SPE Library
The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
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Conference Proceedings
High Temperature Air Channel Testing of Thermally Bonded PVC Geomembrane Seams
Timothy D. Stark, Luis F. Pazmino, May 2015
ABSTRACT: The objective of this paper is to present a procedure for high sheet temperature air channel testing of dual track thermal seams for 0.75 mm thick PVC geomembranes. This objective is accomplished by developing relationships between seam peel strength and seam burst pressure for sheet temperatures ranging from 46.7øC to 62.8øC during field air channel testing. This paper extends the original relationships presented by Thomas et al. (2003a) and Stark et al. (2004) that only extend to 46.7øC because a sheet temperature greater than 46.7øC is frequently encountered during hot summer months. The original relationship is extended to 62.8øC using the Arrhenius model and a polynomial equation is presented that can be used to convert the sheet temperature during field air channel testing to the air channel pressure required to ensure the specified seam peel strength of 2.6 N/mm (15 lb/in) is met or exceeded. Thus, the proposed relationship and equation allow the seam peel strength to be verified by field air channel testing without conducting destructive tests.
Thirty-Year Durability of a 20-Mil PVC Geomembrane
Timothy D. Stark, E. J. Newman, May 2015
In 1971, twenty circular aquaculture ponds were constructed for the W. K. Kellogg
Biological Research Station in Hickory Corners, Michigan. The 30.5-m-diameter research ponds were lined using a 0.51-mm-thick fish-grade PVC geomembrane. Over the years the ponds became congested with dense, persistent stands of cattails, trees, and other vegetation, which required the ponds to be cleared and relined in September 2000 in order to allow the initiation of new experiments. The lack of holes in the exhumed geomembrane suggests that it resisted biological attack from microorganisms and also root penetration. Laboratory testing shows that the tensile behavior of the nearly 30-year-old PVC geomembrane is within current specifications for new 0.51-mm-thick PVC geomembranes. Test results also indicate that performing laboratory tests at in-situ moisture conditions provides a better estimate of the field properties of PVC geomembranes than desiccating the material prior to testing, as is required by ASTM Standard Test Methods.
Curing Kinetic and Viscosity Behavior of Liquid Silicone Rubber for Reaction Injection Molding Analysis
Donghan Kim, Byung-Ohk Rhee, Eun su Han, Mansik Jo, Jun-Hyung Kwon, Jeong-Hyun Lee, Bon-Heung Koo, May 2015
Computer-Aided Engineering (CAE) analysis for the Reaction Injection Molding (RIM) process is very useful to predict problems in design process. For the accurate prediction, the curing reaction of the materials during the process has to be estimated accurately. However, the curing reaction of the LSR is very difficult and restrictive to measure because it is a highly complicated behavior. Accordingly, it is desirable to analyze the curing reaction with finding interrelated components among various measurement methods. Isothermal and non-isothermal tests were carried out to study the curing kinetics behavior using Differential Scanning Calorimetry (DSC). The viscosity measurements were also carried out to study the viscosity behavior using rotational rheometer.
A New CMR-Free Polyamide Imide Resin
Limor Ben Asher, May 2015
Abstract
Polyamide imide [PAI] resin polymers are well-known thermally stable polymers that are used for many high performance coating applications due to their excellent adhesion, temperature resistance, and high strength.
For the various coating uses, PAI resins are used in solvent-based formulations. However, ever-evolving regulations dictate the need to find a solution and replace the traditionally used n-methyl- and ethyl-pyrrolidone [NMP/NEP] solvents. NMP is the most-commonly used solvent in a variety of coating applications. In the 1980?s and 1990?s NMP was used to produce ?environmentally friendly? coatings, replacing cresol as the predominant solvent at that time. Now NMP and NEP have been classified as reprotoxic chemicals, based on the EU REACH regulations and, once again, PAI users face a similar threat which will close entire segments in Europe unless an alternative solvent can be found.
As a key sustainability initiative, Fujifilm Hunt has successfully developed a proprietary alternative solvent solution to the REACH-classified CMR (carcinogenic, mutagenic, reprotoxic) chemicals currently available for PAI coating applications.
