SPE Library

The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.

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Conference Proceedings
High Molecular Weight Flexibilizers in Low Smoke Flame Retardant PVC Compounds
E.R. Griffin, May 2000
Ethylene copolymer resin (ECR) modifiers play an important role in low smoke PVC. As high molecular weight flexibilizers these resins reduce smoke and add strength and low temperature flexibility. This combination allows compounders to increase the flame-retardant additives without compromising strength or flexibility or by adding liquids which increase smoke. This paper is presented to demonstrate these attributes versus liquid plasticizers used in PVC compounds.
Microstructure and Electrical Conductivity of BR/EPDM/Carbon Black Blends
Rigoberto Ibarra-Gómez, Oliverio S. Rodríguez-Fernández, Luis Francisco Ramos-Devalle, May 2000
Important appliances have arised from the study of polymer composites containing conductive particles (e.g., EMI shielding, antistatics, wire coatings for overcurrent prevention). The present work is concerned with dynamic properties related to the microstructural arrangements, as observed by Transmission Electron Microscopy (TEM), in an elastomeric blend system consisting of Polybutadiene (BR), EPDM and Carbon Black (CB). Based on changes in the viscous component signals of BR and from micrographs of samples stained with osmium tetroxide it was found that the CB was located mainly in the BR phase. Final behavior of the conductivity was found to have great dependece on this fact.
Influence of Various Molding Conditions on the Uni-, Bi-, and Tri-Axial Impact Properties of Polyvinyl Chloride (PVC)
Rabeh H. Elleithy, Amjad Abu-Ali, E. Ray Harrell, Jr., Jim Summers, May 2000
This study discusses the influence of molecular weight, melt temperature, mold temperature, and aging on the impact characteristics of molded PVC. Tensile impact (uni-axial), instrumented drop-dart impact (bi-axial), and Izod impact (tri-axial) methods were utilized to assess the impact properties of the material under investigation. It was found that the impact properties were affected by aging more than by the changes in the melt temperature or the mold temperature. Additionally, the molecular weight played a significant role in influencing the impact properties of PVC.
Incidence of Crosslinking Comonomer Composition in the Mechanical Properties of a Multilayer Reinforced Unsaturated Polyester Resin
C.F.Jasso, F. Arreola, A.B. Valenzuela, U. Nahuatlato, I. Neri, R.J. Sanjuan, M.E. Hernández, May 2000
In this work an improvement in mechanical perfomance of a general purpose reinforced unsaturated polyester resin, is attempted by using two different types of crosslinking systems to make composite materials by compression molding. Three resin layers separated by two glass fiber mat pieces conform the composites to be tested. Styrene, divinyl benzene and butyl acrylate in different proportions were used to crosslink the resin. Important variations in two formulation composition zones were found for tensile strength, impact resistence and dynamic properties. A formulation may be chosen to achieve enhanced performance in particular properties.
Rapid Tooling: The Rapid-to-Market Advantage
Mel J. Janaes, James E. Folkestad, May 2000
Industrial Technology is a field of study designed to prepare technical and/or management oriented professionals for employment in business, industry, education, and government. As a young industrial technologist it is my responsibility to understand both the technical aspects of world class equipment and more importantly, strategic application of these technologies for maximum corporate impact. Rapid prototyping and rapid tooling are technologies that if coupled with appropriate management strategies should allow companies to get their products to the market faster. This paper presents how a team of graduate students is using rapid prototyping and rapid tooling to reduce product changes and associated costs and accelerate product development.
COF of LLDPE Films as a Function of Erucamide Surface Concentration
María X. Ramírez, Douglas E. Hirt, Bill Roberts, Marv Havens, Nate Miranda, May 2000
The surface of a polymer film can be modified by allowing additives within the film to diffuse to the surface and accumulate there. Some of the most commonly used surface-property modifiers are slip, antifogging and antistatic agents. Erucamide is a slip agent widely used to reduce coefficient of friction (COF) of polymer films. This research focused on quantifying the relationship between erucamide surface concentration and COF of LLDPE films. The surface concentration was measured using surface washing, and results showed that there were significant COF changes in the surface-concentration range of 0 to 0.5 ?g/cm2.
