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Recycling

Various topics related to sustainability in plastics, including bio-related, environmental issues, green, recycling, renewal, re-use and sustainability.
EFFECT OF EPOXIDIZED SOYBEAN OIL ON MECHANICAL PROPERTIES OF POLYLACTIC ACID BLENDS
Yong Qing, Fu Zhao, Chen Quan, Huan Zheng, Gui Wu, Zhang Zhen, Qu Jin Ping, May 2012

Epoxidized soybean oil (ESO), as a plasticizer, was melt blended with polylactic acid (PLA) in an internal mixer. The effects of ESO on the mechanical properties of the PLA/ESO blends were studied by means of the tensile, flexural, and impact tests. The elongation at break for the PLA/ESO blends was obviously improved with an increase in ESO loading, and was 16.8 times than that for pure PLA when the ESO loading was 5 wt %. Compared with pure PLA, the blends appeared lower tensile strength, tensile modulus, flexural strength, and flexural modulus. However, ESO improved impact strength for PLA matrix. Impact strength for the blends increased at first and then decreased as the ESO loading increased, which arrived a maximum of 2.9 times than that for pure PLA when the ESO loading was 10 wt %.

THEMOPLASTIC STARCH AND POLYETHYLENE BLEND FOR BLOW MOLDED BOTTLE
Gregory J. Anderson, May 2012

HDPE was blended with TPS and blow molded into bottles. The packaging related GHG emissions were reduced 80 percent. The method involved two extruders. The first converted the starch into TPS, while the second mixed the HDPE and TPS for a co-continuous morphology. Further dilution during the melt forming stage resulted in fine droplets of TPS dispersed throughout. The TPS was used in various layer combinations without sacrificing the appearance or performance of the bottles.

TRANSFER EFFICIENCY VERSUS COATING WASTE REDUCTION
Ken Eyestone, May 2012

This paper will discuss published transfer efficiency of a spray applicator versus the real transfer efficiency of the spray applicator. The testing protocols used to determine the published transfer efficiency of a spray applicator will be discussed in relation to actual use of the spray applicator in a manufacturing coating process. The most common sources of material waste and the methods to reduce them to acceptable levels will be used to guide the reader to maximize the real transfer efficiency of their spray application system.

EFFECT OF RECYCLE ON PROPERTIES SABIC
James DeRudder, Yuzhen Yang, Yuanqing He, Wei Zhao, Amanda Flores, May 2012

It is well known that there can be significant sacrifices in properties of recycle containing products. Properties such as color, impact, consistency, and long term aged properties, are commonly reduced in recycled products. We will discuss reasons for loss in properties; showing how these can be modeled with Monte Carlo simulations. Examples will be given to illustrate these property loss effects in polycarbonate, polyester, and in polymer blend products. It will be shown how recycle content products can be designed to have acceptable property profiles.

EFFECT OF THE MOLECULAR STRUCTURE OF PLASTICIZER ON THE MORPHOLOGY OF POLYMER BLENDS WITH THERMOPLASTIC STARCH
Ata Taghizadeh, Basil D. Favis, May 2012

In this study, two different plasticizers from the polyol family have been used in the preparation of thermoplastic starch. The effect of these plasticizers on the interfacial modification of thermoplastic starch/polyethylene mixtures has been examined. When a higher molecular weight plasticizer is used, a different emulsification behaviour is observed for compatibilized systems. The number average droplet size decreases much more effectively with compatibilizer content than the volume average diameter. This behaviour is attributed to the chemical structure of the plasticizer. The mechanical properties of these systems are also presented.

EFFECTS OF HYDROLYTIC DEGRADATION ON THE MECHANICAL PROPERTIES OF RENEWABLE BIOPLASTICS: POLY(TRIMETHYLENE MALONATE) AND POLY(TRIMETHYLENE ITACONATE)
Mathew D. Rowe, Ersan Eyiler, I-Wei Chu, Keisha B. Walters, May 2012

Hydrolytic degradation of two renewable copolymers, poly(trimethylene malonate) (PTM) and poly(trimethylene itaconate) (PTI), was performed in aqueous solutions adjusted to pH values ranging approximately from 5.5 to 11. The influence of the degradation on the elastic modulus of these bioplastics was examined by a new atomic force microscopy (AFM) mode. Elastic modulus was monitored as a function of degradation time (100 to 10000 min) in DI water to determine changes. After degradation for one week the elastic modulus of PTI has decreased by 71 %. PTM was found to be hygroscopic. Due to significant swelling and uneven surfaces—in both the dry and wet state—PTM samples could neither be easily imaged nor its nanomechanical properties evaluated by AFM.