Epoxy Silicate Composite Dielectric Characterization by TSDC Techniques
Andres Garcia, Michael Stoddard, Nathan Warner, Nandika Anne D?Souza, Enis Tuncer, May 2015
Understanding the magnitude and mechanisms of charge release associated with the dielectric properties of materials has implications on the reliability assessment of microelectronics. Insulators protect devices from conductive currents. However, due to dipole-charge and interface trapping, a release current typically appears around the glass transition. The effect of fillers on the charge release is a critical parameter in investigating the reliability of dielectrics. In this paper, thermally stimulated depolarization current (TSDC) was done to analyze the prediction of material behavior. Parallel thermal measurements were done using DSC to analyze the uncharged material relaxations.
Prediction of Short-Term Behavior of Polyamide 6 by Using the Strain Energy Density Theory
Mohamed Hadid, Abderrazak Debilou, May 2015
The Strain Energy Density Theory represents a useful tool for the prediction of the short term viscoelastic behavior of materials. The key in this m is the strain energy density ?SED? of the material. Indeed, by conducting two strain-ramped experiments with different strain rates, it can be established a law that links each point on one curve, to another point on the second curve, provided that the two linked points have the same SED. Once the law parameter is obtained, and by using of a known stress-strain curve, one can predict the stress-strain curve for any other strain rate. This work assesses this technique on a technical thermoplastic which is the polyamide 6. To ensure more accuracy, the test strain is recorded using a non-contacting video extensometer. The processing of the experimental data have allowed to identify; firstly a law that connects the strain to the SED, secondly, a law that links the parameter of the law to the SED.
Enhanced Graphene Exfoliation and Dispersion in Injection Molded Polypropylene Nanocomposites Processed with Supercritical Fluid
Thomas K. Ellingham, Jun Peng, Hrishikesh A. Kharbas, Jason D. McNulty, Lih-Sheng Turng, May 2015
The effects of melt processing nanocomposites of graphene and polypropylene (PP) with supercritical fluid (SCF) were investigated. Blends of 0.5% graphene (by wt.) were mixed via traditional twin-screw extrusion and with supercritical-fluid gas-laden pellets injection molding-foaming technology (SIFT). Tensile bars were formed using traditional injection molding (IM) and microcellular injection molding (MIM). Samples with graphene had lower melt viscosity and higher thermal stability than their neat PP counter?parts. MIM and SIFT samples with graphene had increased tensile strength. Property enhancements were greater where SCF was used (MIM and SIFT). The ability of SCF to increase exfoliation and dispersion of graphene was determined by X-ray diffraction and Raman spectroscopy. Better exfoliation and dispersion of the nanofillers resulted in the observed property enhance?ments.
Functional Additives for Polymers -- Porcessing Aids, Light Weighting and Thermally Conductive Fillers
Steve E. Amos, Baris Yalcin, May 2015
The Advanced Material Division of 3M Company provides several additive classes for polymers used in various applications. 3M? Glass Bubbles can provide light weighting for polymers with and without reinforcing and other fillers. Up to 10% weight reduction can be achieved while maintaining physical properties. Weight reduction potential can be maximized when combined with MuCell? technology. 3M? Cooling Fillers can be used to provide high through plane thermal conductivity with high electrical resitivity. Polymer Processing Additives can be used to speed extrusion and prevent die lip build-up during masterbatch compounding or profile extrusion such as door ding strips, mud flaps and door seals.
Preparation and Characterization of Cellulose Nanofiber Reinforced Poly (Butylene Succinate) Nanocomposites
Jithin Joy, Cintil Jose, Sohil Shah, Lovely Mathew, Sabu Thomas, Srikanth Pilla, May 2015
Biodegradable nanocomposites were prepared from poly(butylene succinate) (PBS) and isora nanofiber (INF), a cellulosic nanofiber extracted from Helicteres isora. The nanocomposites were processed using a brabender twin-screw compounder and an injection-molding machine. The effects of INF on the mechanical (tensile and flexural), viscoelastic and thermal properties of the nanocomposites were investigated. The tensile and flexural moduli of PBS-INF nanocomposites increased with INF content, whereas the toughness and strain-at-break decreased. The tensile and flexural strengths increased up to 1.5phr INF loading beyond which they declined owing to agglomeration of INF. The storage modulus of the nanocomposites increased with the INF content. The addition of INF did not affect the Tg significantly. The area integration under tan ë curve decreased with INF loading indicating that PBS-INF nanocomposites exhibited more elastic behaviour with increasing INF. The addition of INF did not alter the thermal stability of PBS, significantly.