Comparison of Techniques to Measure Additive Diffusivity in Polymer Films
John P. McKibbin, Shilpa Y. Sankhe, Keisha A. Bishop, Douglas E. Hirt, May 2000
The surfaces of a polymer film can be modified by allowing additives within the film to diffuse to the surfaces and accumulate there. To model the diffusion/accumulation process, it is necessary to accurately measure the diffusion coefficient of the additive in the polymer. We have attempted to characterize the diffusivity of erucamide in LLDPE through several means: mass sorption (diffusion in") and surface washing and ATR-FTIR ("diffusion out"). Experiments demonstrate that surface washing can provide inconsistent results. Mass sorption and ATR-FTIR provide comparable results although emphasis is placed on the ATR-FTIR technique because the migration process more closely mimics the behavior of commercial films."
Study of Polypropylene Degradation in a Co-Rotating Twin Screw Extruder
Eric Tizon, David Bigio, Leo Kasehagen, May 2000
Screw design, injection site and operating conditions are critical parameters which influence peroxide injection efficiency during PP vis-breaking. A visual study in a clear barrel extruder was performed with water and corn-syrup to simulate the mixing of a low viscosity ratio system. Liquid injection of peroxide into PP was then performed in a 30 mm COTSE and compared to the normal pre-mixed peroxide method. Operating conditions were found to greatly influence degradation by shear and injection efficiency.
Evolution of the Anisotropic Structure of Poly(phenylene vinylene) Films with Stretching
Runqing Ou, Robert Samuels, Xingwu Wang, Richard Gregory, May 2000
The evolution of the anisotropic structure of PPV films with stretching was studied by three characterization techniques: three dimensional refractive indices using waveguide, infrared dichroism and flatplate x-ray photography. The results show that the cast PPV film without stretching has a highly planar structure. One way stretching converts the film to a uniaxial structure.
Extrusion Blow Molding Process-Development and Optimization
Karel Kouba, Petr Novotny, Peter Gust, May 2000
This paper presents the application of CAE tools for a Blow Molding process. A description of the underlying theory is provided. The predicted thickness distribution for an example part is shown to have a good correlation with experimental measurements. The approach to parison thickness optimization is also demonstrated.
Stress-Induced Crystallization
K.P. Palluch, A.I. Isayev, May 2000
The stress development during polymer processing of semi-crystalline polymers can cause stress-induced crystallization and changes in the crystallization kinetics. The integration of orientation entropy changes calculated by non-linear viscoelastic constitutive equations in crystallization thermodynamics gives us a proper physical model to describe the crystallization behavior in oriented polymer melts. Based on the model a new economic characterization procedure for stress-induced crystallization is put into application. The new model is used to simulate the stress-induced crystallization during the injection molding of isotactic polypropylenes. The results are compared with experimental data.
Interfacial Adhesion in Thermoplastic/LCP Blends
A.I. Isayev, N. Shah, May 2000
Knowledge about interfacial adhesion in thermoplastic/LCP blends is important for manufacturing self-reinforced composites with improved performance. Thus, in the present study, interfacial shear strength between different LCPs and thermoplastics was measured by using fiber pullout method. The LCPs employed were Vectra A - 950, Vectra B - 900, Ultrax KR - 4002 and Ultrax KR - 4003. The thermoplastics included were high density polyethylene, polypropylene, polycarbonate, polyphenylene oxide/polystyrene alloy, polybutylene terephthalate, polyethylene terephthalate, polyethylene naphthalate, polyetherimide and copolyester. Based on these measurements, the similarities and differences in interfacial behavior of various pairs have been found. In addition, ranking of various pairs of thermoplastic/LCP blends has been made concerning their interfacial shear strengths.
Rheology of Highly Interactive Polymer-Filler Mixtures
G. Havet, A.I. Isayev, May 2000
The dynamic properties of polystyrene (PS)/silica mixtures of various concentrations were investigated as a function of frequency and strain along with the flow curves. An abrupt change in the viscoelastic properties is noticed above 1% volume concentration. Observations by means of scanning electron microscopy (SEM) indicate the creation of a 3D network through bridging of filler particles by adsorbed polymer. The rheological behavior is simulated utilizing a double network created by the entangled polymer matrix and the adsorbed polymer. Both networks are represented by a Giesekus viscoelastic constitutive equation. The dependence of rheological properties on filler concentration is taken into account through the density of polymer-filler interactions and a hydrodynamic reinforcement. The relative contribution of both networks is computed through the energy balance consistent with the thermodynamics of the chemical interactions and fluid mechanics. This self-consistent approach allows one to predict the major features of the rheological behavior of such systems.
