SPE Library
The SPE Library contains thousands of papers, presentations, journal briefs and recorded webinars from the best minds in the Plastics Industry. Spanning almost two decades, this collection of published research and development work in polymer science and plastics technology is a wealth of knowledge and information for anyone involved in plastics.
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Conference Proceedings
STUDY INTO THE DENSIFICATION BEHAVIOUR OF POLYETHYLENES FOR ROTATIONAL MOULDING
The melting and densification behaviour of a range of Polyethylenes (PEs) produced from 2 different catalysts, Ziegler-Natta and Metallocene types, were investigated using a novel visual data acquisition and analysis system (TP Picture??), developed by Total Petrochemicals Research Feluy. Differences in the dissolution behaviour of the bubbles were observed and correlations with the material density, densification rate, bubble size/ distribution and MFI were determined.
UNDERSTANDING AND QUANTIFICATION OF DIE DROOL PHENOMENON
DURING POLYPROPYLENE EXTRUSION PROCESS
In this work die build-up phenomenon has been
investigated theoretically by using FEM analysis as well
as experimentally for polypropylene resins which are
commonly used in the biaxial oriented film production. It
has been demonstrated that the negative pressure at the
die exit region is correable with die drool phenomenon in
this case.
UNDERSTANDING AND QUANTIFICATION OF DIE DROOL PHENOMENON DURING POLYPROPYLENE EXTRUSION PROCESS
In this work, die build-up phenomenon has been investigated theoretically, by using FEM analysis, as well as experimentally for polypropylene resins which are commonly used in the biaxial oriented film production. It has been demonstrated that the negative pressure at the die exit region is correable with die drool phenomenon in this case.
FACTORS AFFECTING THE RAPID CRACK PROPAGATION PERFORMANCE OF POLYETHYLENE PIPES
Good resistance to Rapid Crack Propagation (RCP) is considered to be important in plastic pipe field performance. However, RCP is a very complex phenomenon that depends on a variety of factors including pipe geometry (diameter and wall thickness) and test conditions (temperature and pressure). We show the effects, from both theoretical and experimental aspects, of these and other variables on RCP performance and share our concerns about some of the current RCP (S4) test practices.
A STUDY OF CRYSTALLIZATION KINETICS OF POLY (3-HYDROXYBUTYRATE-CO-3-
HYDROXYVALERATE)/ZN-AL LAYERED DOUBLE HYDROXIDE (LDH) STEARATE NANOCOMPOSITES
Isothermal crystallization of poly (3-hydroxybutyrateco-
3-hydroxyvalerate) (PHBV)/ Zn-Al layered double
hydroxide (LDH) stearate nanocomposites was investigated
by means of differential scanning calorimetry (DSC). The
Avrami equation was derived and the parameters were
assessed for the nucleation and crystal growth mechanism of
PHBV and its nanocomposites. (Ref.8)
A STUDY OF CRYSTALLIZATION KINETICS OF POLY (3-HYDROXYBUTYRATE-CO-3-
HYDROXYVALERATE)/ZN-AL LAYERED DOUBLE HYDROXIDE (LDH) STEARATE NANOCOMPOSITES
Isothermal crystallization of poly (3-hydroxybutyrateco- 3-hydroxyvalerate) (PHBV)/ Zn-Al layered double hydroxide (LDH) stearate nanocomposites was investigated by means of differential scanning calorimetry (DSC). The Avrami equation was derived and the parameters were assessed for the nucleation and crystal growth mechanism of PHBV and its nanocomposites.
MORPHOLOGY AND PROPERTIES OF NANOCOMPOSITES BASED ON HDPE/HDPE-G-MA BLENDS
Nanocomposites formed from blends of HDPE and HDPE-g-MA and organoclay were melt processed and analyzed by WAXS and TEM coupled with particle analysis to explore the effect of HDPE-g-MA on extent of exfoliation and mechanical properties. As HDPE-g-MA content increases, the global average particle aspect ratio increases drastically, peaks, and slightly decreases. Relative modulus improves with increased levels of HDPE-g-MA, and then levels off.
MORPHOLOGY AND PROPERTIES OF NANOCOMPOSITES BASED ON HDPE/HDPE-G-MA BLENDS
Nanocomposites formed from blends of HDPE and
HDPE-g-MA and organoclay were melt processed and
analyzed by WAXS and TEM coupled with particle
analysis to explore the effect of HDPE-g-MA on extent of
exfoliation and mechanical properties. As HDPE-g-MA
content increases the global average particle aspect ratio
increases drastically peaks and slightly decreases.
Relative modulus improves with increased levels of
HDPE-g-MA and then levels off.
THE EFFECT OF SECOND SHOT MATERIAL ON WARPAGE OF MOLDED AND COATED LARGE TWO-COMPONENT
Two-component injection compression molding process is the most advanced technology to produce large optical polycarbonate glazing panels. The paper investigates the effects of molding conditions and second shot material on the warpage of finished (coated) parts through a molding trial DOE. The data and results can provide a guideline for a proper part and process design and materials selection to manufacture good quality 2two-component PC panels/glazing with minimum warpage.