EFFECTS OF MOLECULAR ORIENTATIONS AND RESIDUAL STRESSES ON THE ENVIRONMENTAL STRESS CRACKING STRESS CRACKING RESISTANCE OF POLYCARBONATE
Christian Hopmann, Markus Brinkmann, Nikolai Borchmann, Andre Potthoff, May 2012

Environmental stress cracking is the most common failure reason of plastic parts. The influence of the processing conditions has been investigated in a previous research project at IKV. Yet, it was not clear if these effects can be correlated with the molecular orientations or the residual stresses. Therefore the effects of molecular orientations and residual stresses on the ESC?resistance are analyzed. The results of these investigations are discussed in?depth.

ELONGATIONAL RHEOLOGY AND MECHANICAL PROPERTIES OF BIODEGRADABLE PLA/PBSA BLENDS
Hassan Eslami, Musa R. Kamal, May 2012

Blends of poly(lactic acid) (PLA) and poly[(butylene succinate)-co-adipate] (PBSA) were prepared using a twin screw extruder. The morphology of the blends was examined using scanning electron microscopy (SEM). Elongational flow properties of the blends and pure components were studied. A strong strain hardening behavior was observed for PLA/PBSA blends, in which PBSA forms the continuous phase (PBSA wt% ? 50). The results of tensile test showed that even for blends containing only 10wt% PBSA, elongation at break increased significantly. By the addition of PBSA to PLA, a transition from brittle behavior (observed for pure PLA) to ductile behavior was observed.

EMERGING FIBER LASER TECHNOLOGY FOR MARKING PLASTICS
Scott R. Sabreen, May 2012

Ytterbium Fiber Lasers are transforming laser marking of plastics. For the proper application, superior results can be achieved versus Nd:YAG and Vanadate marking lasers. However, fiber lasers are not direct replacements without thorough evaluation, and not all lasers are created equal. The metric for beam quality is M2. The smaller the M2 value, the better the beam quality, whereas M2 = 1 is the ideal laser beam. A laser with superior beam quality can be focused to a small spot size, which leads to a high energy density which is, for many applications, desirable or even required. Such is the case for many thermoplastics including POM Acetals such as Delrin. Fiber lasers are considerably less expensive to procure with zero consumables, only electricity. Further, these lasers are a “Greener” technology than YAG or Vanadate.

ENVIRONMENTAL AGING OF COATED FABRICS COMPOSITES
James M. Sloan, D. Flanagan, C. Pergantis, P. Touchet, H. Feuer, May 2012

The purpose of this work was to perform a comparative analysis of various candidate nitrile coated fabric materials supplied by potential vendors to be used as fuel storage tanks and compare the results to the currently fielded polyurethane storage tanks. Our strategy is to utilize advanced environmental ageing methods to simulate extended weathering conditions. Our results demonstrate that the nitrile coated fabrics performed well in our evaluation. Their breaking strengths are about equal to the currently fielded urethanes and they performed comparably when subjected to environmental ageing conditions.

ENVIRONMENTAL STRESS CRACKING OF A POLY(ACRYLONITRILE:BUTADIENE:STYRENE) CUP HOLDER
Christelle F. Poquette, Niles G. Stenmark, May 2012

Environmental stress cracking (ESC) resistance has become an essential industrial criterion for engineering thermoplastics, as ESC causes unexpected brittle fracture of ductile amorphous plastics. In the automotive industry, a variety of amorphous plastics are used, which need to be ESC resistant, as they come in contact with various fluids while subjected to mechanical stresses. PC-ABS materials offer a good compromise between processibility, cost and mechanical properties. However, this material is prone to ESC failure.

FABRRICATION OF HIGHLY TUBULAR POROUS CHITOSAN/POLY (DL LACTIC-CO-GLYCOLIC ACID) (PLGA) NANOCOMPOSITE STRUCTURES INTENDED FOR TISSUE ENGINEERING SCAFFOLD APPLICATIONS
Zhixiang Cui, HaiBin Zhao, YiYen Peng, XiaoFeng Wang, Jian Han, Lih-Sheng Turng, Changyu Shen, May 2012

In this study, highly tubular porous chitosan/poly (DL lactic-co-glycolic acid) (PLGA) nanocomposite structures were produced via electrospinning and unidirectional freeze drying techniques. The 3D porous structure of chitosan/PLGA was characterized by scanning electron microscopy (SEM). The properties of the chitosan/PLGA nanocomposite, including porosity, water absorption, and mechanical properties, were investigated. The results showed that a highly tubular porous structure with nano-topography was formed and the compressive modulus increased greatly due to the addition of PLGA nanofibers.

