injection molding process. In this paper, we focused on the analysis of injection molding with passive heating, where the replication of 50 nm nanopillar arrays was successful. The effect of the thermal insulation layer on the replication quality was examined by analytical and experimental methods. Finally, the properties of magnetic layer deposited on the injection molded nanopillar array were analyzed.
Viscoelastic Behavior of Sulfonated Polystyrene Ionomers
R.A. Weiss, Hongying Zhao, May 2007
Sulfonated polystyrene ionomers (alkali metal salts) with molecular weight below the entanglement molecular weight of polystyrene were prepared. The rheological behavior of the ionomers was characterized by dynamic and steady-state shear experiments. In general, the viscosity of the ionomers increased with sulfonation level and as the size of the cation decreased. Whereas, the starting polystyrenes were Newtonian fluids, the ionomers were non-Newtonian and viscoelastic.
On Formulation and Processing of Rigid Polyurethanes via Controlled Cure
Sam Kharchenko, Jack Huang, May 2007
A range of polyurethanes (PU) based on methylene diphenyl diisocyanate and polyether polyols varying in molecular mass, backbone structure and functionality are studied. Examination of the kinetic parameters of the PU reactions shows that the curing behavior and the hardness of such complex PU systems do not follow simple mixing rules. Scaling relationships to describe these complex dependencies and basic guidelines for formulation and processing are developed. Limitations of using the OHindex to predict the polyol reactivity are also discussed.
Validation of Injection Molding Simulation Results to Actual Molded Product
Ryan Gelotte, Matthew Broadbent, May 2007
The flow patterns and injection pressures predicted using injection molding simulation software and actual flow patterns and injection pressures of the molded parts using a short study were compared and quantified. A method of validation was developed to compare the simulation results with actual molded parts and indicated that by using the correct combination of mesh type and certain process settings in the simulation software, an accurate prediction can be achieved with the simulation.
Flexural Creep Testing of Thermoplastic Composites
Venkata S. Chevali, Gregg M. Janowski, May 2007
Flexural creep behavior of nylon 6/6 based long fiber thermoplastics (LFT) was determined using transient and dynamic testing methods. While the effect of increasing fiber volume fraction reduced creep, there was only a negligible effect of flow orientation effect. The creep data generated by dynamic mechanical analysis (DMA) tests was consistent with the transient tests.
PVC / Layered Silicate Nanocomposites: Preparation, Characterization, and Properties
Noble Francis, Daniel F. Schmidt, May 2007
Optically transparent nanocomposites were prepared via twin-screw extrusion of a medical-grade flexible PVC resin and an organically modified montmorillonite. Intercalation and orientation of the montmorillonite layers were observed via x-ray diffraction. A positive influence on barrier properties was noted, including a five-fold increase in oxygen barrier at minimal clay loading. Consistent with the literature, no significant changes in thermal stability in air were observed.
Preparation and Characterization of Polyester Thermoset Xerogels for Tissue Engineering Scaffolds
Poonam Borgaonkar, Sachin Sharma, Daniel F. Schmidt, Ming Chen, Sankha Bhowmick, May 2007
Porous polyester thermoset xerogels have been produced via sol-gel chemistry. The pore structure of these materials is tunable and can be altered independent of or in tandem with alterations in composition by adjusting solvent quality, solids content, and processing methodology. Cytocompatibility studies on selected xerogels imply effects of both pore size and materials chemistry, with fully aliphatic polyesters with large pore structures allowing for the growth of mammalian cells.
Modeling of Expansion of Extruded Filamentary Foam
Zhenjin Zhu, Jing Wang, Chul B. Park, May 2007
This paper undertook a numerical study to characterize expansion of extruded polystyrene foam blown with CO2. The effects of processing parameters on foam expansion outside filamentary extrusion dies were examined. Efforts were made to optimize the processing parameters for the achievement of highly expanded foams.
