SPE Library

The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
Morphology Development In Lldpe Stretch Films Prepared With Different Cast Film Process Parameters
Hoda Bayazian, March 2019
Linear low density polyethylene (LLDPE) cast stretch films were produced to evaluate the effects of line speed, air gap, frost line and film thickness on the morphology of the prepared films. Surface morphology of the films were observed using scanning electron microscopy (SEM). It was found that the most effective parameter on the surface morphology of the films is line speed followed by air gap. In addition, relaxation behavior of LLDPE resins was investigated using rheological measurements. For the films with similar thicknesses but prepared at different line speeds the time scale for the melt to relax was correlated with the crystal phase development in the films, which affected the microstructure and crystalline morphology of the films.
Stepped Isothermal Method And Stress Rate Accelerated Creep Rupture Tests For Efficient Creep Investigaton Of Engineering Thermoplastics
Gerald Pilz, March 2019
The use of thermoplastic based fiber reinforced materials in demanding structural applications concerning long-term loading in combination with elevated temperatures and media influences requires comprehensive but experimentally practicable materials characterization. While for the long-term estimation of the time dependent deformation behavior a number of extrapolation methods for creep and creep rupture characterization is available, most of these methods are still rather time consuming. An useful approach for time-efficient creep characterization is the stepped isothermal method (SIM), which primarily was established for fiber and textile materials [1, 2]. The first goal of the present paper was to investigate the applicability of SIM for glass fiber reinforced PA6.6 and PPA materials in the saturated wet state. For this purpose, a specific media cell with an integrated deformation measuring system was built up for creep tests under water immersed test conditions for standard tensile test specimens. Based on the stepwise increased test temperature, the creep deformation was accelerated and subsequently used for the creation of creep modulus master-curve generation in accordance to SIM. Generally, plausible results for the time dependent creep modulus of the materials at 60 °C in wet state were obtained, also in good agreement with the corresponding short-term Young´s modulus values. Further on, a new methodical approach for the estimation of the long-term creep rupture behavior was developed. The established stress rate accelerated creep rupture test method (SRCR) allows for very time-efficient creep rupture estimation based on a series of stress rate dependent tests at various initial load levels. In the present study, this method was successfully implemented on glass fiber reinforced PPA materials. The time dependent creep rupture strength was obtained over a time range up to more than 5 years, also in good agreement with the results of additionally performed conventional creep rupture tests.
Multimodal Hdpe For Small Part Blow Molding
Eric Day, March 2019
A unique combination of reactors, a multi-zone circulating reactor (MZCR) in cascade with a fluidized bed reactor (FBR), and proprietary catalyst used to polymerize multimodal HDPE has enabled the pilot-scale production of Ziegler-Natta (ZN) HDPE blow molding resins having processability similar to chromium (Cr) HDPE resins while maintaining the high environmental stress crack resistance (ESCR) of a ZN HDPE resin. Additionally, these pilotscale multi-modal ZN HDPE blow molding resins feature significantly lower gel levels, giving improved surface finish of blow molded articles. This unique combination of reactors is the basis of LyondellBasell’s new, proprietary Hyperzone PE technology. Resins were produced at the pilot-plant scale for both general-purpose small-container blow molding (SBM) and typical largepart blow molding (LBM) applications, such as intermediate bulk containers (IBC) and drums. This paper focuses on the pilot plant-produced SBM HDPE resin and vits properties.
Troubleshooting A Rate Limitation At The Entry Of A Barrier Melting Section Of A Single-Screw Extruder
Abhishek Dutta, March 2019
Barrier melting sections are extremely common and useful for single-screw extruders. Some common mistakes in their design and operation, however, can reduce their performance. A common mistake when attempting to decrease the discharge temperature for a single-screw extrusion process is to decrease all barrel temperature zones. This method, however, can cause the specific rate of the extruder to decrease for screws that use barrier melting sections. This paper will describe the problem, provide laboratory extrusions that demonstrate the problem, and then provide a case study.