PREPARATION OF REINFORCED POLYPROPYLENE COMPOSITE VIA SMART PELLET ADDITIVES
A commercially available inorganic fiber product Hyperform HPR-803 was introduced into films with both polypropylene (PP) and polysulfone (PSF). These fiber-filled multilayer products were then added to PP resins and injection molded. This methodology allowed for high glass transition temperature PSF to be injection molded at 175oC. The morphology behaviors of the composites were studied by scanning electron microscopy (SEM). Mechanical properties of the composites were investigated by performing tensile, flexural, and impact strength tests.
THE EFFECT OF INJECTION MOLDING PARAMETERS ON THE PROPERTIES OF CARBON NANOTUBES FILLED THERMOPLASTICS
The electrical and mechanical properties of Polycarbonate and Polybutylene Terephthalate carbon nanotubes (CNT) nanocomposites were studied with respect to injection molding processing parameters, by means of design of experiments (DOE). Results demonstrated that the injection molding parameters had a significant effect on the properties of polymer/CNT nanocomposites. While the melt temperature had the most significant effect on the resulting volume resistivity, combination of parameters affected the mechanical properties of each polymer/CNT nanocomposite.
ENGINEERING SOLID SOLUTION PHYSICAL PROPERTIES TO ENABLE PHARMACEUTICAL PRODUCTS
The use of a common solid solution intermediate to support multiple pharmaceutical product applications is demonstrated with particular emphasis on the physical particle attributes required for success.
Design of suspensions, tablets, and injection molded products from spray dried or extruded solid solutions is described together with illustrative preclinical pharmacokinetic profiles.
RHEOLOGICAL CHARACTERIZATION OF ETHYLENE VINYL ACETATE
The behavior of melt flow of Ethylene Vinyl Acetate was studied using a capillary rheometer. The true flow curves were obtained by applying the Bagley correction into the apparent flow curves. It was found that EVA follows the typical pseudoplastic behavior with power indices within the range of polyethyleneƒ??s power indices. Moreover, end pressure losses were estimated.
PROCESSING AND MECHANICAL PROPERTIES OF JUTE FABRIC REINFORCED SMC MOLDINGS
Recent earth environmental concern requires easy
recycle material system and the use of biodegradable
polymer and natural fiber is noticed in composite
materials. In this study jute cloth reinforced SMC was
fabricated. And the effect of water included in jute cloth
was investigated by bending impact and tensile testing.
As a result it was revealed that the dry processing was
very important to apply natural fiber for composite
materials.
Processing and Mechanical Properties of Jute Fabric Reinforced SMC Moldings
Recent earth environmental concern requires easy recycle material system, and the use of biodegradable polymer and natural fiber is noticed in composite materials. In this study, jute cloth reinforced SMC was fabricated. And the effect of water included in jute cloth was investigated by bending, impact and tensile testing. As a result, it was revealed that the dry processing was very important to apply natural fiber for composite materials.
RHEOLOGICAL BEHAVIOR OF SULFONATED POLYSTYRENE IONOMERS
The rheological behavior of the alkali metal salts of oligomeric (Mw = 4 kg/mol) sulfonated polystyrene ionomers (SPS) was characterized using dynamic and steady shear measurements. Sulfonation increased the melt viscosity of the PS, by as much as 4 orders of magnitude, and the zero shear viscosity scaled with the Coulombic strength of the cation Although Mw was below the entanglement molecular weight, the ionomer melts exhibited strong elastic behavior.
SINGLE-WALLED CARBON NANOTUBE DISPERSION WITH ELECTROSTATICALLY TETHERED NANOPLATELETS
We report an exceptionally effective method for physically pulling nanotube bundles apart by utilizing electrostatically tethered nanoplatelets to gather and concentrate sonication energy at the surface of nanotube aggregates. Following dispersion, the nanoplatelets can be separated from the nanotubes by tuning the ionic strength of the medium. This colloidal approach obviates the need to drastically modify nanotube surface chemistry to achieve full exfoliation, thereby preserving their intrinsic properties.
FILLING SIMULATION AND TEMPERATURE PREDICTION IN HOT RUNNER SYSTEMS
A simulation based on the Radial Functions Method was
implemented to estimate temperature and flow in hot
runner systems during the mold filling process of a discshaped
mold cavity. The simulation predicts temperature
developments inside the hot runner and its effects on the
temperature distribution inside the cavity. Filling cycles
were repeated until the system reached steady state
condition.
THE USE OF BETA NUCLEATION TO IMPROVE THE IMPACT STRENGTH
AND REDUCE THE WARPAGE OF POLYPROPYLENE CAPS & CLOSURES
We have developed a unique masterbatch that can
be used to produce polypropylene caps and closures
containing the beta crystalline phase of PP. These caps
exhibit dramatically improved impact strength without a
significant loss of other desirable physical properties.
Another benefit of beta-nucleated closures is improved
dimensional stability and reduced warpage. The
masterbatch can be added during molding of the closures
by blending pellets of the masterbatch with that of the PP
resin and no pre-compounding is required.
THE USE OF BETA NUCLEATION TO IMPROVE THE IMPACT STRENGTH AND REDUCE THE WARPAGE OF POLYPROPYLENE CAPS & CLOSURES
We have developed a unique masterbatch that can be used to produce polypropylene caps and closures containing the beta crystalline phase of PP. These caps exhibit dramatically improved impact strength without a significant loss of other desirable physical properties. Another benefit of beta-nucleated closures is improved dimensional stability and reduced warpage. The masterbatch can be added during molding of the closures by blending pellets of the masterbatch with that of the PP resin, and no pre-compounding is required.
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