Differential Scanning Calorimeters with Increased Sensitivity and Resolution
Vijay N. Reddy, Randy Byrne, Nobutaka Nakamura, Osamu Sakamoto, May 2000
Resolution and sensitivity are two of the most important properties of thermal analyzers. Resolution can be described as the ability to separate and observe two events, which occur close to one another and sensitivity is the ability to detect very small effects. The ability to significantly shorten the overall experimental time and increase throughput, yet obtain data with improved resolution and greater sensitivity are highly desirable. In many labs involving thermal analysis of polymers, today's instruments provide a similar choice. In this paper, improved sensor design and firmware in Differential Scanning Calorimeters (DSC) will be discussed using few application examples.
Linearity and Non-Linearity of Mechanical Properties in Blends of Virgin and Recycled HDPE's
Paul Miller, Edward Kosior, Syed Masood, Pio Iovenitti, May 2000
This paper investigates the behaviour of blends of Recycled Milk Bottle Resin (R-MBR) with Injection Moulding or Film Blowing grade HDPEs (IM-HDPE or FB-HDPE). This was done by measuring changes in mechanical and rheological properties as a function of blend composition and compounding intensity. There were three categories of compounding: bag mixing (BM), single pass single screw extrusion (EBx1) and double pass single screw extrusion (EBx2). The results were examined for linear and non-linear trends, and relationships between morphology, mechanical properties and molecular weights were proposed.
Specific Features of Dynamic Vulcanization and Properties of Thermoplastic Elastomers
Eduard V. Prut, Natalia A. Yerina, May 2000
The macrokinetic of dynamic vulcanizetion was studied. Criteria for selection a cross-linked system and condition for conduction one-step dynamic vulcanizetion were suggested. The influence of the ratio of the basic components, the content of plasticizer and mineral filler on mechanical and processing properties of thermoplastic vulcanizates (TPV) was investigated. The ageing of TPV was connected with recrystallization of polypropylene (PP). The mechanism of TPV's deformation is proposed.
Practitioner Training Program for Troubleshooting Injection Molded Part Defects
Amy Schickline, Jennifer Schmidt, May 2000
The objective of this paper is to document our study of injection molded part defects. The study of the defects is necessary in developing a training program for technicians and engineers. With this program one will be able to understand the causes of the defect and the steps required to eliminate it.
Blend of Post Industrial ABS and PMMA Improves Thermal and Impact Properties
Michelle J. Mikulec, Tony Brooks, May 2000
The recycling of post industrial ABS and PMMA was investigated. A material compound consisting of 100% post industrial (PI) recycled ABS and multicolored acrylic (PMMA) scrap from a manufacturing plants was blended and extruded. Test samples were injection molded and the test results were correlated to virgin material. Additionally, the material was used in injection molding of rear lamp housings in black and gray colors. The test results and economics are promising.
Resistance of Glass Fiber-Reinforced Thermoplastics to Water Hammer
Takafumi Kawaguchi, Hiroyuki Nishimura, Fumiaki Miwa, Kazunori Ito, Takashi Kuriyama, Ikuo Narisawa, May 2000
The resistances of three kinds of short glass fiber or glass bead-reinforced plastics [polyphenyleneether (GFPPE), polyphenylenesulfide (GFPPS), and polyoxymethylene (GBPOM)] to water hammer were studied. The fracture surfaces and the cross sections of the fracture surfaces were observed to investigate the fracture mechanism. PPE showed poor resistance to water hammer compared to PPS and POM. Investigation of the fracture surfaces showed that their surfaces were rather flat and hardly any glass fibers were observed at the fracture surfaces. It was found that the characteristic fracture surfaces was attributable to the breaking of the glass fibers at the fracture surface which is hardly observed in other modes of fracture such as tensile fracture.
Advances in Fusible Core Technique
E. Schmachtenberg, O. Schröder, May 2000
Fusible core technology allows the production of injection molded parts which cannot be manufactured by conventional mold technology because of undercuts and internal geometries. The production sequence consists of several process steps. The reliability and economy of the process depend on each process operation as well as on the correct design of the interfaces between the steps. This paper presents sample applications, production methods and potentials for future applications. Moreover, current R+D work is described which mainly focuses on improved process engineering, a better understanding of the boundary conditions of product design and a wider range of applicable polymers.

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