FRICTION SPOT JOINING OF ALUMINUM 6181-T4 AND CARBON FIBER REINFORCED POLY(PHENYLENE SULFIDE)
Jodo Esteve, Sergio Amancio-Filho, Jorge dos Santos, Leonardo Canto, Elais Hage Jr., May 2012

Due to the increasing use of polymer-metal multi- material structures in automotive and aerospace industries, joining technology has grown in importance. Available techniques to join polymer-metal multi-material structures have been identified to be either too expensive, limited in performance or not environmental friendly. This work intends to investigate the feasibility of the new Friction Spot Joining technology on aluminum AA6181-T4 / poly(phenylene sulfide) laminate structures. Friction spot lap joints with high mechanical strength (29 MPa) were produced and investigated in terms of process temperature (average peak temperatures from 224 to 316 °C) microstructure and compared with similar joints available in the literature. Joints obtained by friction spot presented mechanical performance similar or superior to other available techniques used for joining polymer-metal structures. This is an indicative of the potential of this new technology to produce high performance metal-polymer multi-material structures.

FUNCTIONALITY IN MULTILAYER FILMS FOR PACKAGING
F. Sadeghi, R. Silverwood, A. Housni, A. Ajji, May 2012

During the last decades, the food, pharmaceutical and many other industries have seen several changes in packaging technology and applications because of new consumer demands and market trends. These drivers can be summarized as requirements for high quality, freshness and extended shelf-life of products, with easy-to-use and resistant packaging made with lighter, cheaper and recyclable materials. On the other hand, public demand and awareness for food safety has become a significant concern. This has even intensified on the recent regular outbreak of Listeria and Salmonella bacteria in various area of the world, following the consumption of contaminated meat and cheese products. The outbreak has prompted the public awareness to question food quality in stores and technological solutions that could prevent contamination and/or alert consumers may provide better public protection. Finally, the global market for materials and films used in packaging is very large. When decomposed into various segments such as controlled, active, and smart or barrier packaging, the volumes used and annual growth rates are significant in addition to other concerns such as sustainability. The performance of polymer films and multilayer packages are the result of the microstructure that is imparted to the material as a result of complex interactions between the resin and the thermo- mechanical history that it experiences during processing. This microstructure is strongly influenced by molecular parameters of the resins used (molecular weight, molecular weight distribution, branching, co-monomer type and content, etc.), their layout in multilayer structures and the additives used as well as the rheological, thermodynamic, thermal properties and the crystallization kinetics under the processing conditions. In the past, most of the studies were directed to the improvement of structural properties of films and multilayer structures (mainly mechanical: strength, tear, toughness etc...) and muc

GLASS FIBER REINFORCED ENGINEERING PLASTICS SIZING AN ESSENTIAL COMPONENT FOR PERFORMANCE
Jaap van der Woude, Piet Leegstra, May 2012

Fiber glass reinforced engineering plastics are increasingly important construction materials in transportation, electrical and other field applications. With the use of fiber glass reinforcements, certain material properties such as stiffness, strength and temperature stability are significantly improved. Combined with the base plastics, attractive material properties are obtained making them suitable for very demanding applications. Traditional performance attributes such as mechanical and environmental properties, reductions in total part cost as well as lightweight benefits allow these materials to provide answers to more complex applications, while meeting lightweight, recyclability, food contact and other requirements. It is essential to use the right fiber glass product with the right sizing specific to the application. Sizing provides a powerful solution for many processes and performance attributes of short fiber compounds and allows the final product to meet a variety of additional requirements. In this paper, the latest developments in glass fiber reinforcement will be reviewed, focusing on some of the most important engineering plastics such as polyamide, polyester and others. It will be demonstrated how very small amounts of glass fiber sizing can be very effective in realizing performance attributes over a wide range of requirements. In addition, examples will show how glass fiber reinforcements can greatly enhance the performance of certain biopolymers.