Rigid PVC-Based Nanocomposites Produced through a Novel Melt-Blending Approach
Laurent M. Matuana, Omar Faruk, May 2007
Based on the fusion behaviors of PVC, the influence of compounding route of PVC/Montmorillonite nanocomposites, on their properties, including flexural, tensile, dispersion, and morphology was studied. The experimental results indicate that both the extent of property improvement and dispersion of nanaoparticles in PVC/Montmorillonite nanocomposites are strongly influenced by the degree of gelation achieved in PVC compounds during processing.
Synthesis and Characterization of Some Novel Polyurethanes Based on Rigid or Flexible Aromatic Diisocyanates and Mixtures of Them
Cristina Prisacariu, C. Paul Buckley, May 2007
Polyurethane elastomers were synthesized with ethylene glycol as chain extender. The macrodiol was poly(ethylene adipate) MW = 2000 ± 50. Two isocyanates were employed: 4,4- diphenylmethane diisocyanate (MDI) and 4,4’ - dibenzyl diisocyanate (DBDI), alone or as mixtures. Materials were characterized by DMA, DSC and WAXS. Changes induced by varying the type and the number of isocyanates and the order of their introduction were followed. Crystallinity was strongly reduced when DBDI was mixed with MDI.
Interfacial Adhesion between Hydroxyapatite and Poly(?- Caprolactone) and Their Electrospun Composite Toughness
Shing-Chung Wong, Avinash Baji, May 2007
The interfacial adhesive strength between hydroxyapatite (HAP) and poly(?-caprolactone) (PCL) were determined using T-peel tests. Their composite fracture toughness was determined using essential work of fracture concept. Electrospinning techniques were employed to obtain nanometer scale PCL fibers with and without HAP reinforcements which also create micrometer-scale porosity in the structure. The effects of HAP morphology and HAP content on mechanical properties were evaluated.
Manipulating the Orientation at End of Fill
Brian A. Young, May 2007
Orientation of polymer chains has been shown to have a major effect on component properties. The chain orientation at the end of fill of a component is different from most other areas. Overflows have been used in various areas of the plastics industry to improve weld line strength and provide a more consistent gas channel in gas-assist molding. This study will investigate if the use of overflows to change the orientation of the polymer chains provides a more capable molding condition.
Involving Non-Engineering Students with Engineering Students to Enhance the Learning Experience
Jonathan Meckley, May 2007
Allowing engineering students to work with students of other disciplines offers them an experience they can take with them as they begin their career in industry. The college students take the project from concept to a manufactured product. At the beginning of the project, psychology students interact with sixth-grade students to determine the best features to include in a car. The marketing students will then create a display and video commercial for each car.
The Effect of Overflow Tabs on Affected Area
Jeremy Haibach, Trevor Thorwart, Josh Glessner, May 2007
The purpose of this project was to determine the effect of overflow tabs on ‘affected area’. It was done because overflow tabs could prove to be very important in the medical industry, where tight tolerance parts are needed. Along with that industry, parts with limited gating locations could also use overflow tabs to provide more consistent flow throughout the part.
Rubber-Assisted Embossing Process
Pratapkumar Nagarajan, Katherine Abbott, Donggang Yao, May 2007
This study investigated a rubber-assisted embossing process for structuring thin polymer films. The main advantages of a rubber support instead of a hard counter tool include simplification of the embossing tool, protection of the embossing master, buildup of high pressure, and ease of mold separation. With rubber-assisted embossing, thin polystyrene films in a thickness of 25 ?m were accurately patterned with microgrooves of characteristic dimensions on the order of 100 ?m.
Fountain Flow in Water-Assisted Melt Filling
Xu-Hui Liu, Han-Xiong Huang, May 2007
Water-assisted injection molding (WAIM) provides a new means to manufacture hollow parts at lower costs. However, little work has been done to understand how the polymer melt flows under applying high pressure water. Experimental investigations on the melt flow, especially the fountain flow during water-assisted melt filling in an emulated mold were conducted in this work. The experimental results revealed the formation of fountain flow during melt filling under applying high pressure water.
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