History Of Colour In Plastics
Lucy Gibbons, March 2019
Colour is essential to human experience. From pre-history, through ancient civilization into the modern era, cultures have strived to create colour in the objects around them. Early peoples exploited natural resources to create images from their surroundings, such as red earth, black soot and white chalk. With time people developed more sophisticated techniques to refine minerals to generate a wider palette with blue, green, bright red and yellow. Often toxic in nature, these early inorganic pigments formed the skeleton of the pigment manufacturing industry. With the discovery of coal tar in the 1800s, and the ensuing rapid industrialization of synthetic chemistry, an explosion of colour transpired, leading to the modern chemical industry. The historic generation of plastics followed a parallel path, beginning with use of natural materials such as ivory and tortoiseshell. Progression to processing of natural materials such as rubber, cellulose and shellac to generate more functional plastics, evolved to a place where coal tar chemistry provided a natural next step. This culminated in the discovery of Bakelite, the first fully synthetic plastic in 1907, which ignited the imagination for plastic materials, and the widespread production of consumer and industrial items accelerated. Colour and plastic developments went hand in hand, as by the 1950s the desire for brightly coloured, functional items sky-rocketed. Pigment chemistries were re-imagined with this new era in mind and from this point colour effects were generated specifically for plastic functionality. Textile fibers, automotive parts, plastic bottles, packaging and film; all un-thinkable now, without the effect of colour.
Fabrication And Characterization Of 3-D Porous Hydroxyapatite (Ha)-Modified Polyurethane (Pu) Scaffold For Tissue Engineering
Qianting Wang, March 2019
In this work, the 3-D porous hydroxyapatite (HA)-modified polyurethane (PU) scaffold successfully fabricated by using simple ultrasonic assisted method. The hydrophilcity, water absorption and mechanical properties of HA-modified PU scaffold were significant higher than those of PU scaffolds. Compared with PU scaffold, the addition of HA nanoparticles could effectively improve the attachment and growth of human umbilical vein endothelial cells (HUVECs) cultured on the HA-modified PU scaffold. These results suggest that HA-modified PU scaffold possesses a great potential to be used as tissue engineering scaffold and the ultrasonic assisted technique could be a simple, effective and universal method to decorate the tissue engineering scaffold.
Accelerated Aging And Viscoelastic Effects Of Medical-Grade Resins
Rob Klein, March 2019
Accelerated aging is used throughout the Medical Device sector and other sectors to evaluate materials and devices in an accelerated fashion. Accelerated aging has several typical modes, depending on the type of materials and functional mechanisms involved. One mode is related to stress relaxation and creep, which impacts the function of parts under sustained strain or stress as well as influencing time to develop cracks. This paper explores viscoelastic behavior of moderate melt flow medical grade polycarbonate as related to accelerated aging. The relationships between stress relaxation, creep, and complex modulus (as a function of time and temperature) are discussed. An example demonstrating the correlations between stress relaxation, creep, and Dynamic Mechanical Analysis (DMA) master curve data for a medical-grade polycarbonate is provided. Additionally, Q10 factors as intended for accelerated aging are estimated for stress relaxation of medical-grade polycarbonate using DMA master curve results. Accelerated aging is used throughout the Medical Device sector and other sectors to evaluate materials and devices in an accelerated fashion. Accelerated aging has several typical modes, depending on the type of materials and functional mechanisms involved. One mode is related to stress relaxation and creep, which impacts the function of parts under sustained strain or stress as well as influencing time to develop cracks. This paper explores viscoelastic behavior of moderate melt flow medical grade polycarbonate as related to accelerated aging. The relationships between stress relaxation, creep, and complex modulus (as a function of time and temperature) are discussed. An example demonstrating the correlations between stress relaxation, creep, and Dynamic Mechanical Analysis (DMA) master curve data for a medical-grade polycarbonate is provided. Additionally, Q10 factors as intended for accelerated aging are estimated for stress relaxation of medical-grade polycarbonate using DMA master curve results. Accelerated aging is used throughout the Medical Device sector and other sectors to evaluate materials and devices in an accelerated fashion. Accelerated aging has several typical modes, depending on the type of materials and functional mechanisms involved. One mode is related to stress relaxation and creep, which impacts the function of parts under sustained strain or stress as well as influencing time to develop cracks. This paper explores viscoelastic behavior of moderate melt flow medical grade polycarbonate as related to accelerated aging. The relationships between stress relaxation, creep, and complex modulus (as a function of time and temperature) are discussed. An example demonstrating the correlations between stress relaxation, creep, and Dynamic Mechanical Analysis (DMA) master curve data for a medical-grade polycarbonate is provided. Additionally, Q10 factors as intended for accelerated aging are estimated for stress relaxation of medical-grade polycarbonate using DMA master curve results.