HYDROCARBON FUEL OBTAIN FROM MUNICIPAL WASTE PLASTICS USING STAINLESS STEEL REACTOR
Moinuddin Sarker, Mohammad Mamunor Rashid, Sadikur Rahman, May 2012

Waste plastics usages are increasing all over the world every day. People are consuming plastics in their daily life for all necessary purposes. After they are used all plastic become garbage and its goes to land fill or incineration facilities. It’s creating environmental problem. Waste plastic can be transform into alternate or renewable energy for electricity or feedstock refinery. The thermal degradation process applied with mixture waste plastics of high density polyethylene (HDPE-2), low density polyethylene (LDPE-4), Polypropylene (PP-5) and Polystyrene (PS-6) using stainless steel reactor has been successful in converting into liquid fuel. The polymer has been selected for the experiment 100% HDPE, LDPE, PP and PS by weight. The temperature used for degradation ranges from 150-400 °C and the experiment takes about was 5 -6 hours. The obtain products are liquid fuel, light gas and black carbon residue. Various techniques such as, (Gas Chromatography and Mass Spectrometer, FT-IR and DSC) are used for obtain the analysis of the fuel purposed. GC/MS result indicates hydrocarbon compound in the produced fuel ranges from C3-C28 and also present C1-C4 light gases. Also further fractional distillation process was used to obtain different 5 (Gasoline, Naphtha, Aviation, Diesel and Fuel Oil) category liquid fuel by using different temperature profiles. All of the fraction fuels have different carbon range and contain long chain hydrocarbon like alkane and alkene and some aromatic compound.

HYDROLYTIC DEPOLYMERIZATION OF PET DURING EXTRUSION
Tahereh Mousavand, Maryam Dini Pierre J. Carreau, Pascal Hubert, Musa R. Kamal, May 2012

Depolymerization of PET to high molecular weight oligomers could introduce opportunities to re-use PET waste via chemical recycling. Hydrolysis of PET in the presence of water/steam was carried out in a twin screw extruder, at barrel temperatures of 265°C and 300°C with screw speeds of 20, 60 and 200 rpm. The extruded products were characterized to determine intrinsic viscosity (IV) of samples as well as thermal properties (DSC) and rheological behavior. Proton nuclear magnetic resonance (HNMR) analysis was used to estimate carboxyl end group content. The results showed that the average molecular weight (Mw) of extruded polymer was reduced to less than 10,000 g/mol

IMPROVED UTILIZATION OF CO-PRODUCTS FROM BIOFUEL INDUSTRIES IN NEW MATERIALS USES: A MOVE TOWARDS SUSTAINABLE BIOREFINERY
Amar Mohanty, S. Vivekanandhan, Nima Zarrinbakhsh, Manjusri Misra, May 2012

Ever increasing energy demands, instability and uncertainty of petroleum/fossil fuel sources, and concern over global climate change have led to resurgence in the development of alternative energy that can replace fossil transportation fuel. Biomass conversion into biofuels, results a huge amount of residues or downstream products called as co-products such as distillers’ dried grains with solubles (DDGS), protein meals, crude glycerol, hemicellulose and lignin. As the production of biofuel continues to grow, surplus amounts of co-products become a critical issue and new value addition is needed for their effective utilization. A successful biorefinery begins with the productive usage of all components of biological feedstocks for value-added fuels, chemicals or materials that parallels the traditionall approach used in “petro-refineries”. Still biorefienry is risky investment, with respect to commercial benefits and finding value added uses for their co-products creates economic returns and lead to their sustainability. Thus present articles summaries the prospects of improved utilization of co-products from biofuel industries for new industrial applications.

IMPROVING PACKAGE TRACEABILITY, MARKETABILITY, AND SUSTAINABILITY WITH DIGITAL DECORATING
Chris DeMell, Chris Sobasze, Amy Swab, May 2012

The advent of piezo-based digital decorating enables marketers to deliver variable data, high impact graphics, and micro-targeted marketing with a single technology. Date coding, lot coding and traceability- back to the product’s origin- are now possible, enabling companies to satisfy increasingly stringent FDA requirements. And with no changeovers needed, marketers can economically create regional or store-level campaigns, delivering unique messages to minute market segments. Those messages are certain to pack a punch with near photographic quality images. Better yet, direct-to- package printing improves sustainability by eliminating labels, films and other consumable materials.

INVESTIGATION OF HIGH POWER ULTRASONICS FOR DEPOLYMERIZATION OF POLYLACTIC ACID
David Grewell, Gowrishankar Srinivasan, May 2012

This research work explores the feasibility of ultrasonics to recycle lactic acid by depolymerizing. Post consumer PLA chopped up to 1mm2 was exposed to high power ultrasonics with water or methanol as the suspension media. The treatments were carried out in the presence of organic and ionic salts of alkali metals such a potassium carbonate and zinc chloride as the catalysts. The treatments were replicated by replacing ultrasonics with Hot water bath as the energy source. Analysis with HPLC indicated PLA to Lactic acid conversion was achieved with yields up to 90% utilizing ultrasonics. Energy calculations indicated that Ultrasonics used 30% less energy to achieve the same yield levels as achieve with hot bath technique










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