Mechanical and Morphological Properties of Microcellular Polypropylene Single-Polymer-Composites Prepared by Microcellular Injection Molding
Dongjie Chen, Jian Wang, Lu Yang, Sui Wang, May 2015
Recyclable microcellular polypropylene (PP) single-polymer composites (SPCs) with uniaxial fibers were successfully produced by microcellular injection-molding process. Nitrogen in the supercritical state was used as the physical blowing agent in the microcellular injection molding experiments. The tensile properties of the microcellular PP SPCs with uniaxial fibers were determined. The microcellular PP SPC prepared with an injection pressure of 40 MPa, a nozzle temperature of 205 øC, a holding time of 5 sec and a cooling time of 20 sec has the tensile strength of 23.70 MPa, 24.34% higher than that of the microcellular non-reinforced PP, 7.93 % lower than that of the solid PP. The weight of the microcellular PP SPC is 1.024 g, 11.50% lower than that of the solid PP, 2.09% higher than that of the microcellular non-reinforced PP. The morphological properties were also observed using scanning electron microscope (SEM).
Modeling and Simulation of Internal Circulation Two-Platen Injection Molding Machine Based on AMESim
Lu Yang, Jiong Peng, Dongjie Chen, Jian Wang, May 2015
The internal circulation direct hydraulic two-platen clamping system opened a new era of the development of the injection molding machine. This paper established the hydraulic system models for the internal circulation clamping system by AMESim. Displacement of the moving platen, pressure in the mold-clamping cylinders and flow in the internal circulation valves were calculated. The simulation results showed that the system design was reasonable and reflected the real dynamic characteristics of hydraulic system. The modeling and simulation for the internal circulation two-platen injection molding machine laid the foundation for further studies.
A Study of Two Processing Induced Part Failures
Jose M. Perez, May 2015
Of the four pillars required for the successful development of a plastic part; material selection, part design, processing, and service environment, processing is often assumed to be the most controllable. Even when the service environment has been properly defined, the best design principles implemented, and the appropriate material selected, seemingly insignificant changes in processing can grossly and adversely affect an otherwise well developed product. This paper will explore two case studies where the failure of the parts can be traced directly back to changes in the processing parameters and how these changes ultimately predisposed them to premature failure.
Foamcore Blow Molded Structural Components for Transportation Applications
Steven R. Sopher, May 2015
With emphasis on weight reduction throughout the transportation industry, there is a renewed effort to remove as much mass as possible to improve vehicle performance.
JSP has developed and optimized a blow molding process that combines traditional blow molding with an injection molded particle foam core. This process; called Foamcore, utilizes traditional blow molding equipment combined with a particle foam injection unit to produce a composite blow molded part with a solid foam core.
JSP?s Foamcore technology allows for simpler designs, higher strength to weight ratios, lower part weight, all while using exiting tooling (with minor modifications). Multiple polymers can also be used including Polypropylene, Polyethylene, Polystyrene, etc. for both skin and core materials.
This paper will describe recent advancements of this technology, and how they allow for improved mechanical properties to be realized in the area of transportation applications for structural and semi-structural components. Other features discussed include improvements in thermal insulation, sound abatement, as well as recyclability and End-Of-Life requirements.
Developments in the Production of High Surface Area Fibers and Nonwovens for Filtration
Behnam Pourdeyhimi, May 2015
Sub-micron fibers are expected to bring value to applications where properties such as sound and temperature insulation, fluid holding capacity, softness, barrier property enhancement, high electrochemical activities (electrodes in fuel cells and Li-ion batteries) and filtration performance are needed. This presentation will focus on the various processes used for forming webs made up of sub-micron fibers and will review the latest technologies in Electrospinning, Meltblowing, Melt Fracture, Solution blowing, Bicomponent fiber formation, and Supersoninc nozzles.
Catalytic Technology and Controlled Chemical Release for Post-Harvest Preservation of Fruits and Vegetables
Vinod Malshe, Rajen Raje, Leena Raje, Rupali Hande, May 2015
Roughly 1/3rd (1.3 billion tonnes) of the food produced in the world for human consumption gets wasted every year. Fruits and vegetables have highest wastage rates of almost 40-50%. This is partly due to ethylene action and improper storage and handling. Ethylene, a catalyst generated by climacteric fresh produce is responsible for their ripening. Ripened fruits have more risk of microbial spoilage due to increased sugar %. Improper handling, storage, lack of cold chain etc in post-harvest conditions further increases the loss. In the past, we have reported ?niche? technologies for fruit preservation, such as chemical agents responsible for adsorption and destruction of ethylene. In continuation, now we are introducing some more ?unique? technologies such as using a) Catalytic converters (of ethylene to ethylene oxide), b) Ethylene adsorbers and c) Halogen releasers. We believe that these simple and cost-effective techniques will be the trendsetters to reduce horticultural wastage considerably and in the end benefit the farmer, the retailer and also the consumer. Efficacy of these products was tested by using them as novel additives in flexible packaging, punnets etc. which are commercially used for storage and transport of various fruits and vegetables in which they were effective in reducing ethylene from the storage area. We also experimented use of these products by incorporating them in a plastic film and all through we could acquire considerable shelf life extension of both climacteric and non-climacteric fruits and vegetables. We firmly believe by using such value-added packaging post harvest horticultural losses will be considerably reduced and it can result in a service to mankind.