Innovations And New Trends In Specialty Coatings
Karen Kukla, March 2019
Coatings on plastics is a very dynamic space driven both by the desire for more environmentally friendly coatings and by an ever increasing demand for improved performance and additional functionality. This presentation will discuss the reduction of the carbon footprint by use of waterborne coatings and UV coatings. In addition the importance of UV coatings to improve scratch and mar resistance, improve energy efficiencies and increase throughput will be discussed. Options for dual cure allowing for upgrade of conventional lines and coating formulations to meet customer needs will be covered. New innovations and future directions base on customer needs and expectations will be reviewed as well. The use of bright colors using Nano pigments and dyes, self-healing paint, easy to clean coatings for high gloss interiors, anti-glare coatings and UV reflective coatings to control interior temperature will be introduced.
The Effects Of Material Propertis On Microcellualr Injection Molding Simulation
Sejin Han | Syed Rehmathullah, March 2019
This paper presents a study about the effects of material properties on the modeling of the microcellular injection molding process. In particular, the effects of gas solubility and diffusivity data on the simulation results were examined. Often, actual measured data are not available for these properties. The effectiveness of using a generic equation to estimate these values has been evaluated by comparing the simulation results from this to a simulation that uses the actual measured data. The study indicates that by properly using these estimated material properties data, meaningful simulation results can be obtained.
Influence Of Polyolefin Cross-Contamination On The Slow Crack Growth Resistance Of Polyethylene Pipe Grade
Andreas Frank, March 2019
In order to increase added value of plastics in terms improved circular economy, an increased use of recycled polymers becomes more and more important, also for the plastic pipes industry. Unfortunately, compared to specially designed virgin pipe grades, recycled polymers show deteriorated long-term properties. The current paper investigates the influence of different polyolefin cross-contaminations on the slow crack growth (SCG) resistance of a polyethylene (PE) pipe grade. The investigation was conducted with the CRB test on blends of a virgin PE100 with different contents of polypropylene homopolymer (PP-H), blow molding PE-HD, and a recycled first generation PE-HD. The results demonstrate that 5% of cross-contamination content already results in a significant reduction of SCG resistance and that the highest reduction is caused by blending with PP-H.
Medical Plastics: Review Of Material Models Required For Simulation Through Case Studies
Hossam Metwally, March 2019
Computer simulation to model the manufacturing as well as the performance of plastic part requires a good understanding of the material properties at the representative conditions. The same material behaves differently during different processes, e.g. extrusion is a shear dominated process, while thermoforming is elongation dominated. Additionally, viscoelastic effects may be relevant to capture since they control the amount of die swell depending on the geometry and process conditions. Additionally, plastics are also non-linear materials and exhibit non-linear stress-strain behavior that can possibly be rate dependent as well. This paper is a review highlighting the different processes that have been modeled before and the different material models that are required for a successful simulation will be discussed. The following case studies will be used to highlight the material models; catheter extrusion, tray thermoforming, and catheter kinking.