Extrusion Performance Fluids - Crucial in Maintaining Water-Cooled Extruder Efficiencies
Peter E. Greenlimb, May 2015
Many manufacturers of water-cooled extrusion equipment typically recommend that either distilled water or properly-treated water [1,2] be used to control barrel zone heater/cooler temperatures. While many industrial water treatment professionals treat and maintain cooling towers, chill rolls and other Utility Water Systems in extrusion plants, few, if any, have attempted to solve the corrosion, fouling and mineral deposition issues typically experienced in extruder barrel cooling systems (Process Water Systems).
This paper summarizes our experiences over the past fourteen years developing and successfully applying Extrusion Performance Fluids (EPF) as safe and effective coolants in water-cooled extrusion applications. Key documented case studies and simple extrusion maintenance procedures will be discussed which form the basis for a pending US Patent [3] on EPF and its associated technologies.
Long Chain Branching of Polypropylene via UV Radiation: Effect of Coagent and Other Radiation Variables on Continuous Modification
Yasaman Amintowlieh, Costas Tzoganakis, Alexander Penlidis, May 2015
Continuous photomodification of polypropylene (PP) has been conducted in order to scale up a previously developed batch process for commercialization purposes. Utilizing this process PP rheological properties were modified by incorporation of long chain branches (LCBs).
Trimethylolpropane triacrylate (TMPTA) was employed as a coagent along with benzophenone (BPH), which was the photoinitiator. The effects of TMPTA presence, BPH concentration, and radiation duration on viscoelastic properties and gel content were studied. Gel permeation chromatography (GPC) was used to confirm formation of LCBs in the photomodified PP.
A Study of Glass Spheres Incorporated into Extruded Polyethylene Films
Nicholas Iorio, Christopher Thellen, Sarah L. Cheney, Lauri Kline, David Graham, Jo Ann Ratto Ross, May 2015
Hollow glass microspheres were investigated as an additive in extruded low density polyethylene films. Advantages of this technology may include reductions in plastic material costs, thermal conductivity, packaging weight, density and processing costs. Monolayer films were processed on a blown film extrusion line and characterized for morphology, thermal and mechanical properties. Optical microscopy showed that the microspheres were intact and density was lower than the neat low density polyethylene films.
Marketing and Product Development Strategies in the Chemical Industry Using Dark Data & Data Sciences
Bala Ambravan, Gunaranjan Pemmaraju, May 2015
The GDP contribution from the Industrial sectors is ~$25T, of which the Chemicals and Plastics Industry, is ~$4T in revenues. This traditionally product-centric industry is transforming into a market-facing growthmachine. While chemistry and product innovation will always be pillars of the industry's strength, prioritizationof the development efforts are shifting heavily towards marketing strategies and identification of attractive segments. However, Marketing and Segmentation strategies at chemical companies currently rely on the useof traditional methods such as expertise, relationships, customer feedback, sales calls, static market reports, strategy consultants and patent searches. On the other hand, the use of data, advanced data sciences andautomated intelligence is prevalent in the consumermarketingworld. This paper intends to open up and inspire possibilities in fully utilizing these advances in data sciences from the consumer space, and applying themto the industrial space, in tandem with the extraction of relevant dark data. Deep industry expertise can beaugmented by data sciences & big data analytics, mobile and social platforms and technology, to form a potent mix, which will catalyze this transformation.
Material Selection For Cost Effective Manufacturing: A Methodology for Technical Evaluation
Eric R. Larson, May 2014
This paper presents a methodology for the selection of thermoplastic materials in order to achieve the most cost effective manufacturing solution. Unlike conventional materials selection methods—which rely almost exclusively on quantitative performance data—this method relies on a comprehensive evaluation of cost, including material costs, processing costs, and the cost of secondary operations.
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