Cure And Mechanical Properties Of Filled, Zno-Free, Sulfur-Cured Isoprene Rubber
Barbara DeButts, March 2019
In this study, agricultural proteins were compounded into synthetic isoprene rubber (IR) and sulfur-cured. A constant filler loading of 8 parts per hundred rubber (phr) was used to evaluate the reinforcing capabilities of two full proteins, i.e., corn zein (Zein) and gliadin from wheat (Gd), a hydrolyzed protein, i.e., trypsin hydrolyzed gliadin (THGd), and a neat amino acid, i.e., arginine (Arg). Cure meter testing, tensile testing, and swelling experiments were performed to assess the curing kinetics, Young’s moduli (E), hysteresis, and crosslink densities of the vulcanizates. The filled vulcanizates exhibited comparable or higher E and [X] than an unfilled IR Control, but slower curing kinetics. The hysteresis, or unrecoverable mechanical energy, decreased with increasing elongation in the filled vulcanizates, which was opposite the behavior of the IR Control.
Development Of A Plastic Frame Mounted Bumper That Meets The Requirements For Pedestrian Safety Performance
David Job, March 2019
This paper presents the design and development of a chassis mounted pick-up truck front bumper for the 2018 Ranger Raptor which meets pedestrian safety performance. Truck bumpers are traditionally made of steel to meet customer expectations of a durable vehicle capable of suitable crash protection performance, firmness of feel and rugged styling. Pedestrian safety performance is increasingly becoming a regulation for the sale of vehicles in selected markets around the world.A traditionally mounted steel bumper does not have suitable energy absorption to meet this regulatory requirement. The bumper developed by Ford of Australia uses sandwich plastic bumper fascia with a steel support structure to meet the conflicting requirements of a soft front for pedestrian protection and a solid substructure to meet low speed crash requirements including static and dynamic stiffness for durability.
Challenge To Prepare For Flame-Retardant Polypropylene Foam Boards
Wenli Zhu, March 2019
In this work, neat polypropylene (PP) foam boards was produced under different saturation pressure and foaming temperature by using supercritical CO2 as a blowing agent in an industrial-scale batch foaming system. In addition, the effort was made to prepare for flame-retardant PP foam samples by introducing a basic magnesium sulfate whisker (MSW). The preliminary results showed that with addition of MSW, PP composite samples have increased Limiting Oxygen Index (LOI) and increased tensile property. As the increase of amount of MSW, the average cell sizes of PP foams have little change but the cell densities were decreased thus the volume expansion ratios were decreased as result. To obtain low-density flame-retardant PP foam products, systemic study on the foaming condition on cell morphology need be conducted.
Development Of Polypropylene Nanocomposites Reinforced With Cellulose Filaments
Julie GENOYER, March 2019
In this work, polypropylene (PP) reinforced with cellulose filaments (CF) nanocomposites were studied. Nanocomposites with CF loadings ranging from 0 to 30 wt% were produced by melt extrusion and characterized. Rheology using Carreau-Yasuda with yield stress model was used to estimate the dispersion state of CFs and showed that a suitable dispersion was achieved. Tensile tests were conducted to study the mechanical behavior of the materials. Results showed that nanocomposites with a higher rigidity can be obtained when a suitable dispersion is achieved, however, those nanocomposites are consequently more brittle.
Influence Of Injection Molding Parameters And Fiber Content On Product Roundness Accuracy
Pi-Lin Tsai, March 2019
In recent years, injection molding has become a common polymer molding process in the plastics industry. Injection molding can produce products which have complicated shapes, and offers high efficiency and productivity with low cost. However, uneven volume shrinkage during the injection molding process will cause deformation after demolding and poor product roundness. To find the best approach, this study focused on round products under different molding conditions, including melt temperature, mold temperature, and injection speed. CAE simulation was used to identify the effect of different fiber content and molding conditions on product roundness. Results showed that the roundness of PC material products without fibers was better than those with fibers. Moreover, those which contained more fibers exhibited lower dimensional stability. The uneven shrinkage and variations in roundness were caused by the different fiber orientations in the product. Changing the position of the gate improved the uneven shrinkage caused by fiber orientation. Furthermore, raising the mold temperature also improved the roundness of the product.
The Influence Of Fiber Length And Fiber Orientation On The Impact Behaviour Of Polypropylene
Maiko Ersch, March 2019
Discontinuous fiber reinforced thermoplastics materials combine the process related advantages of injection molding with the enhanced mechanical properties of fiber-reinforced plastics. Since the mechanical properties of FRPs are dependent on the fiber length, long fiber reinforced thermoplastics (LFT) offer a huge potential for lightweight design. In order to analyze the influence of the fiber length and orientation on the stiffness and strength of LFT under high strain rate loading, the authors conducted tensile impact tests as well as part impact tests. Thereby, polypropylene (PP) specimens with different fiber length were analyzed. It can be shown that the influence of the fiber length on the strain rate behavior can be neglected compared to the influence of the fiber orientation. Furthermore, a first implementation to describe the strain rate-dependent material behavior of LFT is presented.
Influence Of Additive Type And Mixing Protocol On The Properties Of Ldpe-Pa6-Blends
Christoph Burgstaller, March 2019
The aim of this work was to compare the effects of compatibilisation with a pre-fabricated additive and the in-situ generation of a similar additive in the melt for LDPE-PA6-blends and to investigate the effect of mixing protocol (i.e. compounding vs. dry-blending) of the prefabricated additive on the resulting properties of reprocessed LDPE-PA6 films. We found, that it is possible to compatibilize LDPEPA6-blends via the addition of maleic anhydride based compatibilizers, regardless of fabrication approach. This effect can be seen from the morphology of the samples as well as from mechanical properties. Also, the reprocessing of films from LDPE and PA6 with reasonable properties is possible when adding a compatibilizer. The best, i.e. the most balanced properties can be found when the compatibilizer is melt compounded, as this gives the best distribution. These results show that it is possible to reuse multilayer materials when considering the blend components and properly selecting a compatibilizer.
Modelling Of The Mechanical Properties Of Medium Saturated Short Fiber-Reinforced Polycarbonate
Simon Koch, March 2019
There is an often ignored correlation between mechanical and chemical stress in plastics parts, which is very time- and cost-intensive to test. The model that was developed in this research allows the prediction of the mechanical properties of fiber-reinforced amorphous thermoplastics under media influence. The media influence is taken into account by the modulus of elasticity of the matrix, which is determined by a molecular dynamics simulation. The results correspond well with the tests for polycarbonate after storage in distilled water. An acoustic emission analysis shows an influence of the medium on the damage behavior of the fiber-reinforced samples during the test. The media storage results in significantly more acoustic emissions during the test. This indicates damage already during the test and not just shortly before the break.
Using Secondary Air Cooling In Blown Film Extrusion: Concept Design And Experimental Study
Christoph Dohm, March 2019
The characteristics and the quality of a blown film are strongly influenced by the stretching and simultaneous cooling of the molten polymer within the bubble formation zone. Moreover, the output rate of the process is generally limited by the cooling rates and the stability of the bubble. As a consequence, the design of cooling systems is highly relevant in terms of process optimization. Beside intensifying the heat removal, the concept of secondary air cooling aims at eliminating unsteady ambient influences during bubble formation and increasing bubble stability. Different concepts for cooling systems with integrated secondary air cooling are presented and experimentally tested. The results confirm that the implementation of secondary air cooling is feasible and generally supports bubble cooling regarding the aforementioned intention. Furthermore, the study reveals that an accurate design of such cooling systems is required.


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